Cast iron is probably the most complex alloy used by human civilization. It includes in its chemical composition more elements than superalloys, that is, base elements (C, Si, Mn, P, S), alloying elements (Cu, Sn, Ni, Cr, Mo, V, Al), and minor elements (As, B, Bi, Cd, Pb, Sb, Se, Te, Ti, Zr). Depending on composition and cooling rate, it solidifies with either stable or metastable eutectic and with the carbon-rich phase, graphite, in a variety of morphologies, from flake/lamellar to nodular/spheroidal. Cast iron is the first man-made metal-matrix composite, combining crystalline iron and crystalline graphite. It has a wide range of properties, including higher specific properties (property/density) than many of its competing materials. For example, cast iron has higher specific fatigue strength and higher specific tensile strength at temperatures above 100 °C than aluminum, and all this at a much lower price. This explains why iron castings represent approximately 70% of the total tonnage of castings worldwide. Thus, collecting the available information on the history, science, and technology of cast iron in a single volume is a worthwhile endeavor. As, at the beginning of human civilization, iron processing was considered magic, which then evolved into an art, then technology, and finally science, culminating today with virtual cast iron, this endeavor is not just worthwhile but also challenging.

Yet, this book intends to be more than a technical compendium. It aspires to also acknowledge the history of cast iron, an important attribute if we care to consider the fast pace of knowledge development. The Renaissance genius Sir Francis Bacon was thought to be the last person who knew everything a person could know, at least in a European nation, in 1600. Until 1900, human knowledge doubled every century. By 1945, knowledge was doubling every 25 years. Today, different types of knowledge have different rates of growth: Nanotechnology knowledge doubles every 2 years, but clinical knowledge doubles every 18 months. On average, human knowledge doubles every 13 months. According to IBM, the building of the “internet of things” will lead to the doubling of knowledge every 12 hours.

But what is knowledge? According to Aristotle (384–322 B.C.E.), considered to be the father of science and the scientific method and the inventor of the language of science, knowledge includes theoretical (episteme—knowing and understanding), practical (praxis—doing), and technical (technē—making, production). It is one of the ambitions of this Volume to include aspects of all these types of knowledge on cast iron. And, as Plato (428–347 B.C.E.), considered to be the founder of Western spirituality, stated, “where there is number there is order; where there is no number there is nothing but disorder,” this Volume also stresses the mathematical, quantitative aspects of the science of cast iron. This is a logical objective, as many of the processes used in iron casting are still empirical in nature, but many others are deeply rooted in mathematics. The knowledge ladder includes generation of knowledge, transfer of knowledge, and implementation of knowledge. Thus, knowledge is not merely the possession of information but rather its implementation and use,which brings us to the main goal of this Volume—to package and transfer knowledge in a form that can facilitate its implementation in praxis. Because this is a monumental, almost impossible task, its completion necessitated the involvement of the top iron casting engineers and scientists in the international community. Their collective effort was successful in assembling what I believe to be the most complete text on cast iron available in the English language today.

This Volume is structured in eleven sections, starting with an introduction that covers the history of cast iron and a detailed classification and discussion of the basic types of cast iron. The following section is a rather academic treatment of the fundamentals of the metallurgy of cast irons, including thermodynamics principles specific to cast iron, microstructure evolution and volumetric changes during solidification and solid-state transformation, and prediction of solidification microstructure through computational modeling, which was dubbed earlier in this preface as “virtual cast iron.” Next, an extensive discussion of the many facets of the science and engineering of processing of cast ironis provided, with particular emphasis on liquid metal preparation, casting processes, and heat treatment. The section on secondary processing addresses issues such as machining, inspection, and quality control. The properties of various types of iron and the effects of processing are treated in a section that concludes with another “virtual cast iron” subject, computer-aided prediction of mechanical properties. The specifications, selection criteria, microstructure, and production particularities of the main classes of cast iron—gray iron, ductile iron, compacted graphite iron, high-alloy iron, and malleable iron—are then discussed in great detail in separate sections. Attention is given to more recent developments, such as thin-wall iron and heavy-section ductile iron castings. Most articles include a large number of references that serve a dual purpose: to give credit where credit is due, and to direct the reader to additional information on the subject, if the reader is interested.

This Volume is the product of the combined efforts of an international team of top scientists and metal casting specialists from no less than 12 countries (Argentina, Brazil, China, Denmark, France, Norway, Poland, Romania, Spain, Sweden, the United Kingdom, and the United States of America) and of the outstanding diligence of the ASM International technical and support personnel, to whom the Editor is deeply grateful. The Editor would like to extend his personal appreciation to the leaders of the ASM International team, Mr. Steve Lampman, Senior Content Developer, and Ms. Vicki Burt, Content Developer, for their remarkable efforts in coordinating this gargantuan task and their personal contributions to the text. It required many, many days. We—the authors, the ASM International team, and the Editor—do hope that the readers will find in this Volume answers to most of the questions that they may have on cast iron for many years to come.