An outer fan-duct assembly of titanium alloy Ti-5Al-2.5Sn (AMS 4910) for a gas-turbine fan section cracked 75 mm (3 in.) circumferentially through a repair weld in an arc weld in the front flange-duct segment. Examination of the crack with a binocular microscope revealed no evidence of fatigue. A blue etch-anodize inspection showed the presence of an alpha case along the edges of the repair weld. The alpha case, a brittle oxide-enriched layer, forms when welds are inadequately shielded from the atmosphere during deposition. The brittleness of this layer caused transgranular cracks to form and propagate in tension under the thermal stresses created by the repair-weld heat input. The crack resulted from contamination and embrittlement of a repair weld that had received inadequate gas shielding. Thermal stresses cracked the oxide-rich layer that formed. The gas-shielding accessories of the welding torch were overhauled to ensure that leak-in or entrainment of air was eliminated. Also, the purity of the shielding-gas supplies was rechecked to make certain that these had not become contaminated.

A forging die in a 250-ton press producing brass valves began to show signs of fatigue after a few thousand hits. By the time it reached 30,000 hits, the die was badly damaged and was submitted for analysis along with one of the last forgings produced. The investigation included visual and macroscopic inspection, metallographic and chemical analysis, SEM imaging, optical profilometry, mechanical property testing, and EDX analysis. The die was made of chromium hot-work tool steel and the forgings were made of CuZn39Pb3 heated to an initial working temperature 700 deg C. The entire surface of the die was covered with fatigue cracks and many fillets had been plastically deformed. Several other types of damage were also observed, including areas of oxidation, corrosion pits, voids, abrasive wear, die adhesion, and thermal fatigue. Fatigue cracking was the primary cause of failure with significant contributions from the other damage mechanisms.

In Nov. 1998, the west superheater outlet header at an electricity generating plant began to leak steam. Subsequent investigation revealed the presence of a crack that extended for 360 deg around the full circumference of the header and through the full cross-sectional thickness. The subsequent inspection of this header and the east superheater header revealed the presence of extremely severe ligament cracking. They operated at 2400 psi (16.5 MPa) and a temperature of 540deg C (1005 deg F). Both were fabricated from seamless pipe produced in accordance with ASME Specification SA-335, and the steel was Grade P22, a 2.25Cr-1Mo alloy steel. Visual and metallurgical evaluations showed the cracking in the west superheater outlet header was caused by thermal fatigue. Tube holes had served as a preferential site for thermal fatigue cracking.

A short fracture section of a forged and normalized Ck 35 (DIN 17200) steel slide showed three distinct zones: a dark colored crystalline area, an incipient crack propagating into a far advanced, rubbed fracture surface, and a fine crystalline final break. Metallographic examination showed the dark incipient crack was present before the last heat treatment and was oxidized and decarburized prior to the conclusion of the annealing process. The crack ran perpendicular to the fiber, so it was not formed before or during forging. It was a thermal stress crack produced during flame cutting of the middle section of the slide. The initial crack acted as a sharp notch favoring the formation of the fatigue fracture which lead to the failure of the slide.

Radiant tubes that failed prematurely in an ethylene cracking furnace were analyzed to determine the cause of their early demise. The tubes were made from austenitic heat-resistant steel and cracked along their longitudinal axis. New and used tubes were compared using scanning electron microscopy, energy dispersive x-ray spectrometry, and mechanical property testing. This provided critical information and revealed that improper coking and decoking had removed the protective oxide layer (Cr 2 O 3 ) that normally prevents coke deposits from forming on exposed surfaces. Without this layer, coke readily accumulates on the surface of the tubes, fueling carbon diffusion into the metal and a corresponding degradation in microstructure and loss of ductility at high temperatures.

High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.

A brass elbow that formed one termination of a steam heating coil failed adjacent to the brazed connection after ten years of service. Chemical analysis showed that the elbow was made from a 60-40 CuZn brass containing 3% lead and 1% tin, a typical alloy used for the manufacture of components by the hot stamping process. Microscopic examination indicated failure from dezincification. The fact that the screwed end was not affected indicated that the trouble was not caused by the condensate, which flowed through the elbow, but originated from the water heated in the vessel. The helical mode of the cracking was probably due to the torsional stresses which would be imposed on the elbow by thermally induced movements of the coil in service.

High temperature corrosion may occur in numerous environments and is affected by factors such as temperature, alloy or protective coating composition, time, and gas composition. This article explains a number of potential degradation processes, namely, oxidation, carburization and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay coatings, thermal barrier coatings, and ceramic coatings.

Failures in boilers and other equipment taking place in power plants that use steam as the working fluid are discussed in this article. The discussion is mainly concerned with failures in Rankine cycle systems that use fossil fuels as the primary heat source. The general procedure and techniques followed in failure investigation of boilers and related equipment are discussed. The article is framed with an objective to provide systematic information on various damage mechanisms leading to the failure of boiler tubes, headers, and drums, supplemented by representative case studies for a greater understanding of the respective damage mechanism.

This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.

An investigation was conducted to better understand the time-dependent degradation of thermal barrier coated superalloy components in gas turbines. First-stage vanes are normally subjected to the highest gas velocities and temperatures during operation, and were thus the focus of the study. The samples that were analyzed had been operating at 1350 °C in a gas turbine at a combined-cycle generating plant. They were regenerated once, then used for different lengths of time. The investigation included chemical analysis, scanning electron microscopy, SEM/energy dispersive spectroscopy, and x-ray diffraction. It was shown that degradation is driven by chemical and mechanical differences, oxide growth, depletion, and recrystallization, the combined effect of which results in exfoliation, spallation, and mechanical thinning.

A broken exhaust valve from the cylinder of a motor car had a 30-mm disk diam and 8-mm stem diam. The site of the fracture was directly where the valve cone joined the cylindrical stem. Both the cone and the stem were heavily scaled in the vicinity of the fracture; in some parts the scale has flaked off. Furthermore, the rim of the disk was badly damaged by secondary mechanical action. The core of the valve had a very fine austenitic microstructure with precipitations of numerous granular and very fine, mostly rounded carbides and tine segregation bands. A hard alloy facing was welded on to the valve seat. Fracture was a consequence of fatigue corrosion cracking, itself strongly promoted by the presence of sulphur compounds. The origin of these corrosive sulphur compounds could not be explained.

This article reviews the applied aspects of creep and stress-rupture failures. It discusses the microstructural changes and bulk mechanical behavior of classical and nonclassical creep behavior. The article provides a description of microstructural changes and damage from creep deformation, including stress-rupture fractures. It also describes metallurgical instabilities, such as aging and carbide reactions, and evaluates the complex effects of creep-fatigue interaction. The article concludes with a discussion on thermal fatigue and creep fatigue failures.

Leaks developed at random locations in aluminum brass condenser tubes within the first year of operation of a steam condenser in a nuclear power plant. One failed tube underwent scanning electron microscopy surface examination and optical microscope metallography. It was determined that the tube failed from crevice corrosion under seawater deposits that had formed on the inner surface. Mechanical cleaning of the condenser tubes every 6 months and installation of intake screens of smaller mesh size were recommended.

Stainless steel liners (AISI type 321) used in bellows-type expansion joints in a duct assembly installed in a low-pressure nitrogen gas system failed in service. The duct assembly consisted of two expansion joints connected by a 32 cm (12 in.) OD pipe of ASTM A106 grade B steel. Elbows made of ASTM A234 grade B steel were attached to each end of the assembly, 180 deg apart. A 1.3 mm (0.050 in.) thick liner with an OD of 29 cm (11 in.) was welded inside each joint. The upstream ends were stable, but the downstream ends of the liners remained free, allowing the components to move with the expansion and contraction of the bellows. Investigation (visual inspection, hardness testing, and 30x fractographs) supported the conclusion that the liners failed in fatigue initiated at the intersection of the longitudinal weld forming the liner and the circumferential weld by which it attached to the bellows assembly. Recommendations included increasing the thickness of the liners from 1.3 to 1.9 mm (0.050 to 0.075 in.) in order to damp some of the stress-producing vibrations.

The principal types of elevated-temperature mechanical failure are creep and stress rupture, stress relaxation, low- and high-cycle fatigue, thermal fatigue, tension overload, and combinations of these, as modified by environment. This article briefly reviews the applied aspects of creep-related failures, where the mechanical strength of a material becomes limited by creep rather than by its elastic limit. The majority of information provided is applicable to metallic materials, and only general information regarding creep-related failures of polymeric materials is given. The article also reviews various factors related to creep behavior and associated failures of materials used in high-temperature applications. The complex effects of creep-fatigue interaction, microstructural changes during classical creep, and nondestructive creep damage assessment of metallic materials are also discussed. The article describes the fracture characteristics of stress rupture. Information on various metallurgical instabilities is also provided. The article presents a description of thermal-fatigue cracks, as distinguished from creep-rupture cracks.

Leakage was detected at the welds between stiffening plates and the pipe in a transfer line carrying butane and related petrochemical compounds. The line and reinforcing rings were of AISI 316 stainless steel, the pipe being of 508 mm diam and 6.25 mm wall thickness. The design temperature and pressure were 621 deg C and 2.75 kPa, respectively, while the operating conditions were 579 deg C and 1.03 kPa. The line was insulated. Failure occurred after approximately 90,000 h of operation, shutdowns being approximately two per annum. The cracking occurred at the toe of welds between the plates and the pipe. The creep damage failure was attributed to repeated relaxation cycles of very high thermal stresses of resulting from the periodic shutdowns, temperature fluctuations during service, or both. This failure emphasized the information available from an evaluation of the operative creep mechanism, namely grain boundary sliding, relating to the periodic nature of the loading, with high residual stresses being present.

This article provides an overview of the effects of various material- and process-related parameters on residual stress, distortion control, cracking, and microstructure/property relationships as they relate to various types of failure. It discusses phase transformations that occur during heat treating and describes the metallurgical sources of stress and distortion during heating and cooling. The article summarizes the effect of materials and the quench-process design on distortion and cracking and details the effect of cooling characteristics on residual stress and distortion. It also provides information on the methods of minimizing distortion and tempering. The article concludes with a discussion on the effect of heat treatment processes on microstructure/property-related failures.