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Book Chapter
Function and Properties Factors in Plastics Processing Selection
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006935
EISBN: 978-1-62708-395-9
... for such processes as resin transfer molding and pultrusion, in which the resin must flow through preplaced glass reinforcements. For other processes, such as extra-high-strength molding compound and prepreg compression molding, the resin must be thickened by reaction to stay on the glass reinforcements. With sheet...
Abstract
Manufacturing process selection is a critical step in plastic product design. The article provides an overview of the functional requirements that a part must fulfil before process selection is attempted. A brief discussion on the effects of individual thermoplastic and thermosetting processes on plastic parts and the material properties is presented. The article presents process effects on molecular orientation. It also illustrates the thinking that goes into the selection of processes for size, shape, and design factors. Finally, the article describes how various processes handle reinforcement.
Book Chapter
Abbreviations—Characterization and Failure Analysis of Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006945
EISBN: 978-1-62708-395-9
... reinforced reaction injection molding relative thermal index resin transfer molding room temperature vulcanizing Society of Automotive Engineers scanning Auger microscopy styrene-acrylonitrile styrene butadiene styrene butadiene rubber short beam shear; styrene-butadiene-styrene styrene-ethylene-butylene...
Abstract
This article is a compilation of abbreviations of terms, techniques, standards, compounds, and properties of materials that are relevant to the characterization and failure analysis of plastics.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006916
EISBN: 978-1-62708-395-9
... applications, two-part systems are used. For example, in resin transfer molding (RTM), reaction injection molding (RIM), and vacuum assisted resin transfer molding (VARTM), a meter mixer is used to precisely mix parts A and B prior to injecting it into the mold cavity. If the mix ratio is not carefully...
Abstract
This article focuses on manufacturing-related failures of injection-molded plastic parts, although the concepts apply to all plastic manufacturing processes It provides detailed examples of failures due to improper material handling, drying, mixing of additives, and molecular packing and orientation. It also presents examples of failures stemming from material degradation improper use of metal inserts, weak weld lines, insufficient curing of thermosets, and inadequate mixing and impregnation in the case of thermoset composites.
Book Chapter
Polymer Processing—An Introduction
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006864
EISBN: 978-1-62708-395-9
... for producing symmetrical parts requiring very high strength in one direction, such as pressure tubes, or for wrapping pressure vessels. The process is also useful for producing continuous oriented-fiber preforms for use in compression molding or resin transfer molding, probably in combination with other...
Abstract
This article discusses technologies focused on processing plastic materials or producing direct tools used in plastics processing. The article focuses on extrusion and injection molding, covering applications, materials and their properties, equipment, processing details, part design guidelines, and special processes. It also covers the functions of the extruder, webline handling, mixing and compounding operations, and process troubleshooting. Thermoforming and mold design are covered. Various other technologies for polymer processing covered in this article are blow molding, rotational molding, compression molding, transfer molding, hand lay-up process, casting, and additive manufacturing.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006925
EISBN: 978-1-62708-395-9
.... Engineering plastics all have, as their principal constituent, one or more synthetic polymer resins and almost universally contain additives. Additives, which have much smaller molecules than polymers, provide color, flexibility, rigidity, flame resistance, weathering resistance, and/or processibility...
Abstract
This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.
Book
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.9781627083959
EISBN: 978-1-62708-395-9
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006923
EISBN: 978-1-62708-395-9
..., and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties. chemical composition elastomeric materials...
Abstract
This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.
Book Chapter
Electrical Testing and Characterization of Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006913
EISBN: 978-1-62708-395-9
... Compression moldings, transfer moldings Aminos (melamine-formaldehyde and urea-formaldehyde) Good general electrical properties, especially arc resistance Compression moldings, extrusions, transfer moldings, laminates, film Diallyl phthalates (DAP) (allylics) Unsurpassed among thermosets in retention...
Abstract
This article addresses electrical testing and characterization of plastics and presents a number of techniques for evaluating the electrical properties of insulating materials, with a special focus on plastics, accompanied by a list of the electrical properties of different types of plastics. It provides the reader with sufficient information to select the appropriate electrical test(s) for a specific application. The tests covered in this article are widely used in industry to determine the electrical properties of insulating materials, particularly plastics. The article lists and defines terms used in connection with testing and specification of plastics for electrical applications.
Book Chapter
Characterization of Thermosetting Resins and Polymers
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006924
EISBN: 978-1-62708-395-9
... Abstract This article discusses the most common thermal analysis methods for thermosetting resins. These include differential scanning calorimetry, thermomechanical analysis, thermogravimetric analysis, and dynamic mechanical analysis. The article also discusses the characterization of uncured...
Abstract
This article discusses the most common thermal analysis methods for thermosetting resins. These include differential scanning calorimetry, thermomechanical analysis, thermogravimetric analysis, and dynamic mechanical analysis. The article also discusses the characterization of uncured thermosetting resins as well as the curing process. Then, the techniques to characterize the physical properties of cured thermosets and composites are presented. Several examples of stress-strain curves are shown for thermosets and thermoplastic polymers.
Book Chapter
Environmental Stress Cracking
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006917
EISBN: 978-1-62708-395-9
... entanglement. Further, if the molding process produces poorly fused knit lines, these can act as localized weakened areas, which are highly susceptible to ESC. As such, it is essential that the molding process maintains the integrity of the molding resin by producing adequate crystallinity, polymer chain...
Abstract
While there are many fracture mechanisms that can lead to the failure of a plastic component, environmental stress cracking (ESC) is recognized as one of the leading causes of plastic failure. This article focuses on unpacking the basic concepts of ESC to provide the engineer with a better understanding of how to evaluate and prevent it. It then presents factors that affect and contribute to the susceptibility of plastic to ESC: material factors, chemical factors, stress, and environmental factors. The article includes the collection of background information to understand the circumstances surrounding the failure, a fractographic evaluation to assess the cracking, and analytical testing to evaluate the material, design, manufacturing, and environmental factors.
Book Chapter
Effects of Composition, Processing, and Structure on Properties of Engineering Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006915
EISBN: 978-1-62708-395-9
... ). The term engineering resin or engineering plastic usually refers only to thermoplastics, which can be molded and remolded to shape, and excludes thermosets such as epoxy resins that cure into an infusible solid. Some rubbers (e.g., polyurethanes) that are cured or vulcanized are nevertheless classed...
Abstract
This article provides practical information and data on property development in engineering plastics. It discusses the effects of composition on submolecular and higher-order structure and the influence of plasticizers, additives, and blowing agents. It examines stress-strain curves corresponding to soft-and-weak, soft-and-tough, hard-and-brittle, and hard-and-tough plastics and temperature-modulus plots representative of polymers with different degrees of crystallinity, cross-linking, and polarity. It explains how viscosity varies with shear rate in polymer melts and how processes align with various regions of the viscosity curve. It discusses the concept of shear sensitivity, the nature of viscoelastic properties, and the electrical, chemical, and optical properties of different plastics. It also reviews plastic processing operations, including extrusion, injection molding, and thermoforming, and addresses related considerations such as melt viscosity and melt strength, crystallization, orientation, die swell, melt fracture, shrinkage, molded-in stress, and polymer degradation.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003571
EISBN: 978-1-62708-180-1
.... The micrograph ( Fig. 9 ) shows that a transfer layer is formed on the polymer surface in addition to the transfer layer found on the counterface. These strong and highly adhesive transfer layers help improve the wear resistance of the polymer composite. Fig. 8 Specific wear rates for phenolic resin...
Abstract
Plastics or polymers are used in a variety of engineering and nonengineering applications where they are subjected to surface damage and wear. This article discusses the classification of polymer wear mechanisms based on the methodologies of defining the types of wear. The first classification is based on the two-term model that divides wear mechanisms into interfacial and bulk or cohesive. The second is based on the perceived wear mechanism. The third classification is specific to polymers and draws the distinction based on mechanical properties of polymers. In this classification, wear study is separated as elastomers, thermosets, glassy thermoplastics, and semicrystalline thermoplastics. The article describes the effects of environment and lubricant on the wear failures of polymers. It presents a case study on nylon as a tribological material. The article explains the wear failure of an antifriction bearing, a nylon driving gear, and a polyoxymethylene gear wheel.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001852
EISBN: 978-1-62708-241-9
... Abstract A 2–3 mm thick electroformed nickel mold showed early cracking under thermal load cycles. To determine the root cause, investigators obtained monotonic and cyclic properties of electroformed nickel at various temperatures and identified possible fatigue mechanisms. With the help...
Abstract
A 2–3 mm thick electroformed nickel mold showed early cracking under thermal load cycles. To determine the root cause, investigators obtained monotonic and cyclic properties of electroformed nickel at various temperatures and identified possible fatigue mechanisms. With the help of finite element modeling, they analyzed the material as well as the design and in-service application of the mold. They discovered that overconstraining the mold, while it was in service, caused excessive thermal stresses which accelerated crack initiation and propagation. Investigators also proposed remedies to prevent additional failures.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006850
EISBN: 978-1-62708-395-9
... of phenolic resin increases by almost 2 orders of magnitude when fillers such as carbon and aramid fibers are added to the phenolic resin matrix. The micrographs in Fig. 9 show that a transfer layer is formed on the polymer surface in addition to the transfer layer found on the counterface. These strong...
Abstract
This article presents the mechanisms of polymer wear and quantifies wear in terms of wear rate (rate of removal of the material). Interfacial and bulk wear are discussed as well as a discussion on the wear study of "elastomers," "thermosets," "glassy thermoplastics," and "semicrystalline thermoplastics." The article also discusses the effects of environment and lubricant on the wear failures of polymers. It presents a case study on considering nylon as a tribological material and failure examples, explaining wear resistance of polyurethane elastomeric coatings and failure of an acetal gear wheel.
Book Chapter
Thermal Stresses and Physical Aging of Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006932
EISBN: 978-1-62708-395-9
... temperatures. Although time-consuming techniques can be used to analyze thermal stresses, several useful qualitative tests are described in this article. Flow-induced orientation effects are also discussed. Orientation commonly occurs in processing using such techniques as extrusion, injection molding...
Abstract
Engineering plastics, as a general class of materials, are prone to the development of internal stresses which arise during processing or during servicing when parts are exposed to environments that impose deformation and/or temperature extremes. Thermal stresses are largely a consequence of high coefficients of thermal expansion and low thermal diffusivities. Although time-consuming techniques can be used to analyze thermal stresses, several useful qualitative tests are described in this article. The classification of internal stresses in plastic parts is covered. The article describes the effects of low thermal diffusivity and high thermal expansion properties, and the variation of mechanical properties with temperature. It discusses the combined effects of thermal stresses and orientation that result from processing conditions. The article also describes the effect of aging on properties of plastics. It explains the use of high-modulus graphite fibers in amorphous polymers.
Book Chapter
Designing with Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006927
EISBN: 978-1-62708-395-9
..., especially interior corners. Resin Casting Casting is one of the most basic low-pressure molding processes and utilizes hollow tools or molds, sometimes with a vacuum assist to ensure complete filling of the mold. The low molding pressures allow for the use of low-cost tools, but this can also result...
Abstract
This article provides background information needed by design engineers to create part designs optimized for plastics and plastic manufacturing processes. It describes the four essential elements of plastic part development, namely, material, process, tooling, and design, and provides general design rules for the plastic forming processes covered. It also discusses the steps involved in design validation and verification.
Book Chapter
Failures Related to Castings
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
... specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance. aluminum casting defects castings copper ductile iron failure analysis gray iron melting solidification steel Introduction...
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Book Chapter
Failures Related to Casting
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003508
EISBN: 978-1-62708-180-1
... iron, gray cast iron, malleable irons, ductile iron, low-alloy steel castings, austenitic steels, corrosion-resistant castings, and cast aluminum alloys are the materials discussed. The article describes the general types of discontinuities or imperfections for traditional casting with sand molds...
Abstract
This article focuses on the general root causes of failure attributed to the casting process, casting material, and design with examples. The casting processes discussed include gravity die casting, pressure die casting, semisolid casting, squeeze casting, and centrifugal casting. Cast iron, gray cast iron, malleable irons, ductile iron, low-alloy steel castings, austenitic steels, corrosion-resistant castings, and cast aluminum alloys are the materials discussed. The article describes the general types of discontinuities or imperfections for traditional casting with sand molds. It presents the international classification of common casting defects in a tabular form.
Book Chapter
Design-Related Failures of Plastic Parts
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006938
EISBN: 978-1-62708-395-9
... and whose contact with the part may be irregular. Due to the often highly complicated nature of product assemblies, the designer must carefully understand the system-level performance and load transfers between components. For plastic components, these considerations include the potential for thermal...
Abstract
A design may be improvable without presenting an unacceptable risk related to safety or performance. However, design-related failures can result from an oversight in performing one of the major design activities or from a failure to balance the competing demands inherent to part design. This article focuses on design-related failures in products utilizing polymeric materials, and reviews important considerations of the design envelope of plastic parts. The article provides a non-exhaustive list and descriptions of design tools that can support the design process and the prevention of design-related failures. It also discusses the most common causes of design-related failures of plastic parts. The article can assist in both failure analysis and in the prevention of failures in which design may be a contributing factor or a root cause.
Book Chapter
Fundamentals of Polymer Additives
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006939
EISBN: 978-1-62708-395-9
... due to poor thermal-oxidative stability ( Ref 1 ). The use of additives in thermosetting polymers is equally important. One of the oldest thermosets, Bakelite, exhibits high cure shrinkage, which leads to cracks in the mold material ( Ref 2 ). Suitable filler additives reduce the cure shrinkage...
Abstract
Polymer materials are key building blocks of the modern world, commonly used in packaging, automobiles, building materials, electronics, telecommunications, and many other industries. These commercial applications of polymeric materials would not be possible without the use of additives. This article is divided into five sections: mechanical property modifiers, physical property modifiers, biological function modifiers, processing aids, and colorants. It describes three classes of additives that are used to inhibit biological activity, six classes of mechanical property modifiers, three classes of physical property modifiers, and two classes of both colorants and processing aids.
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