Because of the tough engineering environment of the railroad industry, fatigue is a primary mode of failure. The increased competitiveness in the industry has led to increased loads, reducing the safety factor with respect to fatigue life. Therefore, the existence of corrosion pitting and manufacturing defects has become more important. This article presents case histories that are intended as an overview of the unique types of failures encountered in the freight railroad industry. The discussion covers failures of axle journals, bearings, wheels, couplers, rails and rail welds, and track equipment.

Although aluminum alloys are inherently corrosion resistant, there are many operating environments where they require additional protection. This article describes the conditions under which aluminum is prone to corrode and explains how to prevent it through the addition of conversion coatings and paints. It addresses some of the more common corrosion mechanisms, including corrosion driven by pH extremes, pitting corrosion, crevice corrosion, galvanic corrosion, and filiform corrosion. The article also describes in-plant as well as field application procedures for cleaning and coating, and discusses the advantages and limitations of the various materials and chemicals used.

This article is concerned with gear tooth failures influenced by friction, lubrication, and wear, and especially those failure modes that occur in wind-turbine components. It provides a detailed discussion on wear (including adhesion, abrasion, polishing, fretting, and electrical discharge), scuffing, and Hertzian fatigue (including macropitting and micropitting). Details for obtaining high lubricant specific film thickness are presented. The article describes the selection criteria for lubricants, such as oil, grease, adhesive open gear lubricant, and solid lubricants. It discusses the applications of oil and gear lubricants and the types of standardized gear tests. The article presents some recommendations for selecting lubricants and lubricant viscosity for enclosed gear. It provides some examples of failure modes that commonly occur on gears and bearings in wind turbine gearboxes.

Cast irons provide excellent resistance to a wide range of corrosion environments when properly matched with that service environment. This article presents basic parameters to be considered before selecting cast irons for corrosion services. Alloying elements can play a dominant role in the susceptibility of cast irons to corrosion attack. The article discusses the various alloying elements, such as silicon, nickel, chromium, copper, and molybdenum, that enhance the corrosion resistance of cast irons. Cast irons exhibit the same general forms of corrosion as other metals and alloys. The article reviews the various forms of corrosions, such as graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. It discusses the four general categories of coatings used on cast irons to enhance corrosion resistance: metallic, organic, conversion, and enamel coatings.

Carbonitriding is a modified form of carburizing that involves the introduction and diffusion of atomic nitrogen into the surface steel during carburization. This article discusses the composition, depth, and hardenability of a carburized case, and demonstrates how to control atmosphere in batch and continuous furnaces. It discusses the most important considerations in the selection of carbonitriding temperature. The article also describes the processing factors for minimizing retained austenite in the carbonitrided case. Hardness testing and carbonitriding of powder metallurgy parts, quenching and tempering of carbonitrided steel parts, and applications of carbonitriding are also covered in the article.

Homogenization, in a broad sense, refers to the processes designed to achieve uniform distribution of solutes or phases in a given matrix. This article addresses the root cause for inhomogeneities in cast components. It is nearly a standard industrial practice to homogenize alloys before thermomechanical processing. The article lists the objectives of homogenization and benefits of homogenization treatments. The benefits include increased resistance to pitting corrosion, increased resistance to stress-corrosion cracking, improved ductility, and uniform precipitate distribution during subsequent aging. The article provides a schematic illustration of an energy-dispersive X-ray spectroscope (EDS) scattered data of solute distributions across a dendrite due to microsegregation of chromium and molybdenum. It concludes with information on the computational modeling for simulation of microsegregation of chromium and molybdenum.

This article discusses the commonly encountered forms of automotive body corrosion. The corrosion forms include general or uniform corrosion, cosmetic or under-film corrosion, galvanic corrosion, crevice corrosion, poultice or under-deposit corrosion, and pitting corrosion. Corrosion-resistant sheet metals, such as electrogalvanized steel, hot dip galvanized steel, and hot dip galvannealed steel, are reviewed. The article provides information on the paint and sealant systems for corrosion control in automotive body applications.

This article addresses the major heat-transfer components of the water-steam loop of a power plant. It describes the various types of condensers, including water-cooled condensers and air-cooled condensers. The article explains the corrosion mechanisms encountered in the condensers, including erosion-corrosion, galvanic corrosion, and pitting corrosion. It discusses the types of deaerators and deals with their corrosion problems. The article provides a discussion on two types of feedwater heaters: channel feedwater heaters and header feedwater heaters. It summarizes the corrosion problems associated with common feedwater heater tube materials.

This article begins with a discussion on the components and importance of flue gas desulfurization (FGD) technology used in power plant for pollution control. It further discusses the corrosion problems encountered in different operating zones of FGD system and the major forms of corrosive attack encountered in those zones, including crevice corrosion, pitting corrosion, and acid attack. The article concludes with information on the materials selection and design features for minimizing the possibility of corrosion.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

Steel automotive exhaust systems suffer from various forms of corrosion. This article illustrates exhaust system components with typical upper metal skin temperatures and alloys of construction. It discusses high-temperature corrosion of automotive exhaust systems, including oxidation, hot salt attack, and thermal fatigue. The article describes the various forms of corrosion which occur at the cold end of an exhaust system. The forms of cold end exhaust corrosion, including condensate pitting corrosion, exterior salt pitting, crevice corrosion, intergranular corrosion, and galvanic corrosion.

The steam turbine is the simplest and most efficient engine for converting large amounts of heat energy into mechanical work. This article discusses the primary corrosion mechanisms such as corrosion fatigue, stress-corrosion cracking (SCC), pitting, corrosion, and erosion-corrosion, in steam turbines. It illustrates the various causes of the corrosiveness of the steam turbine environments through a Mollier diagram. The article describes the four parts of design disciplines that affect turbine corrosion, namely, mechanical design, heat transfer, flow and thermodynamics, and physical shape. It lists the ways to control the steam and surface chemistry, and design and material improvements to minimize turbine corrosion.

Advances in vehicle design and technology require engine coolant technology to minimize the degradation of nonmetals and prevent the corrosion of the metals in the cooling system. This article provides a detailed discussion on the functions, operation, materials, and major components of the cooling system. It discusses various forms of corrosion that occur in cooling systems, including uniform corrosion, galvanic corrosion, crevice corrosion, pitting corrosion, intergranular corrosion, erosion corrosion, and cavitation corrosion. The article presents information on engine coolant base components and inhibitors used for corrosion prevention. It reviews the coolant performance tests recommended by ASTM, SAE, and vehicle manufacturers. The article concludes with a description on the difference between light-duty automotive and heavy-duty diesel engine coolants.

Corrosion, fatigue, and their synergistic interactions are among the principal causes of damage to aircraft structures. This article describes aircraft corrosion fatigue assessment in the context of different approaches used to manage aircraft structural integrity, schedule aircraft inspection intervals, and perform repair and maintenance of aircraft in service. It illustrates the types of corrosive attack observed in aircraft structures, including uniform, galvanic, pitting, filiform, fretting, intergranular, exfoliation corrosion, and stress-corrosion cracking. The article discusses geometric parameters such as pit dimensions, surface roughness, loss of metal thickness, and volume increase due to pillowing to quantitatively characterize the types of corrosion. It also explains the two most common fatigue life assessment methods used in the military aerospace industry: fatigue crack initiation and crack growth analysis.

This article discusses the main materials and water chemistry characteristics of the primary and secondary water circuits of a pressurized water reactor (PWR). It reviews the corrosion issues of PWR materials and the influence of corrosion and fouling on primary and secondary circuit radiation fields. The article explains the primary side intergranular stress corrosion cracking (IGSCC) in different materials, namely, nickel-base alloys, high-strength nickel-base alloys, low-strength austenitic stainless steels, and high-strength stainless steels. The secondary side corrosion in steam generator including denting, pitting, intergranular attack and IGSCC is also discussed. The article examines laboratory studies that have resulted in models and computer codes for evaluating and predicting intergranular corrosion, and considers the remedial actions for preventing or arresting intergranular corrosion. It concludes with information on the external bolting corrosion in nuclear power reactors.

This article describes the commonly observed forms of airplane corrosion, namely: general corrosion, exfoliation corrosion, pitting corrosion, microbiologically induced corrosion, galvanic corrosion, filiform corrosion, crevice corrosion, stress-corrosion cracking, and fretting. It discusses the factors influencing airplane corrosion from the manufacturing perspective: design, manufacturing, and service-related factors. The article explains the collection of corrosion data and provides an overview of the implementation and evolution of airline corrosion prevention and control programs and directions being considered in the design for corrosion prevention of airplanes.

This article discusses the influence of the materials, design, package type, and environment on corrosion in microelectronics. It describes the common sources and mechanisms of corrosion in microelectronics, including anodic, cathodic, and electrolytic reactions resulting in uniform corrosion, galvanic corrosion, pitting corrosion, creep corrosion, dendrite growth, fretting, stress-corrosion cracking, and whisker growth. The article presents effective measures for minimizing the moisture retention in hermetic packages and/or moisture ingress in plastic packages. It concludes with information corrosion tests.

This article describes the corrosion of principal parts of mining equipment such as mine shafts, wire rope, rock bolts, and pump and piping systems. It discusses the diagnosis and prevention of various types of corrosion including uniform corrosion, pitting corrosion, crevice corrosion, erosion-corrosion, and intergranular corrosion. The article explains the corrosion in tanks, reactor vessels, cyclic loading machinery, and pressure leaching equipment.

This article describes the processes involved in the production of hafnium and its alloys. It discusses the physical, mechanical and chemical properties of hafnium. The aqueous corrosion testing of hafnium and its alloys is detailed. The article reviews the corrosion resistance of hafnium in specific media, namely, water, steam, hydrochloric acid, nitric acid, sulfuric acid, alkalis, organics, molten metals, and gases. Forms of corrosion, namely, galvanic corrosion, crevice corrosion, and pitting corrosion are included. The article explains the corrosion of hafnium alloys such as hafnium-zirconium alloys and hafnium-tantalum alloys. It also deals with the applications of hafnium and its alloys in the nuclear and chemical industries.

This article provides an overview of the identification systems for various grades of wrought stainless steels, namely, the American Iron and Steel Institute numbering system, the Unified Numbering System, and proprietary designations. It elaborates on five major families of stainless steels, as defined by the crystallographic structure. These include ferritic stainless steels, austenitic stainless steels, martensitic stainless steels, and precipitation-hardening stainless steels. The mechanism of corrosion protection for stainless steels is reviewed. The article examines the effects of composition, processing, design, fabrication, and external treatments on the corrosion of stainless steels. Various forms of corrosion, namely, general, galvanic, pitting, crevice, intergranular, stress-corrosion cracking, erosion-corrosion, and oxidation, are reviewed. Corrosion testing for; corrosion in atmosphere, water, and chemical environments; and the applications of stainless steels in various industries are also discussed.