Identification of the fracture mechanism is one of the principal responsibilities of a failure analyst and is an important component of any root-cause analysis. This article explores the varied mechanisms responsible for metal fracture, particularly regarding fractography. The behavior of engineering materials at fracture is based on a large number of interrelated characteristics from the atomic level to the component level. These characteristics range from ductile to brittle at the microscale and macroscale levels. Fundamental relative ductility results from the type of electronic bonding, the crystal structure, and the broader long-range degree of order. It provides detailed discussion on ductile fracture, brittle fracture, mixed fracture, embrittlement, stress-corrosion cracking.

This article describes the general factors that can influence fracture appearances. The focus is on the general practical relationships of fracture appearances, with factors presented in some broad categories, including: material conditions (e.g., crystal structure and microstructure); loading conditions (stress state, strain rate, and fatigue); manufacturing conditions (casting, metal-working, machining, heat treatment, etc.); and service and environmental factors (hydrogen embrittlement, stress corrosion, temperature, and corrosion fatigue).

With any polymeric material, chemical exposure may have one or more different effects. Some chemicals act as plasticizers, changing the polymer from one that is hard, stiff, and brittle to one which is softer, more flexible, and sometimes tougher. Often these chemicals can dissolve the polymer if they are present in large enough quantity and if the polymer is not crosslinked. Other chemicals can induce environmental stress cracking (ESC), an effect in which brittle fracture of a polymer will occur at a level of stress well below that required to cause failure in the absence of the ESC reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface embrittlement and temperature on polymer performance.

This article aims to identify and illustrate the types of overload failures, which are categorized as failures due to insufficient material strength and underdesign, failures due to stress concentration and material defects, and failures due to material alteration. It describes the general aspects of fracture modes and mechanisms. The article briefly reviews some mechanistic aspects of ductile and brittle crack propagation, including discussion on mixed-mode cracking. Factors associated with overload failures are discussed, and, where appropriate, preventive steps for reducing the likelihood of overload fractures are included. The article focuses primarily on the contribution of embrittlement to overload failure. The embrittling phenomena are described and differentiated by their causes, effects, and remedial methods, so that failure characteristics can be directly compared during practical failure investigation. The article describes the effects of mechanical loading on a part in service and provides information on laboratory fracture examination.

Hydrogen damage is a term used to designate a number of processes in metals by which the load-carrying capacity of the metal is reduced due to the presence of hydrogen. This article introduces the general forms of hydrogen damage and provides an overview of the different types of hydrogen damage in all the major commercial alloy systems. It covers the broader topic of hydrogen damage, which can be quite complex and technical in nature. The article focuses on failure analysis where hydrogen embrittlement of a steel component is suspected. It provides practical advice for the failure analysis practitioner or for someone who is contemplating procurement of a cost-effective failure analysis of commodity-grade components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also provided.

Metal-induced embrittlement is a phenomenon in which the ductility or the fracture stress of a solid metal is reduced by surface contact with another metal in either the liquid or solid form. This article summarizes some of the characteristics of liquid-metal- and solid-metal-induced embrittlement. This phenomenon shares many of these characteristics with other modes of environmentally induced cracking, such as hydrogen embrittlement and stress-corrosion cracking. The discussion covers the occurrence, failure analysis, and service failures of the embrittlement. The article also briefly reviews some commercial alloy systems in which liquid-metal-induced embrittlement or solid-metal-induced embrittlement has been documented and describes some examples of cracking due to these phenomena, either in manufacturing or in service.

This article provides a detailed discussion on heat treatment of titanium alloys such as alpha alloys, alpha-beta alloys, and beta and near-beta alloys. Common processes include stress-relief, annealing, solution treating, aging, quenching, and age hardening. It provides information on the effects of alloying elements on alpha/beta transformation. The article also discusses the heat treating procedures, and the furnaces used for heat treating titanium and titanium alloys.

This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition. Methods such as precipitation from salt solution and gas, chemical embrittlement, hydride decomposition, and thermite reactions are also discussed. The article also discusses the methods used to produce powders electrolytically and the types of metal powders produced. The physical and chemical characteristics of these powders are also reviewed.

Quench cracking is a brittle fracture phenomenon, and its occurrence depends not only on the stress changes but also on the mechanical characteristics of metals. Simulation of quenching processes has become possible in the analysis of quench cracking. This article commences with a discussion on the studies conducted to determine the origin of quench cracks, and then describes various test procedures for determining the susceptibility of quench cracking. It provides a description of the brittle fracture in terms of fracture mechanics and fracture toughness of quenched metals, and discusses the effects of impurities, hydrogen, and surface roughness on cracking. The article exemplifies simulation works applied to several successful cracking tests on cylindrical and complex-shaped steel parts.

Tempering of steel is a process in which hardened or normalized steel is heated to a temperature below the lower critical temperature and cooled at a suitable rate, primarily to increase ductility, toughness, and grain size of the matrix. This article provides an overview of the variables that affect the microstructure and mechanical properties of tempered steel, namely, the tempering temperature, tempering time, carbon content, alloy content, and residual elements. Tempering after hardening is performed to relieve quenching stresses and ensure dimensional stability of steel. The article discusses the embrittlement problems associated with tempering. Four types of equipment are used for tempering, namely, convection furnaces, salt bath furnaces, oil bath equipment and molten metal baths. Special procedures for tempering are briefly reviewed.

High-velocity oxyfuel (HVOF)-applied thermal spray coatings are viable candidates for replacement of hard chrome in numerous applications. HVOF thermal spraying can be used to deposit both metal alloy and cermet coatings that are dense and highly adherent to all the commonly used base metals in airframe structures. This article summarizes the results of materials and component testing. It also presents a cost/benefit analysis of HVOF WC/17Co and WC/10Co4Cr coatings on aircraft landing gear components.

This article focuses on the analysis of materials and mechanical- (or biomechanical-) based medical device failures. It reviews the failure analysis practices, including evidence receipt, cleaning, nondestructive examination, destructive examination, exemplars analysis, and device redesign. The article examines the common failure modes, such as overload, fatigue, corrosion, hydrogen embrittlement, and fretting, of medical devices. The failure analysis of orthopedic implants, such as permanent prostheses and internal fixation devices, is described. The article reviews the failure mechanisms in some of the more common medical device materials, namely, stainless steels, titanium alloys, cobalt-base alloys, and nitinol. It presents case histories with examples for failure analysis.

Electroslag welding (ESW) involves high energy input relative to other welding processes, resulting generally in inferior mechanical properties and specifically in lower toughness of the heat-affected zone. Electrogas welding (EGW) is a method of gas metal or flux cored arc welding, wherein an external gas is supplied to shield the arc, and molding shoes are used to confine the molten weld metal for vertical-position welding. This article describes the fundamentals, temperature relations, consumables, metallurgical and chemical reactions, and process development of ESW. The problems, quality control, and process applications of ESW and EGW are also discussed.

Submerged arc welding (SAW) is suited for applications involving long, continuous welds. This article describes the operating principle, application, advantages, limitations, power source, equipment, and fluxes in SAW. It reviews three different types of electrodes manufactured for SAW: solid, cored, and strip. The article highlights the factors to be considered for controlling the welding process, including fit-up of work, travel speed, and flux depth. It also evaluates the defects that occur in SAW: lack of fusion, slag entrapment, solidification cracking, and hydrogen cracking. Finally, the article provides information on the safety measures to be followed in this process.

This article provides a discussion on ten rules for the effective production of reliable castings. These rules include good-quality melt, liquid front damage, liquid front stop, bubble damage, core blows, shrinkage damage, convection damage, segregation, residual stress, and location points.

This article presents the primary considerations and mechanisms for corrosion and explains how they are involved in the selection of materials for process equipment in refineries and petrochemical plants. It discusses the material selection criteria for a number of ferrous and nonferrous alloys used in petroleum refining and petrochemical applications. The article reviews the mechanical properties, fabricability, and corrosion resistance of refinery steels. It describes low- and high-temperature corrosion, hydrogen embrittlement, and cracking such as stress-corrosion, sulfide stress, and stress-oriented hydrogen-induced cracking. The article considers hydrogen attack, corrosion fatigue, and liquid metal embrittlement and the methods of combating them. It explains the causes of velocity-accelerated corrosion and erosion-corrosion. The article summarizes some corrective measures that can be implemented to control corrosion. The applicable standards for materials used in corrosive service conditions in upstream and downstream petroleum service are presented in a tabular form.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.