This article begins with a discussion on the effects of alloying and impurity elements on the properties of aluminum cast alloys and their chemical compositions. It describes the various means of structural control, namely, chemistry control, control of element ratios based on the stoichiometry of intermetallic phases, and control of solidification conditions. The article discusses the modification and grain refinement of aluminum-silicon alloys by the use of modifiers and refiners to influence eutectic and hypereutectic structures in aluminum-silicon alloys. It provides information on foundry alloys for specific casting applications. The article concludes with a discussion on the heat treatment...