Thermal spray coatings (TSCs) are surface coatings engineered to provide wear-, erosion-, abrasion-, and corrosion-resistant coatings for original equipment manufacture and for the repair and upgrading of in-service equipment. This article presents an overview of five thermal spray processes and the specific flame and arc spray processes used to preserve large steel components and structures. It describes the TSC selection guide and an industrial process procedure guide for applying aluminum and zinc TSCs onto steel.