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spherical carbides
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Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.steel.c9001245
EISBN: 978-1-62708-232-7
... acicular martensite with fine spherical carbide inclusions ( Fig. 6 ) up to a depth of 5–6 mm. The martensite indicated no signs of tempering treatment. Adjoining the purely martensitic peripheral zone was a transition zone with increasing amount of bainite and pearlite from the exterior to the interior...
Abstract
A working roll of 210 mm diam and 500 mm face length was examined because of shell-shaped fractures. The roll consisted of Fe-0.83C-1.6Cr steel. The chromium content was low for a roll of this diam. The crack origin was located about 10 mm under the roil face. Surface hardness (HV1) of 900 kp/sq mm was exceptionally high corresponding to the martensitic peripheral structure. An untempered piece with such a thick cross section and a hardened peripheral zone with such high hardness must have high residual stresses that culminate in the transition zone. Therefore it must be very sensitive against additional stresses, be these of a mechanical or thermal nature. This contributed to the fragmenting of the roll face.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c9001191
EISBN: 978-1-62708-225-9
... Abstract Inner rings of spherical roller bearings out of full hardening ball bearing steel 100 CrMn 6 (Fe-1C-1.5Cr-1.1Mn, Material No. 1.3520) failed in service. Due to the cracks, parts from the middle flange broke or the rings failed in radial direction completely. All the cracks and fracture...
Abstract
Inner rings of spherical roller bearings out of full hardening ball bearing steel 100 CrMn 6 (Fe-1C-1.5Cr-1.1Mn, Material No. 1.3520) failed in service. Due to the cracks, parts from the middle flange broke or the rings failed in radial direction completely. All the cracks and fracture originated from the middle flange. In all of the three rings one flank showed heavy wearing and scouring. The cracks started from the edge of this flank with the cylindrical mantle surface of the middle flange. The cracking resembled fatigue cracking. However, in a fine-grained hardened steel such as this, fracture faces due to stress-cracking and overload fracture look the same. Metallographic examination showed the failure of the rings was a result of repeated heating and rapid cooling of the surface due to the grinding of the bearings on one flank of the middle flange. The stress-cracks (grindcracks) spread in steps which finally led to the breaking off of parts from the middle flange and complete failure of the rings.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c9001003
EISBN: 978-1-62708-227-3
... flux. The embrittlement was shown to be caused by the flow of corrosion generated hydrogen which converted the cementite to methane which nucleated voids in the steel. A thermodynamic estimate indicated that a small amount of chromium would stabilize the carbides against decomposition by hydrogen...
Abstract
Gross wastage and embrittlement were observed in plain carbon steel desuperheaters in five new Naval power plants. The gross wastage could be duplicated in laboratory bomb tests using sodium hydroxide solutions and was concluded to be caused by free caustic concentrated by high heat flux. The embrittlement was shown to be caused by the flow of corrosion generated hydrogen which converted the cementite to methane which nucleated voids in the steel. A thermodynamic estimate indicated that a small amount of chromium would stabilize the carbides against decomposition by hydrogen in this temperature range, and laboratory tests with 2-14% Cr steel verified this.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c9001164
EISBN: 978-1-62708-227-3
... sulfur, mainly from the flue gas, and calcium and chlorine, mainly from the sea water. The gray corrosion product was interspersed with rust and a black carbonaceous deposit. Corrosion pitting and poor weld penetration, with carbide precipitation and heavy etching at grain boundaries, indicated...
Abstract
Plate perforation occurred in the cylindrical section and walls of the inlet foot (2.38 mm thick Incoloy 825 plate welded using INCO welding rod 135) of an inert gas fire prevention system in an oil tanker. Cross-sectional microprobe analysis showed the corrosion product to contain sulfur, mainly from the flue gas, and calcium and chlorine, mainly from the sea water. The gray corrosion product was interspersed with rust and a black carbonaceous deposit. Corrosion pitting and poor weld penetration, with carbide precipitation and heavy etching at grain boundaries, indicated sensitization and susceptibility to aqueous intergranular corrosion. Chemical analysis showed the predominant acid radical to be sulfate (6.20% in the carbonaceous deposit and 0.60% in the corrosion product), suggesting that oxidation of SO2 in the flue gas caused the corrosion. Moisture condensation, the carbon acting as a cathode, and alloy susceptibility to intergranular corrosion contributed to the corrosion.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c9001657
EISBN: 978-1-62708-227-3
...) is even better for failure assessment purposes. Metallographic samples are first examined in the unetched condition to study the distribution of primary carbides, sulphocarbides, inclusions and various forms of casting defects. Coated components are also best suited for an unetched microstructural...
Abstract
The circumstances surrounding the in-service failure of a cast Ni-base superalloy (Alloy 713LC) second stage turbine blade and a cast and coated Co-base superalloy (MAR-M302) first stage air-cooled vane in two turbine engines used for marine application are described. An overview of a systematic approach, analyzing the nature of degeneration and failure of the failed components, utilizing conventional metallurgical techniques, is presented. The topographical features of the turbine blade fracture surface revealed a fatigue-induced crack growth pattern, where crack initiation had taken place in the blade trailing edge. An estimate of the crack-growth rate for the stage II fatigue fracture region coupled with the metallographic results helped to identify the final mode of the turbine blade failure. A detailed metallographic and fractographic examination of the air-cooled vane revealed that coating erosion in conjunction with severe hot-corrosion was responsible for crack initiation in the leading edge area.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003545
EISBN: 978-1-62708-180-1
... deformation, including stress-rupture fractures. It also describes metallurgical instabilities, such as aging and carbide reactions, and evaluates the complex effects of creep-fatigue interaction. The article concludes with a discussion on thermal fatigue and creep fatigue failures. aging carbide...
Abstract
This article reviews the applied aspects of creep and stress-rupture failures. It discusses the microstructural changes and bulk mechanical behavior of classical and nonclassical creep behavior. The article provides a description of microstructural changes and damage from creep deformation, including stress-rupture fractures. It also describes metallurgical instabilities, such as aging and carbide reactions, and evaluates the complex effects of creep-fatigue interaction. The article concludes with a discussion on thermal fatigue and creep fatigue failures.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006780
EISBN: 978-1-62708-295-2
...). Other potential microstructural changes include in situ graphitization that occurs in iron-base alloys without adequate carbide-stabilizing elements present. Iron carbide (cementite) decomposes to graphite and iron. Chromium is typically added to prevent this. In situ graphitization is also affected...
Abstract
The principal types of elevated-temperature mechanical failure are creep and stress rupture, stress relaxation, low- and high-cycle fatigue, thermal fatigue, tension overload, and combinations of these, as modified by environment. This article briefly reviews the applied aspects of creep-related failures, where the mechanical strength of a material becomes limited by creep rather than by its elastic limit. The majority of information provided is applicable to metallic materials, and only general information regarding creep-related failures of polymeric materials is given. The article also reviews various factors related to creep behavior and associated failures of materials used in high-temperature applications. The complex effects of creep-fatigue interaction, microstructural changes during classical creep, and nondestructive creep damage assessment of metallic materials are also discussed. The article describes the fracture characteristics of stress rupture. Information on various metallurgical instabilities is also provided. The article presents a description of thermal-fatigue cracks, as distinguished from creep-rupture cracks.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006795
EISBN: 978-1-62708-295-2
... at approximately 20 to 30° is not universally observed and is dependent on factors such as particle shape and fragmentation ( Ref 51 – 53 ). When ductile materials are impacted by spherical particles that do not fragment, the maximum erosion rate can occur at 90°, illustrating that material behavior depends...
Abstract
Erosion is the progressive loss of original material from a solid surface due to mechanical interaction between that surface and a fluid, a multicomponent fluid, an impinging liquid, or impinging solid particles. The detrimental effects of erosion have caused problems in a number of industries. This article describes the processes involved in erosion of ductile materials, brittle materials, and elastomers. Some examples of erosive wear failures are given on abrasive erosion, liquid impingement erosion, cavitation, and erosion-corrosion. In addition, the article provides information on the selection of materials for applications in which erosive wear failures can occur.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001758
EISBN: 978-1-62708-241-9
... creep voiding along grain boundaries and/or interdendritic regions. Internal voids can also nucleate at carbides and other microconstituents, especially in single crystal castings that do not possess grain boundaries. References References 1. Howmet Alcoa , Whitehall, Michigan 2...
Abstract
This article describes the visual, fractographic, and metallographic evidence typically encountered when analyzing stress rupture of turbine airfoils. Stress-rupture fractures are generally heavily oxidized, tend to be rough in texture, and are primarily intergranular and/or interdendritic in appearance compared to smoother, transgranular fatigue type fractures. Often, gross plastic yielding is visible on a macroscopic scale. Commonly observed microstructural characteristics include creep voiding along grain boundaries and/or interdendritic regions. Internal voids can also nucleate at carbides and other microconstituents, especially in single crystal castings that do not possess grain boundaries.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003508
EISBN: 978-1-62708-180-1
...; generally spherical and often coated with oxide Cold shot G 113 Spherical metallic inclusions inside blowholes or other cavities or in surface depressions (see A 311). Composition approximates that of the alloy cast but nearer to that of a eutectic Internal sweating, phosphide sweat G 120...
Abstract
This article focuses on the general root causes of failure attributed to the casting process, casting material, and design with examples. The casting processes discussed include gravity die casting, pressure die casting, semisolid casting, squeeze casting, and centrifugal casting. Cast iron, gray cast iron, malleable irons, ductile iron, low-alloy steel castings, austenitic steels, corrosion-resistant castings, and cast aluminum alloys are the materials discussed. The article describes the general types of discontinuities or imperfections for traditional casting with sand molds. It presents the international classification of common casting defects in a tabular form.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003568
EISBN: 978-1-62708-180-1
... at approximately 20 to 30° is not universally observed and is dependent on factors such as particle shape and fragmentation ( Ref 46 , 47 , 48 ). When ductile materials are impacted by spherical particles that do not fragment, the maximum erosion rate can occur at 90°. Erosion of a given material as a function...
Abstract
Erosion occurs as the result of a number of different mechanisms, depending on the composition, size, and shape of the eroding particles; their velocity and angle of impact; and the composition of the surface being eroded. This article describes the erosion of ductile and brittle materials with the aid of models and equations. It presents three examples of erosive wear failures, namely, abrasive erosion, erosion-corrosion, and cavitation erosion.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003564
EISBN: 978-1-62708-180-1
... of the ring and cone fracture is provided by the Hertz theory of elastic contact. Traditionally, Hertzian cone cracks have been most widely studied in flat, silicate glass plate, using spheres of hard steel or tungsten carbide. Extension to ceramics is becoming more prevalent, and the theory of Hertzian...
Abstract
Rolling-contact fatigue (RCF) is a surface damage process due to the repeated application of stresses when the surfaces of two bodies roll on each other. This article briefly describes the various surface cracks caused by manufacturing processing faults or blunt impact loads on ceramic balls surfaces. It discusses the propagation of fatigue cracks involved in rolling contacts. The characteristics of various types of RCF test machines are summarized. The article concludes with a discussion on the various failure modes of silicon nitride in rolling contact. These include the spalling fatigue failure, the delamination failure, and the rolling-contact wear.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
... G 112 (a) Metallic inclusions of the same chemical composition as the base metal; generally spherical and often coated with oxide Cold shot G 113 Spherical metallic inclusions inside blowholes or other cavities or in surface depressions. Internal sweating, phosphide sweat...
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006807
EISBN: 978-1-62708-329-4
... mechanisms that affect the creep rate, such as carbide precipitation, agglomeration of carbides and other precipitates, grain-boundary sliding, void generation and growth, and so on. However, assigning a unique internal variable to each microscopic mechanism of interest can become a daunting, and often...
Abstract
This article provides some new developments in elevated-temperature and life assessments. It is aimed at providing an overview of the damage mechanisms of concern, with a focus on creep, and the methodologies for design and in-service assessment of components operating at elevated temperatures. The article describes the stages of the creep curve, discusses processes involved in the extrapolation of creep data, and summarizes notable creep constitutive models and continuum damage mechanics models. It demonstrates the effects of stress relaxation and redistribution on the remaining life and discusses the Monkman-Grant relationship and multiaxiality. The article further provides information on high-temperature metallurgical changes and high-temperature hydrogen attack and the steps involved in the remaining-life prediction of high-temperature components. It presents case studies on heater tube creep testing and remaining-life assessment, and pressure vessel time-dependent stress analysis showing the effect of stress relaxation at hot spots.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003546
EISBN: 978-1-62708-180-1
... are such that the microstructure remains stable. The essential features of the microstructure of blade alloys are: Large cuboidal γ′ precipitates for creep resistance Small spherical γ′ precipitates to provide strength Large grains to reduce the intrinsic creep rate by reducing the grain-boundary area and therefore...
Abstract
Thermomechanical fatigue (TMF) refers to the process of fatigue damage under simultaneous changes in temperature and mechanical strain. This article reviews the process of TMF with a practical example of life assessment. It describes TMF damages caused due to two possible types of loading: in-phase and out-of-phase cycling. The article illustrates the ways in which damage can interact at high and low temperatures and the development of microstructurally based models in parametric form. It presents a case study of the prediction of residual life in a turbine casing of a ship through stress analysis and fracture mechanics analyses of the casing.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003532
EISBN: 978-1-62708-180-1
... rougher appearance due to the linking up of the microvoids. Below the fracture surface, spherical ruptures are frequently seen, which are also indicative of a ductile fracture mechanism. Fig. 3 Light micrographs of section profiles of (a) a nickel-plated ductile fracture and (b) a nickel-plated...
Abstract
This article provides a discussion on the metallographic techniques used for failure analysis, and on fracture examination in materials, with illustrations. It discusses various metallographic specimen preparation techniques, namely, sectioning, mounting, grinding, polishing, and electrolytic polishing. The article also describes the microstructure examination of various materials, with emphasis on failure analysis, and concludes with information on the examination of replicas with light microscopy.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006781
EISBN: 978-1-62708-295-2
... are such that the microstructure remains stable. The essential features of the microstructure of blade alloys include: Large cuboidal γ′ precipitates for creep resistance Small spherical γ′ precipitates to provide strength Large grains to reduce the intrinsic creep rate by reducing the grain-boundary area...
Abstract
Thermomechanical fatigue (TMF) is the general term given to the material damage accumulation process that occurs with simultaneous changes in temperature and mechanical loading. TMF may couple cyclic inelastic deformation accumulation, temperature-assisted diffusion within the material, temperature-assisted grain-boundary evolution, and temperature-driven surface oxidation, among other things. This article discusses some of the major aspects and challenges of dealing with TMF life prediction. It describes the damage mechanisms of TMF and covers various experimental techniques to promote TMF damage mechanisms and elucidate mechanism coupling interactions. In addition, life modeling in TMF conditions and a practical application of TMF life prediction are presented.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006791
EISBN: 978-1-62708-295-2
... in the shape of an annulus. To achieve proper alignment of the specimens, an alignment pin is used, consisting of a cylindrical lower region with a spherical upper region. To conduct the test, the bottom specimen is fixed while a load ( F ) is applied to the upper specimen, which is rotated via an applied...
Abstract
Friction and wear are important when considering the operation and efficiency of components and mechanical systems. Among the different types and mechanisms of wear, adhesive wear is very serious. Adhesion results in a high coefficient of friction as well as in serious damage to the contacting surfaces. In extreme cases, it may lead to complete prevention of sliding; as such, adhesive wear represents one of the fundamental causes of failure for most metal sliding contacts, accounting for approximately 70% of typical component failures. This article discusses the mechanism and failure modes of adhesive wear including scoring, scuffing, seizure, and galling, and describes the processes involved in classic laboratory-type and standardized tests for the evaluation of adhesive wear. It includes information on standardized galling tests, twist compression, slider-on-flat-surface, load-scanning, and scratch tests. After a discussion on gear scuffing, information on the material-dependent adhesive wear and factors preventing adhesive wear is provided.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001831
EISBN: 978-1-62708-241-9
... used in the bearing are quenching and tempering, it can be observed that both the materials are composed of acicular martensites and evenly distributed carbides. However, more grain boundaries of the retained austenites were present in the outer ring, Fig. 3a . This phenomenon is consistent...
Abstract
An air blower in an electric power plant failed unexpectedly when a roller bearing in the drive motor fractured along its outer ring. Both rings, as well as the 18 rolling elements, were made from GCr15 bearing steel. The bearing also included a machined brass (MA/C3) cage and was packed with molybdenum disulfide (MoS 2 ) lithium grease. Metallurgical structures and chemical compositions of the bearing’s matrix materials were inspected using a microscope and photoelectric direct reading spectrometer. SEM/EDS was used to examine the local morphology and composition of fracture and contact surfaces. Chemical and thermal properties of the bearing grease were also examined. The investigation revealed that the failure was caused by wear due to dry friction and impact, both of which worsened as a result of high-temperature degradation of the bearing grease. Fatigue cracks initiated in the corners of the outer ring and grew large enough for a fracture to occur.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.9781627083294
EISBN: 978-1-62708-329-4
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