After ten years of satisfactory operation, economizer-tube failures occurred in a large black liquor recovery boiler for a paper mill. The economizer contained 1320 finned tubes. Two fins ran longitudinally for most of the tube length and were attached by fillet welding on one side. The economizer tube leaks occurred at the end of the fin near the bottom of the economizer. A sample from a tube that had not failed showed heavy pitting attack on the inside of the tube, probably due to excess oxygen in the feedwater. Penetrant testing revealed numerous longitudinal cracks on the inside in the area of the fin tip. Cracking at the end of the fin-to-tube fillet weld was noted. The results indicate the failures were due to corrosion fatigue whose stresses were primarily thermally induced. A temporary solution included inspecting all tubes with shear-wave ultrasonics. Tubes with the most severe cracking were ground and repair welded. The square corners of the fins were trimmed back with a gradual taper so that expansion strains would be more gradually transferred to the tube surface. Water chemistry was closely evaluated and monitored, especially with regard to oxygen content.

Engineering plastics, as a general class of materials, are prone to the development of internal stresses which arise during processing or during servicing when parts are exposed to environments that impose deformation and/or temperature extremes. Thermal stresses are largely a consequence of high coefficients of thermal expansion and low thermal diffusivities. Although time-consuming techniques can be used to analyze thermal stresses, several useful qualitative tests are described in this article. The classification of internal stresses in plastic parts is covered. The article describes the effects of low thermal diffusivity and high thermal expansion properties, and the variation of mechanical properties with temperature. It discusses the combined effects of thermal stresses and orientation that result from processing conditions. The article also describes the effect of aging on properties of plastics. It explains the use of high-modulus graphite fibers in amorphous polymers.

A failure analysis was conducted on a flow-sensing device that had cracked while in service. The polysulfone sensor body cracked radially, adjacent to a molded-in steel insert. This article describes the investigative methods used to conduct the failure analysis. The techniques utilized included scanning electron microscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry, thermomechanical analysis, and melt flow rate determination. It was the conclusion of the investigation that the part failed via brittle fracture, with evidence also indicating low cycle fatigue associated with cyclic temperature changes from normal service. The design of the part and the material selection were significant contributing factors because of stresses induced during molding, physical aging of the amorphous polysulfone resin, and the substantial differential in coefficients of thermal expansion between the polysulfone and the mating steel insert.

A large diameter steel pipe reinforced by stiffening rings with saddle supports was subjected to thermal cycling as the system was started up, operated, and shut down. The pipe functioned as an emission control exhaust duct from a furnace and was designed originally using lengths of rolled and welded COR-TEN steel plate butt welded together on site. The pipe sustained local buckling and cracking, then fractured during the first five months of operation. Failure was due to low cycle fatigue and fast fracture caused by differential thermal expansion stresses. Thermal lag between the stiffening rings welded to the outside of the pipe and the pipe wall itself resulted in large radial and axial thermal stresses at the welds. Redundant tied down saddle supports in each segment of pipe between expansion joints restrained pipe arching due to circumferential temperature variations, producing large axial thermal bending stresses. Thermal cycling of the system initiated fatigue cracks at the stiffener rings. When the critical crack size was reached, fast fracture occurred. The system was redesigned by eliminating the redundant restraints and by modifying the stiffener rings to permit free radial thermal breathing of the pipe.

A return bend (made from ASTM A213, grade T11, ferritic steel) from a triolefin-unit heater ruptured after two years in service. The unit operated at 2410 kPa, with a hydrocarbon feed stream (85% propylene) entering at 260 to 290 deg C and leaving at 425 to 480 deg C. The fracture was found to terminate at the welds that joined the bend to the pipeline. A high concentration of both small and large inclusions was exhibited by the metallographic examination of the steel near the fracture. Branched cracks similar to those produced by stress corrosion of steel were observed in a section through the fireside edge of the fracture surface. Scale was observed over most of the crack path which acted as a stress raiser. The effect of the oxide was magnified during thermal cycles because of differential thermal expansion, with the steel having a greater expansion coefficient than the scale. It was recommended that material that is intended for critical applications where failure cannot be tolerated should be non-destructively examined.

This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.

The defects observed along weldings of stainless steel pipelines employed in marine environments were evidenced by metallographic and electrochemical examination. A compilation of cases on the effect of defective weldings, in addition to improper choice of stainless steel for water pipelines, lead to the conclusion that intercrystalline corrosion in steels involved precipitation of a surplus phase at grain boundaries. Intercrystalline corrosion in austenitic stainless steels due to precipitation of chromium carbides during conditions generated due to welding and ways to avoid the precipitation (including reduction of carbon content, appropriate heat treatment, cold work of steel, reduction of austenitic grain size and stabilizing elements) were described. The presence of microcracks due to highly localized heat concentrations with consequent thermal expansion and considerable shrinkages during cooling was investigated. The specimens were taken from various sources including transverse and longitudinal welding seam, sensitized areas and it was concluded appropriate material selection with respect to medium could control some corrosion processes.

The welds joining the liner and shell of a fluid catalytic cracking unit failed. The shell was made of ASTM A515 carbon steel welded with E7018 filler metal. The liner was made of type 405 stainless steel and was plug welded to the shell using ER309 and ER310 stainless steel filler metal. Fine cracks starting inside the weld zone and spreading outward through the weld and toward the surface were observed during examination. Decarburization and graphitization of the carbon steel at the interface was noted. The high carbon level was found to allow martensite to form eventually. The structure was found to be austenitic in the area where the grain-boundary precipitates appeared heaviest. The composition of the precipitates was analyzed using an electron microprobe to reveal presence of sulfur. Microstructural changes in the weld alloy at the interface were interpreted to be caused by dilution of the alloy and the presence of sulfur caused hot shortness. The necessary internal stress to produce extensive cracking was produced by the differential thermal expansion of the carbon and stainless steels. Periodic careful gouging of the affected areas followed by repair welding was recommended.

A deformed steel tube was received for failure analysis after buckling during a heat-treat operation. The tube was subjected to various metallurgical tests as well as nondestructive testing to confirm the presence of residual stresses. The microstructure of the tube was found to be homogenous and had no banded structure. However, x-ray diffraction analysis confirmed the presence of up to 6% retained austenite which likely caused the tube to buckle during the 910 °C heat treating procedure.

Corrosion failure occurred in a titanium clad tubesheet because of a corrosive tube-side gas-liquid mixture leaking through fatigue cracks in the seal welds at tube-to-tubesheet joints. The tubesheet was a carbon steel plate clad with titanium on the tube side face. The seal weld cracks were initiated by cyclic stress imposed by exchanger tubes. The gas-liquid mixture passed through cracks under tube-side pressure, resulting in severe corrosion of the steel backing plate. The failure started with the loosening of the expanded tube-to-tubesheet joints. Loose joints allowed the exchanger tubes to impose load on seal welds and the shell side cooling water entered the crevice between the tubesheet and the tubes. The cooling water in the crevice caused galvanic reaction and embrittlement of seal welds. Brittle crack opening and crack propagation in seal welds occurred due to the cyclic stress imposed by the tubes. The cyclic stress arised from the thermal cycling of the heat exchanger. The possible effects of material properties on the failure of the tubesheet are discussed.

This paper reviews several fatigue failures from the waterwall, superheater, and economizer portions of the boiler, their causes and how they were mitigated and monitored. Some cases required simple field modifications by cutting or welding, repair of existing controls, and/or changes in maintenance. Nondestructive inspections by visual, magnetic particle, ultrasonic, and radiographic methods for detecting and monitoring damage are discussed. These failures are presented to provide hindsight that will help others in increasing the success rate for anticipating and analyzing the remaining life of other units.

Stainless steel liners (AISI type 321) used in bellows-type expansion joints in a duct assembly installed in a low-pressure nitrogen gas system failed in service. The duct assembly consisted of two expansion joints connected by a 32 cm (12 in.) OD pipe of ASTM A106 grade B steel. Elbows made of ASTM A234 grade B steel were attached to each end of the assembly, 180 deg apart. A 1.3 mm (0.050 in.) thick liner with an OD of 29 cm (11 in.) was welded inside each joint. The upstream ends were stable, but the downstream ends of the liners remained free, allowing the components to move with the expansion and contraction of the bellows. Investigation (visual inspection, hardness testing, and 30x fractographs) supported the conclusion that the liners failed in fatigue initiated at the intersection of the longitudinal weld forming the liner and the circumferential weld by which it attached to the bellows assembly. Recommendations included increasing the thickness of the liners from 1.3 to 1.9 mm (0.050 to 0.075 in.) in order to damp some of the stress-producing vibrations.

A 2–3 mm thick electroformed nickel mold showed early cracking under thermal load cycles. To determine the root cause, investigators obtained monotonic and cyclic properties of electroformed nickel at various temperatures and identified possible fatigue mechanisms. With the help of finite element modeling, they analyzed the material as well as the design and in-service application of the mold. They discovered that overconstraining the mold, while it was in service, caused excessive thermal stresses which accelerated crack initiation and propagation. Investigators also proposed remedies to prevent additional failures.

Following leakage which developed within the furnace of a horizontal multi-tubular type boiler, examination revealed a series of cracks adjacent to the stiffening rings in the first plain furnace ring. The fire-side surface of the sample was coated with a layer of oxide scale. Microscopical examination of sections through the cracks showed them to be filled with oxide and to be of the multi-branched type, having blunt terminations. The general nature of the cracks was characteristic of cracking from thermal or corrosion fatigue, as results from the operation of varying stresses in an oxidizing or corrosive environment. The cracking in this particular case was due principally to the inordinately large gap between the components. Additionally, several of the sealing welds of the tubes to the back tube plate were cracked in a radial manner, and it would appear that in addition, abnormal thermal conditions may well have been experienced intermittently in service.

Several surface-mount chip resistor assemblies failed during monthly thermal shock testing and in the field. The resistor exhibited a failure mode characterized by a rise in resistance out of tolerance for the system. Representative samples from each step in the manufacturing process were selected for analysis, along with additional samples representing the various resistor failures. Visual examination revealed two different types of termination failures: total delamination and partial delamination. Electron probe microanalysis confirmed that the fracture occurred at the end of the termination. Transverse sections from each of the groups were examined metallographically. Consistent interfacial separation was noted. Fourier transform infrared and EDS analyses were also performed. It was concluded that low wraparound termination strength of the resistors had caused unacceptable increases in the resistance values, resulting in circuit nonperformance at inappropriate times. The low termination strength was attributed to deficient chip design for the intended materials and manufacturing process and exacerbated by the presence of polymeric contamination at the termination interface.

This article provides information on the development of finite element analysis (FEA) and describes the general-purpose applications of FEA software programs in structural and thermal, static and transient, and linear and nonlinear analyses. It discusses special-purpose finite element applications in piping and pressure vessel analysis, impact analysis, and microelectronics. The article describes the steps involved in the design process using the FEA. It concludes with two case histories that involve the use of FEA in failure analysis.

A 44.5 mm (1.75 in.) diam type 321 stainless steel seamless tube in a power-generating turbine failed after 19,000 h in service. The tube was used to carry a mixture of approximately 25% steam and 75% hot air. Three fractured pieces and part of the tube containing the mating fracture surface were examined. Both fractographic and metallographic features revealed that the failure was by thermal fatigue caused by the presence of biaxial thermal stresses on the inner surface of the tube. It was recommended that the steam and air be thoroughly mixed prior to entering the tube to decrease the temperature fluctuations of the inner surface.

Cracking occurred within the plastic jacket (injection molded from an impact-modified, 15% glass-fiber-reinforced PET resin.) of several assemblies used in a transportation application during an engineering testing regimen which involved cyclic thermal shock (exposing the parts to alternating temperatures of -40 and 180 deg C (-40 and 360 deg F)). Prior to molding, the resin had reportedly been dried at 135 deg C (275 deg F). The drying process usually lasted 6 h, but occasionally, the material was dried overnight. Comparison investigation (visual inspection, 20x SEM views, micro-FTIR, and analysis using DSC and TGA) with non-failed parts supported the conclusion that that the failure was via brittle fracture associated with the exertion of stresses that exceeded the strength of the resin as-molded caused by the disparity in the CTEs of the PET jacket and the mating steel sleeve. The drying process had exposed the resin to relatively high temperatures, which caused substantial molecular degradation, thus limiting the part's ability to withstand the stresses. The drying temperature was found to be significantly higher than the recommendation for the PET resin, and the testing itself exposed the parts to temperatures above the recognized limits for PET.

A design may be improvable without presenting an unacceptable risk related to safety or performance. However, design-related failures can result from an oversight in performing one of the major design activities or from a failure to balance the competing demands inherent to part design. This article focuses on design-related failures in products utilizing polymeric materials, and reviews important considerations of the design envelope of plastic parts. The article provides a non-exhaustive list and descriptions of design tools that can support the design process and the prevention of design-related failures. It also discusses the most common causes of design-related failures of plastic parts. The article can assist in both failure analysis and in the prevention of failures in which design may be a contributing factor or a root cause.