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surface properties
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Published: 15 May 2022
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006869
EISBN: 978-1-62708-395-9
... S increases with F N . In order to correlate material properties and the wear behavior of various composites, a model was developed ( Ref 23 ). As shown in Fig. 7 , surface deformation and wear mechanisms depend on the matrix’s hardness and fracture energy. When pressure P overcomes...
Abstract
Reinforced polymers (RPs) are widely used in structural, industrial, automotive, and engineering applications due to their ecofriendly nature and the potential to manipulate their properties. This article addresses the technical synthesis of RPs, referring to their tribological behavior, to provide insights into the contribution and interaction of influential parameters on the wear behavior of polymers. It provides a brief discussion on the effects of significant parameters on RP tribology. The article describes abrasive and adhesive wear and provides a theoretical synthesis of the literature regarding the wear mechanisms of RPs. It also describes the synthesis of abrasive wear failure of different types of RPs and highlights the contribution of these influential parameters. The article addresses the synthesis of adhesive wear failure of different types of RPs.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.conag.c0090965
EISBN: 978-1-62708-221-1
...-06, signifying minimum properties of 552 MPa (80 ksi) tensile strength, 379 MPa (55 ksi) yield strength, and 6% elongation. Investigation The upper frame supports the crusher bowl section and can be unevenly loaded during crushing. The fracture surface of the frame section received...
Abstract
The upper frame from a large cone crusher failed in severe service after an unspecified service duration. The ductile iron casting was identified as grade 80-55-06, signifying minimum properties of 552 MPa (80 ksi) tensile strength, 379 MPa (55 ksi) yield strength, and 6% elongation. Investigation (visual inspection, chemical analysis, unetched 30x images, and 2% nital etched 30x images) was difficult because the fracture surface of the frame section was obliterated by postfracture corrosion. Repeated attempts at cleaning using progressively stronger chemicals revealed that no telltale fracture morphology remained. However, the investigation supported the conclusion that the crusher frame failed via brittle overload fracture, likely due to excessive service stresses and substandard mechanical properties. Recommendations included additional quality-control measures to provide better spheroidal graphite morphology at the frame surface.
Book Chapter
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006939
EISBN: 978-1-62708-395-9
... fillers, flame retardants, antiaging additives, antistatics, plasticizers, antimicrobials, viscosity modifiers, colorants, heat stabilizers, impact modifiers, compatibilizers, and surface modifiers. This article is divided into five sections: mechanical property modifiers, physical property modifiers...
Abstract
Polymer materials are key building blocks of the modern world, commonly used in packaging, automobiles, building materials, electronics, telecommunications, and many other industries. These commercial applications of polymeric materials would not be possible without the use of additives. This article is divided into five sections: mechanical property modifiers, physical property modifiers, biological function modifiers, processing aids, and colorants. It describes three classes of additives that are used to inhibit biological activity, six classes of mechanical property modifiers, three classes of physical property modifiers, and two classes of both colorants and processing aids.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003549
EISBN: 978-1-62708-180-1
... corrosion-resistant properties to a passive surface film. The naturally occurring passive film is usually enhanced with immersion in a hot nitric acid solution or steam. For example, stainless steel surgical implants develop this passive layer when the implants are sterilized in steam. The exact nature...
Abstract
This article provides an overview of the electrochemical nature of corrosion and analyzes corrosion-related failures. It describes corrosion failure analysis and discusses corrective and preventive approaches to mitigate corrosion-related failures of metals. These include: change in the environment; change in the alloy or heat treatment; change in design; use of galvanic protection; use of inhibitors; use of nonmetallic coatings and liners; application of metallic coatings; use of surface treatments, thermal spray, or other surface modifications; corrosion monitoring; and preventive maintenance.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006761
EISBN: 978-1-62708-295-2
... affect material properties results. Material may have been tested prior to forming or other deformation. Subsequent coatings or surface modifications such as case hardening may have improved or degraded mechanical properties. Variations from one location to another due to local materials processing...
Abstract
Mechanical testing is an evaluative tool used by the failure analyst to collect data regarding the macro- and micromechanical properties of the materials being examined. This article provides information on a few important considerations regarding mechanical testing that the failure analyst must keep in mind. These considerations include the test location and orientation, the use of raw material certifications, the certifications potentially not representing the hardware, and the determination of valid test results. The article introduces the concepts of various mechanical testing techniques and discusses the advantages and limitations of each technique when used in failure analysis. The focus is on various types of static load testing, hardness testing, and impact testing. The testing types covered include uniaxial tension testing, uniaxial compression testing, bend testing, hardness testing, macroindentation hardness, microindentation hardness, and the impact toughness test.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003550
EISBN: 978-1-62708-180-1
... cracking mechanical properties plasticization polymer degradation polymeric materials rubber products salvation surface degradation swelling THE MECHANICAL PROPERTIES of polymeric materials are often segregated into short-term and long-term properties. The category of short-term properties...
Abstract
The article commences with an overview of short-term and long-term mechanical properties of polymeric materials. It discusses plasticization, solvation, and swelling in rubber products. The article further describes environmental stress cracking and degradation of polymers. It illustrates how surface degradation of a plain strain tension specimen alters the ductile brittle transition in polyethylene creep rupture. The article concludes with information on the effects of temperature on polymer performance.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001298
EISBN: 978-1-62708-215-0
... by acid etching. Post-plating baking operations subsequently reduced the fatigue strength of the spar. Chemical etching Fatigue strength Mechanical properties Rotor blades 7075-T7351 UNS A97075 Pitting corrosion Fatigue fracture Surface treatment related failures Background...
Abstract
A helicopter tail rotor blade spar failed in fatigue, allowing the outer section of the blade to separate in flight. The 7075-T7351 aluminum alloy blade had fiberglass pockets. The blade spar was a hollow “D” shape, and corrosion pits were present on the inner surface of the hollow spar A single corrosion pit, 0.38 mm (0.015 in.) deep, led to a fatigue failure of the spar The failure initiated on the pylon side of the blade. Dimensional analysis of the spar near the failure revealed measurements within engineering drawing tolerances. Though corrosion pitting was present, there was an absence of significant amounts of corrosion product and all of the pits were filled with corrosion-preventative primer. This indicated that the pitting occurred during spar manufacture, prior to the application of the primer The pitting resulted from multiple nickel plating and defective plating removal by acid etching. Post-plating baking operations subsequently reduced the fatigue strength of the spar.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006913
EISBN: 978-1-62708-395-9
... resistance or conductance is always involved in the measurement. The measured value is largely a property of the contamination that is present on the specimen at the time. However, the dielectric constant of the specimen influences the deposition of contaminants, and its surface characteristics affect...
Abstract
This article addresses electrical testing and characterization of plastics and presents a number of techniques for evaluating the electrical properties of insulating materials, with a special focus on plastics, accompanied by a list of the electrical properties of different types of plastics. It provides the reader with sufficient information to select the appropriate electrical test(s) for a specific application. The tests covered in this article are widely used in industry to determine the electrical properties of insulating materials, particularly plastics. The article lists and defines terms used in connection with testing and specification of plastics for electrical applications.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.aero.c9001708
EISBN: 978-1-62708-217-4
.... Care was taken to ensure that the test specimens removed were from the same location and in the same orientation as for the specimens removed from the broken blade. To determine strength and Charpy V-notch toughness properties, specimens were extracted from the surface location, as well as from...
Abstract
The paper describes the findings from a damaged propeller blade made from Mn-Ni-Al-bronze, commercially known as Superston 70 (ABS Type 5). The blade had broken at the 0.65 pitch radius location, and the fracture occurred in a brittle mode. The findings reported here point to two potential contributors to the propeller blade failure, viz., the presence of casting flaws at the low pressure side of the propeller blade and service stresses at this surface that reached approximately 400 MPa. This stress value exceeded the yield strength at the corresponding location of the unbroken blade by approximately 40%.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006867
EISBN: 978-1-62708-395-9
... reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface...
Abstract
With any polymeric material, chemical exposure may have one or more different effects. Some chemicals act as plasticizers, changing the polymer from one that is hard, stiff, and brittle to one which is softer, more flexible, and sometimes tougher. Often these chemicals can dissolve the polymer if they are present in large enough quantity and if the polymer is not crosslinked. Other chemicals can induce environmental stress cracking (ESC), an effect in which brittle fracture of a polymer will occur at a level of stress well below that required to cause failure in the absence of the ESC reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface embrittlement and temperature on polymer performance.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.homegoods.c0090424
EISBN: 978-1-62708-222-8
... Abstract A plastic bracket exhibited relatively brittle material properties, which ultimately led to catastrophic failure. The part had been injection molded from a medium-viscosity polycarbonate resin and had been in service for a short duration prior to the failure. Investigation (visual...
Abstract
A plastic bracket exhibited relatively brittle material properties, which ultimately led to catastrophic failure. The part had been injection molded from a medium-viscosity polycarbonate resin and had been in service for a short duration prior to the failure. Investigation (visual inspection and analysis using micro-FTIR in the ATR mode) revealed the spectrum showed changes in the relative intensities of several bands, as compared to the results representing the base material. A spectral subtraction was performed, and the results produced a good match with diphenyl carbonate, which is a common breakdown product produced during the decomposition of polycarbonate. The conclusion was that the most likely cause of the molecular degradation was improper drying and/or exposure to excessive heat during the injection molding process that in turn caused the material degradation.
Series: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001079
EISBN: 978-1-62708-214-3
... similar to the rotor in question, the fracture toughness, K Ic , was conservatively estimated to be about 39 MPa m (35 ksi in. ). This property was nonexistent at the time of rotor manufacture and hence was never previously measured. Assuming that the observed surface flaws were cracks...
Abstract
Numerous flaws were detected in a steam turbine rotor during a scheduled inspection and maintenance outage. A fracture-mechanics-based analysis of the flaws showed that the rotor could not be safely returned to service. Material, samples from the bore were analyzed to evaluate the actual mechanical properties and to determine the metallurgical cause of the observed indications. Samples were examined in a scanning electron microscope and subjected to chemical analysis and several mechanical property tests, including tensile, Charpy V-notch impact, and fracture toughness. The material was found to be a typical Cr-Mo-V steel, and it met the property requirements. No evidence of temper embrittlement was found. The analyses showed that the observed flaws were present in the original forging and attributed them to lack of ingot consolidation. A series of actions, including overboring of the rotor to remove indications close to the surface and revision of starting procedures, were implemented to extend the remaining life of the rotor and ensure its fitness for continued service.
Book Chapter
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006937
EISBN: 978-1-62708-395-9
... Abstract Optical testing of plastics includes the characterization of materials and the analysis of optical components. If a material is tested for transmission, haze, yellowness, and refractive index, the knowledge of its optical properties is nearly complete. For optical components, surface...
Abstract
Optical testing of plastics includes the characterization of materials and the analysis of optical components. If a material is tested for transmission, haze, yellowness, and refractive index, the knowledge of its optical properties is nearly complete. For optical components, surface irregularity, birefringence, and internal contamination must also be considered. These characteristics are a function of the material and the fabrication method. Gloss and color also are affected by the base material and measured as optical properties.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c9001685
EISBN: 978-1-62708-235-8
... strain rates. These results, which are shown in Table 2 , showed a 50% reduction in elongation in the notched specimens with no appreciable effect on strength. Fig. 7 Geometry of notch machined into tensile specimen to simulate surface defect. Effect of Notch on Mechanical Properties...
Abstract
The U-0.8wt%Ti alloy is often used in weapon applications where high strength and fairly good ductility are necessary. Components are immersion quenched in water from the gamma phase to produce a martensitic structure that is amenable to aging. Undesirable conditions occur when a component occasionally cracks during the quenching process, and when tensile specimens fail prematurely during mechanical testing. These two failures prompted an investigative analysis and a series of studies to determine the causes of the cracking and erratic behavior observed in this alloy. Quench-related failures whereby components that cracked either during or immediately after the heat treatment/quenching operation were sectioned for metallographic examination of the microstructure to examine the degree of phase transformation. Examination of premature tensile specimen failures by scanning electron microscopy and X-ray imaging of fracture surfaces revealed pockets of inclusions at the crack origins. In addition, tests were conducted to evaluate the detrimental effects of internal hydrogen on ductility and crack initiation in this alloy.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c9001908
EISBN: 978-1-62708-235-8
... of these components exhibited shrinkage cavities and gas holes, and most failed to meet the required mechanical properties. Effect of Manufacturing Defects on Performance Heat checks are most often located on surfaces corresponding to areas in the die that are subject to high thermal stresses or where...
Abstract
Cluster bomb tailcone assemblies each containing two aluminum die-cast components were rejected because of the poor surface condition of the die castings. Numerous heat checks were found on the surfaces of the tailcones and radiographic inspection revealed inclusions, gas holes, and shrinkage defects in the castings. Most of the components failed to meet required mechanical properties because of these casting defects.
Image
Published: 01 January 2002
Fig. 12 Generic types of transfer wear behavior when semicrystalline polymers are slid on a hard smooth surface. In most of the cases there is a formation of transfer layer on the counterface though the shear, and adhesive properties of the transfer films will vary depending upon
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Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006935
EISBN: 978-1-62708-395-9
..., a microwave cooking dish would have the critical properties of not being affected by microwaves, not tainting hot food, and not being softened or distorted by contact with hot food. Desirable properties would be dishwashing and freezer temperature resistance, nonstick capabilities, an easily cleaned surface...
Abstract
Manufacturing process selection is a critical step in plastic product design. The article provides an overview of the functional requirements that a part must fulfil before process selection is attempted. A brief discussion on the effects of individual thermoplastic and thermosetting processes on plastic parts and the material properties is presented. The article presents process effects on molecular orientation. It also illustrates the thinking that goes into the selection of processes for size, shape, and design factors. Finally, the article describes how various processes handle reinforcement.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003571
EISBN: 978-1-62708-180-1
... the shear, and adhesive properties of the transfer films will vary depending upon the mechanical properties of the polymer and the surface topography of the counterface. Reprinted with permission from Ref 1 Early studies on the friction and wear of thermoplastics was motivated by the prospect...
Abstract
Plastics or polymers are used in a variety of engineering and nonengineering applications where they are subjected to surface damage and wear. This article discusses the classification of polymer wear mechanisms based on the methodologies of defining the types of wear. The first classification is based on the two-term model that divides wear mechanisms into interfacial and bulk or cohesive. The second is based on the perceived wear mechanism. The third classification is specific to polymers and draws the distinction based on mechanical properties of polymers. In this classification, wear study is separated as elastomers, thermosets, glassy thermoplastics, and semicrystalline thermoplastics. The article describes the effects of environment and lubricant on the wear failures of polymers. It presents a case study on nylon as a tribological material. The article explains the wear failure of an antifriction bearing, a nylon driving gear, and a polyoxymethylene gear wheel.
Image
Published: 15 May 2022
Fig. 11 Generic types of transfer wear behavior when semicrystalline polymers are slid on a hard, smooth surface. In most cases, there is a formation of a transfer layer on the counterface, although the shear and adhesive properties of the transfer films will vary depending on the mechanical
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