A large portion of the four-hole Lane plate disintegrated and consisted mainly of corrosion products after remaining in the body for 26 years. Transformation structures and carbides were exhibited by the plate which was made from chromium steel. Minimal corrosion was exhibited by the soft austenitic 304 stainless steel used to make the screws. The corrosion products of the plate were revealed by microprobe analysis to impregnate the surrounding tissues. Improper material selection was concluded to be the reason for the general corrosion behavior.

Evidence of destructive pitting on the gear teeth (AMS 6263 steel) in the area of the pitchline was exhibited by an idler gear for the generator drive of an aircraft engine following test-stand engine testing. The case hardness was investigated to be lower than specified and it was suggested that it had resulted from surface defects. A decarburized surface layer and subsurface oxidation in the vicinity of pitting were revealed by metallographic examination of the 2% nital etched gear tooth sample. It was concluded that pitting had resulted as a combination of both the defects. The causes for the defects were reported based on previous investigation of heat treatment facilities. Oxide layer was caused by inadequate purging of air before carburization while decarburization was attributed to defects in the copper plating applied to the gear for its protection during austenitizing in an exothermic atmosphere. It was recommended that steps be taken during heat treatment to ensure neither of the two occurred.

Alloy 430 stainless steel tube-to-header welds failed in a heat recovery steam generator (HRSG) within one year of commissioning. The HRSG was in a combined cycle, gas-fired, combustion turbine electric power plant. Alloy 430, a 17% Cr ferritic stainless steel, was selected because of its resistance to chloride and sulfuric acid dewpoint corrosion under conditions potentially present in the HRSG low-pressure feedwater economizer. Intergranular corrosion and cracking were found in the weld metal and heat-affected zones. The hardness in these regions was up to 35 HRC, and the weld had received a postweld heat treatment (PWHT). Metallographic examination revealed that the corroded areas contained undertempered martensite. Fully tempered weld areas with a hardness of 93 HRB were not attacked. No evidence of corrosion fatigue was found. Uneven temperature control during PWHT was the most likely cause of failure.

A weld that attached the head to the shell of a preheater containing steam at 1.4 MPa (200 psi) and was used in the manufacture of paper cracked in service. The original joint contained a 6.4 by 50 mm backing ring that had been tack welded to the inside surface of the shell in a position to project beyond the fully beveled top edge of the shell. The projecting edge of the ring fitted against a deep undercut on the inner corner of the rim of the head. The internal 90-deg angle in this undercut was sharp, with almost no fillet. A bevel from the lower edge of the undercut to the outside of the head completed the groove for the circumferential attachment weld. Investigation (visual inspection and actual size views etched in hot 50% hydrochloric acid) supported the conclusion that cracking occurred in the HAZ in the head of the original design, originating in the sharp corner of the undercut, which was an inherent stress raiser. Recommendations included revised joint design to ensure full root penetration.

Welded steel storage vessels used to hold mildly alkaline solution were produced in exactly the same manner from deep-drawn aluminum-killed SAE 1006 low-carbon steel sheet. After the cylindrical shell was drawn, a top low-carbon steel closure was welded to the inside diameter. The containers were then filled with the slightly alkaline solution, pressurized, and allowed to stand under ambient conditions. A small number, less than 1%, were returned because they began to leak in service. Inspection revealed general corrosion and pitting on the inner surfaces. However, other tanks that experienced the same service conditions developed no corrosion. Corrosion was linked to forming defects that provided sites for localized corrosion, and to lack of steam drying after cleaning, which increased susceptibility to general corrosion.

This article briefly reviews the various metallurgical or environmental factors that cause a weakening of the grain boundaries and, in turn, influence the occurrence of intergranular (IG) fractures. It discusses the mechanisms of IG fractures, including the dimpled IG fracture, the IG brittle fracture, and the IG fatigue fracture. The article describes some typical embrittlement mechanisms that cause the IG fracture of steels.

A number of failures involving carbon and alloy steels were analyzed to assess the effects of inclusions and their influence on mechanical properties. Inclusions, including brittle oxides and more ductile manganese sulfides (MnS), affect fatigue endurance limit, fatigue crack propagation rates, fracture toughness, notch toughness, and transverse tensile properties, and do so in an anisotropic manner with respect to rolling direction. Significant property anisotropy has been documented in the failures investigated, providing evidence that designers failed to account for it. Typical fracture morphologies observed in such cases and metallographic appearances of MnS-containing materials are illustrated.

This article briefly reviews the factors that influence the occurrence of intergranular (IG) fractures. Because the appearance of IG fractures is often very similar, the principal focus is placed on the various metallurgical or environmental factors that cause grain boundaries to become the preferred path of crack growth. The article describes in more detail some typical mechanisms that cause IG fracture. It discusses the causes and effects of IG brittle cracking, dimpled IG fracture, IG fatigue, hydrogen embrittlement, and IG stress-corrosion cracking. The article presents a case history on IG fracture of steam generator tubes, where a lowering of the operating temperature was proposed to reduce failures.

An oxygen line that was part of a mobile, truck -mounted oxygen-acetylene welding unit exploded in service. Analysis revealed that the failure occurred at the flexible hose-to-valve connection. It was further determined that a steel adapter had been installed at the point of failure to make the connection. Use of the adapter which joined with a brass nipple, created an unacceptable dissimilar metal joint. The steel also provided a source for the generation of sparks. Loctite, a hydrocarbon sealant that is highly flammable and explosive in contact with pure oxygen, had been used to seal the threaded joint. It was recommended that only brass fittings be used to assemble removable joints and that use of washers, sealants, and hydrocarbon lubricants be strictly avoided.

Hydrogen damage is a term used to designate a number of processes in metals by which the load-carrying capacity of the metal is reduced due to the presence of hydrogen. This article introduces the general forms of hydrogen damage and provides an overview of the different types of hydrogen damage in all the major commercial alloy systems. It covers the broader topic of hydrogen damage, which can be quite complex and technical in nature. The article focuses on failure analysis where hydrogen embrittlement of a steel component is suspected. It provides practical advice for the failure analysis practitioner or for someone who is contemplating procurement of a cost-effective failure analysis of commodity-grade components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also provided.

This article provides an overview of the classification of hydrogen damage. Some specific types of the damage are hydrogen embrittlement, hydrogen-induced blistering, cracking from precipitation of internal hydrogen, hydrogen attack, and cracking from hydride formation. The article focuses on the types of hydrogen embrittlement that occur in all the major commercial metal and alloy systems, including stainless steels, nickel-base alloys, aluminum and aluminum alloys, titanium and titanium alloys, copper and copper alloys, and transition and refractory metals. The specific types of hydrogen embrittlement discussed include internal reversible hydrogen embrittlement, hydrogen environment embrittlement, and hydrogen reaction embrittlement. The article describes preservice and early-service fractures of commodity-grade steel components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also reviewed.

A cast dragline bucket tooth failed by fracturing after a short time in service. The tooth was made of medium-carbon low-alloy steel heat treated to a hardness of 555 HRB. The fracture surface was covered with chevron marks. These converged at several sites on the surface of the tooth. A hardfacing deposit was located at each of these sites. Visual inspection of the hardfacing deposits revealed numerous transverse cracks, characteristic of many types of hardfacing. This failure was caused by cracks present in hardfacing deposits that had been applied to the ultrahigh-strength steel tooth. Given the small critical crack sizes characteristic of ultrahigh-strength materials, it is generally unwise to weld them. It is particularly inadvisable to hardface ultrahigh-strength steel parts with hard, brittle, crack-prone materials when high service stresses will be encountered. The operators of the dragline bucket were warned against further hardfacing of these teeth.

A broken cross-recessed die was examined. Examination of the unetched, polished section for impurities revealed several coarse streaks of slag. The purity did not therefore correspond to the requirements set for a high speed tool steel of the given theoretical quality DMo 5. After etching with 5% nital the polished surface exhibited a pronounced, easily-visible, fibrous structure. Microscopic examination revealed that this etch pattern was produced by marked segregation bands. The very unfavorable structure for a high speed steel tool of these dimensions and subject to such stresses together with the low purity favored the fracture of the tool.

Beveled weld-joint V-sections were fabricated to connect inlet and outlet sections of tubes in a type 347 stainless steel heat exchanger for a nitric acid concentrator. Each V-section was permanently marked with the tube numbers by a small electric-arc pencil. After one to two years of service, multiple leaks were observed in the heat-exchanger tubes. Investigation supported the conclusion that the corrosion occurred at two general locations: the stop point of the welds used to connect the inlet and outlet legs of the heat exchanger, and the stop points on the identifying numerals. Recommendations included replaced the material with type 304L stainless steel.

Routine inspections of a carbon steel wood pulp digester revealed a sharply increasing number of cracks in the overlay metal on the internal surface of the digester after 1 and 2 years of service. The weld overlay was composed of type 309 stainless steel on the top fourth of the digester and of a proprietary high-nickel material on the bottom three-fourths. Examination revealed three distinct modes of deterioration. General corrosion was linked to the use of unspecified overlay metal. Cracking resulted during installation from the use of a material susceptible to hot cracking. Deep corrosion fissures then developed at hot crack sites as a result of crevice corrosion. Use of the appropriate overlay material was recommended.

Critical heat exchanger components are usually manufactured from durable steels, such as stainless steel, which exhibit good strength and corrosion resistance. Failure of a heat exchanger occurred due to specification of a plain carbon steel that did not survive service in the SO2 vapor environment. However, failure analysis showed that cavitation erosion was the responsible failure mechanism, not corrosion as might be expected.

An automotive front-wheel outer angular-contact ball bearing generated considerable noise shortly after delivery of the vehicle. The inner and outer rings were made of seamless cold-drawn 52100 steel tubing, the balls were forged from 52100 steel, and the retainer was stamped from 1008 steel strip. The inner ring, outer ring, and balls were austenitized at 845 deg C (about 1550 deg F), oil quenched, and tempered to a hardness of 60 to 64 HRC. Investigation (visual inspection) supported the conclusion that failure was caused by fretting due to vibration of the stationary vehicle position without bearing rotation. Recommendations included improving methods of securing the vehicle during transportation to eliminate vibrations.

A 150 mm (6 in.) schedule 80S type 304 stainless steel pipe (11 mm, or 0.432 in., wall thickness), which had served as an equalizer line in the primary loop of a pressurized-water reactor, was found to contain several circumferential cracks 50 to 100 mm (2 to 4 in.) long. Two of these cracks, which had penetrated the pipe wall, were responsible for leaks detected in a hydrostatic test performed during a general inspection after seven years of service. Investigation (visual inspection, visual and ultrasonic weld examination, water analysis, and chemical analysis) supported the conclusion that the failure was caused by SCC due to stress, sensitization, and environment. Recommendations included replacing all pipe sections and installing them using low-heat-input, multiple-pass welding procedures.

Gross wastage and embrittlement were observed in plain carbon steel desuperheaters in five new Naval power plants. The gross wastage could be duplicated in laboratory bomb tests using sodium hydroxide solutions and was concluded to be caused by free caustic concentrated by high heat flux. The embrittlement was shown to be caused by the flow of corrosion generated hydrogen which converted the cementite to methane which nucleated voids in the steel. A thermodynamic estimate indicated that a small amount of chromium would stabilize the carbides against decomposition by hydrogen in this temperature range, and laboratory tests with 2-14% Cr steel verified this.