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Exfoliation is a structure-dependent form of localized intergranular corrosion that follows grain boundaries in the rolling direction of wrought materials, particularly aluminum alloys. Highly cold-worked materials with elongated grain boundaries tend to be most affected. The article provides information on accelerated salt spray and total-immersion testing methods to help rate the exfoliation corrosion susceptibility of various aluminum alloys and alloy compositions. It also discusses visual assessment challenges and identifies several ASTM designations and where and how they apply.

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