A pressure vessel failed causing an external fire on a nine-story coke gasifier in a refinery power plant. An investigation revealed that the failure began as cracking in the gasifier internals, which led to bulging and stress rupture of the vessel shell, and the escape of hot syngas, setting off the fire. The failure mechanisms include stress relaxation cracking of a large diameter Incoloy 825 tube, stress rupture of a 4.65 in. thick chromium steel shell wall, and the oxidation of chromium steel exposed to hot syngas. The gasifier process and operating conditions that contributed to the high-temperature degradation were also analyzed and are discussed.

This article reviews the applied aspects of creep and stress-rupture failures. It discusses the microstructural changes and bulk mechanical behavior of classical and nonclassical creep behavior. The article provides a description of microstructural changes and damage from creep deformation, including stress-rupture fractures. It also describes metallurgical instabilities, such as aging and carbide reactions, and evaluates the complex effects of creep-fatigue interaction. The article concludes with a discussion on thermal fatigue and creep fatigue failures.

This article focuses primarily on what an analyst should know about applying X-ray diffraction (XRD) residual stress measurement techniques to failure analysis. Discussions are extended to the description of ways in which XRD can be applied to the characterization of residual stresses in a component or assembly. The article describes the steps required to calibrate instrumentation and to validate stress measurement results. It presents a practical approach to sample selection and specimen preparation, measurement location selection, and measurement depth selection, as well as an outline on measurement validation. The article also provides information on stress-corrosion cracking and corrosion fatigue. The importance of residual stress in fatigue is described with examples. The article explains the effects of heat treatment and manufacturing processes on residual stress. It concludes with a section on the XRD stress measurements in multiphase materials and composites and in locations of stress concentration.

This article commences with a discussion on the characteristics of stress-corrosion cracking (SCC) and describes crack initiation and propagation during SCC. It reviews the various mechanisms of SCC and addresses electrochemical and stress-sorption theories. The article explains the SCC, which occurs due to welding, metalworking process, and stress concentration, including options for investigation and corrective measures. It describes the sources of stresses in service and the effect of composition and metal structure on the susceptibility of SCC. The article provides information on specific ions and substances, service environments, and preservice environments responsible for SCC. It details the analysis of SCC failures, which include on-site examination, sampling, observation of fracture surface characteristics, macroscopic examination, microscopic examination, chemical analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium.

This article describes the underlying fundamentals, applications, the relevance and necessity of performing proper stress analysis in conducting a failure analysis. It presents an introduction to the stress analysis of bodies containing crack-like imperfections and the topic of fracture mechanics. The fracture mechanics approach is an important part of stress analysis at the tips of sharp cracks or discontinuities. The article reviews fracture mechanics concepts, including linear elastic fracture mechanics, elastic-plastic fracture mechanics, and subcritical fracture mechanics. It also provides information on the applications of fracture mechanics in failure analysis.

A deformed steel tube was received for failure analysis after buckling during a heat-treat operation. The tube was subjected to various metallurgical tests as well as nondestructive testing to confirm the presence of residual stresses. The microstructure of the tube was found to be homogenous and had no banded structure. However, x-ray diffraction analysis confirmed the presence of up to 6% retained austenite which likely caused the tube to buckle during the 910 °C heat treating procedure.

Copper electrical feedthrough pins used in a bolting application in a refrigeration compressor had functioned without failure for years of production and thousands of units. When some of the pins began to fail, an investigation was conducted to determine the cause. Visual examination revealed that the observed fractures were mixed brittle intergranular with ductile microvoid dimples. An extensive analysis of failed samples combined with a process of elimination indicated that the fractures were due to stress-corrosion cracking caused by an unidentified chemical species within the sealed compressor chamber. A unique combination of applied stress, residual stress, stress riser, and grain size helped isolate the failure mechanism to a single production lot of material.

A group of control valves that regulate production in a field of sour gas wellheads performed satisfactorily for three years before pits and cracks were detected during an inspection. One of the valves was examined using chemical and microstructural analysis to determine the cause of failure and provide preventive measures. The valve body was made of A216-WCC cast carbon steel. Its inner surface was covered with cracks stemming from surface pits. Investigators concluded that the failure was caused by a combination of hydrogen-induced corrosion cracking and sulfide stress-corrosion cracking. Based on test data and cost, A217-WC9 cast Cr–Mo steel would be a better alloy for the application.

Nineteen out of 26 bolts in a multistage water pump corroded and cracked after a short time in a severe working environment containing saline water, CO 2 , and H 2 S. The failed bolts and intact nuts were to be made from a special type of stainless steel as per ASTM A 193 B8S and A 194. However, the investigation (which included visual, macroscopic, metallographic, SEM, and chemical analysis) showed that austenitic stainless steel and a nickel-base alloy were used instead. The unspecified materials are more prone to corrosion, particularly galvanic corrosion, which proved to be the primary failure mechanism in the areas of the bolts directly exposed to the working environment. Corrosion damage on surfaces facing away from the work environment was caused primarily by chloride stress-corrosion cracking, aided by loose fitting threads. Thread gaps constitute a crevice where an aggressive chemistry is allowed to develop and attack local surfaces.

Small paddles used to mix pulp had experienced a high incidence of breakage through the shafts. In some of the shanks, shrinkage was found relatively close to the surface where threads had been cut all the length of the shaft. Chemistries were within normal CF-8M ranges. Metallography showed the parts to be correctly heat treated. Cross sections of several of the parts showed pitting corrosion, and beneath the pits, stress-corrosion cracks in areas where the shafts had been bent during use. All the samples showed deep SCC in the areas where bending had occurred. In several cases, centerline shrinkage from inadequate risering had decreased life by reducing the cross-sectional area. Type CF-8M is not resistant to chloride SCC where the chloride concentration is considerable. The biggest problem was the bending of these parts. Deformed material with high residual stresses would always be susceptible to SCC. Redesign to lower stresses was essential. In addition, change to a high-strength duplex stainless steel with its higher strength and greater resistance to chlorides was recommended. Finally, the part must be adequately risered to produce solid shanks free from shrinkage.

A CF-8M (cast type 316) neck liner or manway was removed from the top of a digester vessel. Repeated attempts to repair the part in the field during its life cycle of many years had failed to keep the unit from leaking. The casting was a CF-8M modified with the molybdenum level at the top end of the range. The plate was standard 317L material. The filler metal was type 316, although marginal in molybdenum content. Investigation (visual inspection, chemical analysis, micrographs, and metallographic examination) supported the conclusion that the damage to the neck liner was due to Cl-SCC in an area of debris buildup. It appeared the original casting suffered SCC in a low-oxygen area high in chlorides from repeated wet/dry cycles where there was a buildup of debris. Recommendations included redesigning the neck liner to eliminate the abrupt change where there was debris buildup. If redesign was impossible, an alloy more resistant to Cl-SCC, such as a duplex stainless steel or a high-molybdenum (4 to 6%) austenitic stainless steel, should be used.

Several air heat exchangers failed in service in a pulp and paper operation. The tubes were made from AISI 316 stainless steel with an extruded aluminum fin mechanically bonded to the outside. Originally, the failures were blamed on poor tube to header welds. The units were sent back to the manufacturer for repair. Some of the units failed the hydrostatic test after they were repaired. Microscopic examination revealed the presence of branched transgranular cracks characteristic of stress-corrosion cracking. Only some of the tubes failed and these did so by stress-corrosion cracking. The most probable primary cause of the stress-corrosion cracking was local high residual stresses indicated by the areas of high hardness in the tubes. Low halogens in the water and airborne corrodents found normally in a pulp and paper mill were all that were required in the presence of high residual stresses in the tubes to initiate stress-corrosion cracking. Use of a low-carbon grade of stainless steel such as 316L was recommended to facilitate formation of the tube without producing excessive residual stresses. It was recommended also that failed units be segregated until it can be determined if the failure was related to operating pressure or some other unique cause.

The Pandia digester is a long cylindrical vessel which uses alkaline sulfite liquor to cook sawdust for pulping. The inlet cone was fabricated from AISI 304L stainless steel with E308 welds. Typical liquor concentration was approximately 80% NaOH, 20% Na2SO3 with chloride concentrations at 2 grams per liter. The operating pressures in the inlet cone were up to 1.2 MN/sq m (170 psig). The inlet cone had developed leaks within a year of service. Liquid penetrant inspection showed significant through-wall cracking near the fillet welds joining the bottom flange and side wall and the butt welds. Metallographic specimens were prepared from the welds to examine the microstructure and nature of the cracks. The cooking liquor at the inlet cone contained over ppm chlorides and was aggressive to 304 stainless steel. The cracking was identified as chloride-induced SCC. The inlet cone was replaced with an Inconel clad carbon steel inlet cone to combat the SCC.

A falling film black liquor evaporator consisted of flat twin plate heat exchangers and was used to increase black liquor solids content prior to its burning in the recovery boiler. Several plate heat exchangers were fabricated of AISI type 316L stainless steel by electric resistance welding. Cracks initiated at the inside surface of the welded areas and penetrated through the wall thickness. In several locations, the weld fractured and the plates separated with significant spring back, indicative of high residual stresses attributed to fabrication and weld procedures. The cracks had extended radially from the electric resistant weld into the base metal. Metallographic examination revealed the cracks were transgranular and branching, characteristic of SCC in austenitic stainless steels. The fracture surfaces had a brittle cleavage-like appearance, typical of SCC in austenitic stainless steels. Chlorides in the service environment were a contributory factor. The primary factor causing SCC localized at the electric resistant welds was substantial residual stresses as a result of fabrication procedures. It was recommended that the heat exchanger plates be subjected to stress-relief heat treatment following fabrication and welding.

An ASTM A 504 carbon steel railway car wheel that was used on a train in a metropolitan railway system failed during service, causing derailment. The wheel was completely fractured from rim to hub. Macrofractography of the fracture surface showed road grime, indicating that the crack had existed for a considerable time prior to derailment and initiated in the flange. Failure propagated from the flange across the rim and down the plate to the bore of the hub. Two zones that exhibited definite signs of heating were observed. The fracture initiation site was typical of fatigue fracture. No defects were found that could have contributed to failure. The wheel conformed to the chemical, microstructural, and hardness requirements for class A wheels. Failure was attributed to repeated severe heating and cooling of the rim and flange due to brake locking or misapplication of the hand brake. It was recommended that the brake system on the car be examined and replaced if necessary.

An arsenical admiralty brass (UNS C44300) finned tube in a generator air cooler unit at a hydroelectric power station failed. The unit had been in operation for approximately 49,000 h. Stereomicroscopic examination revealed two small transverse cracks that were within a few millimeters of the tube end, with one being a through-wall crack. Metallographic examination of sections containing the cracks showed branching secondary cracks and a transgranular cracking mode. The cracks appeared to initiate in pits. EDS analysis of a friable deposit found on the inside diameter of the tube and XRD analysis of crystalline compounds in the deposit indicated the possible presence of ammonia. Failure was attributed to stress-corrosion cracking resulting from ammonia in the cooling water. It was recommended that an alternate tube material, such as a 70Cu-30Ni alloy or a titanium alloy, be used.

Two AISI type 316 stainless steel dished ends failed through the formation of intergranular stress-corrosion cracks (IGSCC) within a few months of service. The dished ends failed in the straight portions near the circumferential welds that joined the ends to the cylindrical portions of the vessel. Both dished ends were manufactured from the same batch and were supplied by the same manufacturer One of the dished ends had been exposed to sodium at 550 deg C (1020 deg F) for 500 h before failure due to sodium leakage was detected. The other dished end was used to fabricate a second vessel that was kept in storage for 1 year Clear evidence of sensitization was found in areas where IGSCC occurred. Sensitization was extensive in the dished end that had been exposed to sodium at high temperature, and it occurred in a narrow band similar to that typical of weld decay in the dished end that had been kept in storage. Solution annealing was recommended to relieve residual stress, thereby reducing the probability of failure. It was also recommended that the carbon content of the steel be lowered, i.e., that a 316L grade be used.

Several type 304L stainless steel dished ends used in the fabrication of cylindrical vessels developed extensive cracking during storage. All of the dished ends had been procured from a single manufacturer and belonged to the same batch. When examined visually, several rust marks were observed, indicating contamination by rusted carbon steel particles. Liquid penetrant testing was used to determine the extent of the cracks, and in situ metallographic analysis was performed over the cracked region. The morphology of the cracks was indicative of transgranular stress-corrosion cracking (TGSCC). Conditions promoting the occurrence of the TGSCC included significant tensile stresses on the inside of the dished ends, the presence of surface contamination by iron due to poor handling practice using carbon steel implements, and storage in a coastal environment with an average temperature of 25 to 32 deg C (77 to 90 deg F), an average humidity ranging from 70 to 80%, and an atmospheric NaCl content ranging from 8 to 45 mg/m2 /day. Recommendations preventing further occurrence of the situation were strict avoidance of the use of carbon steel handling implements, strict avoidance of cleaning practices that cause long-term exposure to chlorine-containing cleaning fluid, and solution annealing of the dished ends at 1050 deg C (1920 deg F) for 1 h followed by water quenching to relieve residual stresses.

Original carbon steel and subsequent replacement austenitic stainless steel superheater tube U-bend failures occurred in a waste heat boiler. The carbon steel tubes had experienced metal wastage in the form of caustic corrosion gouging, while the stainless steel tubes failed by caustic-induced stress-corrosion cracking. Sodium was detected by EDS in the internal deposits and the base of a gouge in a carbon steel tube and in the internal deposits of the stainless steel tube. The sodium probably formed sodium hydroxide with carryover moisture and caused the gouging, which was further aggravated by the presence of silicon and sulfur (silicates and sulfates). It was recommended that the tubes be replaced with Inconel 600 or 601, as a practical option until the carryover problem could be solved.

A type 430Ti stainless steel flue gas expansion joint cracked because of caustic-induced stress-corrosion cracking. Energy-dispersive X-ray spectroscope analysis of the fracture surface deposits revealed the presence of sodium and potassium—caustics in hydroxide form. Primary fracture surfaces were all similar in appearance, and a primary crack origin could not be identified. A secondary crack brought to fracture in the laboratory showed brittle, cleavage features rather than classic, tensile overload features. This suggested that the material was embrittled.