Another failure in a turbogenerator, similar to the accidents in Toronto described in Metal Progress in July 1956, was due to the presence of fatigue cracks at ventilating holes. These acted as stress-raisers during temporary and minor overspeeding, inducing an almost instantaneous brittle failure which wrecked the machine, fortunately without human casualty.

Forged austenitic steel rings used on rotor shafts in two 100,000 kW generators burst from overstressing in a region of ventilation holes. A variety of causes contributed to the brittle fractures in the ductile austenitic alloy, including stress concentration by holes, work hardened metal in the bores, and a variable pattern of residual stress.

A corrosion resistant chromium nickel steel (X 2 Cr-Ni-Mo 18 10) worm drive used in a chemical plant at 80 deg C and 100 to 200 atm pressure to transport media containing chloride failed during normal operation. Visual inspections showed that the entire surface of the gear was covered with fine branching cracks and was flaking off. Microscopic examination showed that the unetched polished material had disintegrated to an average depth of 1 mm below the surface. A micrograph of the etched surface revealed numerous deformation lines and transgranular cracking. The failure was thus due to stress-corrosion cracking and additional corrosion due to ventilation elements. Because austenitic chromium nickel steels are prone to stress-corrosion cracking, particularly in the presence of chlorine compounds at high temperatures, and because austenitic rust- and acid-resistant steels are prone to smearing and work hardening during machining, it was recommended that these types of steels be machined only with sharp, short tools mounted in rigid structures. In addition, residual stresses should be eliminated by post-process annealing in a protective atmosphere.

A welded vessel made of acid resistant 18-8 steel used in a derusting operation started to leak after a long period due to the formation of cracks. The vessel was heated from the outside and did not come into direct contact with the flame. It was surrounded by a casing of unalloyed steel. Where the cracks had not eroded away, it was clear they ran transcrystalline, indicative of stress-corrosion cracking. Because the cracks propagated from the outer surface of the vessel, they were not caused by the derusting agent but by the external atmosphere in conjunction with welding stresses. The narrow gap between vessel and mild steel casing may have aggravated the situation in that it hindered ventilation and evaporation of condensation and favored the absorption and concentration of acids and salts. Contact and crevice corrosion due to deposition of rust from the mild steel casing may have contributed.

The lock ring of a centrifuge drum was fractured after one year's operation. The ring, with a trapezoidal thread on the inside, was made of steel with approximately 0.5%C-1.3%Mn-1.1%Cr and was hardened and tempered to 105 kp/sq mm strength at 11% elongation (d10). It fractured radially in one of four places in which the cross section was weakened by short grooves that served as tool grips for tightening the cover. The fracture propagated from the base of the thread and followed it in a circumferential direction until it was broken through radially at the top across the ring due to a weakening caused by the external reduction of the cross section. The uppermost turn was corroded at the base by pitting favored by differences in ventilation and formation of Evans elements in the narrow gap between thread and counterthread. Metallographic examination showed that the pitting favored intergranular fissures and therefore it can be established that stress corrosion accelerated cracking of the ring Although since the drum was used for the processing of various liquids, the exact corroding medium cannot be stated.

An elbow made from welded steel tube had become leaky along a well-defined line in the axial direction. The entire wall of the tube was corroded, and the longitudinally-welded seam stood out clearly as a result of particularly intensive corrosive attack. The appearance of the corroded surface indicates the action of water with a high oxygen content. The oxygen in the return water must have originated from the ventilation of the open expansion vessel. Because of the corrosion-favoring effect of a crevice, water with a high oxygen-content that was perhaps still warm or even hot found particularly favorable conditions for corrosion in the defective welded seam (crevice corrosion). The tube material itself is perfectly satisfactory and in no way responsible for the failure.

Two hot water reheat coil valves from a heating/ventilating/air-conditioning system failed in service. The values, a 353 copper alloy 19 mm (3/4 in.) valve and a 360 copper alloy 13 mm (1/2 in.) valve, had been failing at an increasing rate. The failures were confined to the stems and seats. Visual examination revealed severe localized metal loss in the form of deep grooves with smooth and wavy surfaces. Metallographic analysis of the grooved areas revealed uniform metal loss. No evidence of intergranular or selective attack indicating erosion-corrosion was observed, Recommendations included use of a higher-copper brass, cupronickel, or Monel for the valve seats and stems and operation of the valves in either the fully opened or closed position.

High-level radioactive wastes generated during the processing of nuclear materials are kept in large underground storage tanks made of low-carbon steel. The wastes consist primarily of concentrated solutions of sodium nitrate and sodium hydroxide. Each of the tanks is equipped with a purge ventilation system designed to continuously remove hydrogen gas and vapors without letting radionuclides escape. Several intergranular cracks were discovered in the vent pipe of one such system. The pipe, made of galvanized steel sheet, connects to an exhaust fan downstream of high-efficiency particulate air filters. The failure analysis investigation concluded that nitrate-induced stress-corrosion cracking was the cause of the failure.

This paper describes the remote ultrasonic (UT) examinations of a high-level radioactive waste storage tank at the Savannah River Site in South Carolina. The inspections, carried out by E.R. Holland, R.W. Vande Kamp, and J.B. Elder, were performed from the contaminated, annular space of the 46 year old, inactive, 1.03 million gallon waste storage tank. A steerable, magnetic wheel wall crawler was inserted into the annular space through small (6 in., or 150 mm, diam) holes/risers in the tank top. The crawler carried the equipment used to simultaneously collect data with up to four UT transducers and two cameras. The purpose of this inspection was to verify corrosion models and to investigate the possibility of previously unidentified corrosion sites or mechanisms. The inspections included evaluation of previously identified leak sites, thickness mapping, and crack detection scans on specified areas of the tank. No indications of reportable wall loss or pitting were detected. All thickness readings were above minimum design tank-wall thickness, although several small indications of thinning were noted. The crack detection and sizing examinations revealed five previously undetected indications, four of which were only partially through-wall. The cracks that were examined were found to be slightly longer than expected but still well within the flaw size criteria used to evaluate tank structural integrity.

Applying general techniques of failure analysis, the authors deduced that an in-flight explosion brought down a passenger plane. Other evidence pinpointed the location of the explosive, an important factor in establishing responsibility.

A nozzle in a wastewater vaporizer began leaking after approximately three years of service with acetic and formic acid wastewaters at 105 deg C (225 deg F) and 414 kPa (60 psig). The shell of the vessel was weld fabricated from 6.4 mm (0.25 in.) E-Brite stainless steel plate and measured 1.5 m (58 in.) in diameter and 8.5 m (28 ft) in length. Investigation (visual inspection, chemical analysis, radiography, dye-penetrant inspection, and hydrostatic testing of all E-Brite welds, 4x images, 100x/200x images electrolytically etched with 10% oxalic acid, and V-notch Charpy testing) supported the conclusion that failure of the nozzle weld was the result of intergranular corrosion caused by the pickup of interstitial elements and subsequent precipitation of chromium carbides and nitrides. Carbon pickup was believed to have been caused by inadequate joint cleaning prior to welding. The increase in the weld nitrogen level was a direct result of inadequate argon gas shielding of the molten weld puddle. Two areas of inadequate shielding were identified: improper gas flow rate for a 19 mm (0.75 in.) diam gas lens nozzle, and contamination of the manifold gas system. Recommendations included changes in the cleaning and welding process.

Macrofractographs of the fracture surface from a multibladed fan showed that cracks started at the corner where bending stress was concentrated and propagated through the blade by fatigue. Peak stress at the monitoring position was less than 10 MPa. To simulate crack growth, the rotor was repeatedly deformed by a hydraulic fatigue tester. Comparison of striations of the failed blade with that of the tested one revealed the failed blade was loaded with more than 30 MPa of stress. These tests confirmed that the rotor and blades had sufficient strength to withstand up to 3x the stress of normal operation. The casing of the fan was vibrated at 10 to 60 Hz. Peak stress easily overcame 30 MPa, which was enough to initiate cracking. The fracture surfaces and starting position were the same as those on the failed fan. It was concluded that the exciting force from an air compressor caused blade failure.

There are many reasons why plastic materials should not be considered for an application. It is the responsibility of the design/materials engineer to recognize when the expected demands are outside of what the plastic can provide during the expected life-time of the product. This article reviews the numerous considerations that are equally important to help ensure that part failure does not occur. It provides a quick review of thermoplastic and thermoset plastics. The article focuses primarily on thermoset materials that at room temperature are below their glass transition temperature. It describes the motivation for material selection and the goal of the material selection process. The use of material datasheets for material selection as well as the processes involved in plastic material selection and post material selection is also covered.

This article presents a general overview of outdoor weather aging factors, their effects on the performance of polymeric materials, and the accelerated test methods that can be used to investigate those effects. These test methods are used to characterize material performance when subjected to specific, often controlled, and well-defined factors. The article also presents an overview of weathering instrument types that simulate outdoor stress factors.

Plastic product failures are directly attributed to one of the following four reasons: omission of a critical performance requirement, improper materials specification, design error, and processing/manufacturing error. Therefore, product failures can be minimized or eliminated if all of these parameters are comprehensively examined during the design process. This article focuses on all of these factors, except processing-related failures, which are outside the design and engineering domain. It is dedicated to the identification and avoidance of common problems associated with the selection and designing of plastic parts. The article provides information on the material-related design criteria that depend on the applications, environmental conditions of use, and performance requirements. It discusses physical properties of plastics based on their relevance to real-world environmental conditions. The most-common design problems related to design considerations are also covered.

This article addresses the forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. It describes the mechanisms of corrosive attack for specific forms of corrosion such as galvanic corrosion, uniform corrosion, pitting and crevice corrosion, intergranular corrosion, and velocity-affected corrosion. The article contains a table that lists combinations of alloys and environments subjected to selective leaching and the elements removed by leaching.

Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.