Severe pitting corrosion of a carbon steel tube was observed in the air preheater of a power plant, which runs on rice straw firing. Approximately 1450 tubes were removed from Stage 3 of the preheater (air inlet and flue gas outlet) due to corrosion and local bursting. Samples from Stage 2 (where corrosion was low) and Stage 3 (severe corrosion) were taken and subjected to visual inspection, SEM, x-ray diffraction, microhardness measurement, and chemical and microstructural analysis. It was determined that extended non-operation of the plant resulted in the settlement of corrosive species on the tubes in Stage 3. The complete failure of the tube occurred due to diffusion of these elements into the base metal and precipitation of potassium and chlorine compounds along the grain boundaries, with subsequent dislodging of grains. The nonmetallic inclusions acted as nucleating sites for local pitting bursting. Nonuniform heat transfer in Stage 3 operation accelerated the selective corrosion of front-end tubes. The relatively high heat transfer in this stage resulted in condensation of some corrosive gases and consequent corrosion. Continuous operation of the plant with some precautions during assembly of the tubes reduced the corrosion problem.

A weld that attached the head to the shell of a preheater containing steam at 1.4 MPa (200 psi) and was used in the manufacture of paper cracked in service. The original joint contained a 6.4 by 50 mm backing ring that had been tack welded to the inside surface of the shell in a position to project beyond the fully beveled top edge of the shell. The projecting edge of the ring fitted against a deep undercut on the inner corner of the rim of the head. The internal 90-deg angle in this undercut was sharp, with almost no fillet. A bevel from the lower edge of the undercut to the outside of the head completed the groove for the circumferential attachment weld. Investigation (visual inspection and actual size views etched in hot 50% hydrochloric acid) supported the conclusion that cracking occurred in the HAZ in the head of the original design, originating in the sharp corner of the undercut, which was an inherent stress raiser. Recommendations included revised joint design to ensure full root penetration.

The thin plates within a type 309 stainless steel chlorinated solvent combustion preheater/heat exchanger designed to process fumes from a solvent coating process showed severe corrosion within 6 months of service. Within a year corrosion had produced holes in the plates, allowing gases to shunt across the preheater/exchanger. Metallographic examination of the plates showed that accelerated internal oxidation had been the cause of failure. Corrosion racks of candidate alloys (types 304, 309, and 316 stainless steels, Inconel 600, Inconel 625, Incoloy 800, Incoloy 825, and Inco alloy C-276) were placed directly in the hot gas stream, containing HCl and Cl2, for in situ testing. Results of this investigation showed that nickel-chromium corrosion-resistant alloys, such as Inconel 600, Inconel 625, and Inco alloy C-276, performed well in this environment. Laboratory testing of the same alloys, along with Inconel alloys 601, 617, and 690 and stainless steel type 347 was also conducted in a simulated waste incinerator nitrogen atmosphere containing 10% Co2, 9% O2, 4% HCl, 130 ppm HBr and 100 ppm SO2 at 595, 705, 815, and 925 deg C (1100, 1300,1500, and 1700 deg F). The tests confirmed the suitability of the nickel-chromium alloys for such an environment. Inconel 625 was selected for fabrication of a new preheater/exchanger.

In a shipyard one of the two posts of a loading gear fractured under a comparatively small load at the point where it was welded into the ship’s deck. The post consisted of several pipe lengths that were produced by longitudinal seam welding of 27 mm thick sheets. The sheet metal was a construction steel of 60 to 75 kp/sq mm strength. Thick-walled parts of steels of such high strength must be preheated to approximately 200 deg C along the edges prior to welding to minimize the strong heat losses by the cold mass of the part. In the case under investigation this either was not done at all or the preheating was not high enough or sufficiently uniform. This damage was therefore caused by a welding defect.

A roadarm for a tracked vehicle failed during preproduction vehicle testing. The arm was a weldment of two cored low-alloy steel sand castings specified to ASTM A 148, grade 120–95. A maximum carbon content of 0.32% was specified. The welding procedure called for degreasing and gas metal arc welding; neither preheating nor postheating was specified. The filler metal was E70S-6 continuous consumable wire with a copper coating to protect it from atmospheric oxidation while on the reel. Analysis of the two castings revealed that the carbon content was higher than specified, ranging from 0.40 to 0.44%. The fracture occurred in the HAZ , where quenching by the surrounding metal had produced a hardness of 55 HRC. Some roadarms of similar carbon content and welded by the same procedure had not failed because they had been tempered during a hot-straightening operation. Brittle fracture of the roadarm was caused by a combination of too high a carbon equivalent in the castings and the lack of preheating and postheating during the welding procedure. A pre-heat and tempering after welding were added to the welding procedure.

An air bottle, machined from a solid block of aluminum alloy 2219-T852, displayed liquid-penetrant crack indications after assembly welding. The air bottle was machined to rough shape, a 3.8 mm (0.15 in.) wall thickness cylindrical cup with a 19 mm (3/4 in.) wall thickness integral boss on one side. After annealing, hot spinning, annealing a second time, and tack welding a port fitting, the assembly was torch preheated to 120 to 150 deg C (250 to 300 deg F). The port fitting was then welded in place. Final full heat treatment to the T62 temper was followed by machining, testing, and inspection. The crack indications were found only on one side of the boss and on the lower portion of the hot-spun dome region. The metallographic specimens revealed triangular voids and severe intergranular cracks. The cracks displayed the glossy surfaces typical of melted and resolidified material. The localized cracks in the air bottle were from grain-boundary eutectic melting caused by local torch overheating used in preparation for assembly welding of a port fitting. A change in design was scheduled to semiautomatic welding without the use of preheating for the joining of the port fitting for the dome opening.

A seamless hot-drawn boiler tube NW 300 of 318 mm OD and 9 mm wall thickness made of steel 15Mo3 was bent with sand filling after preheating allegedly to 1000 deg C. In the process it had cracked repeatedly in the drawn fiber. The composition corresponded to specifications, but exceptionally high copper content was noticeable. Microstructural examination showed the damage was due to overheating and burning during preheating and bending. Furthermore, crack formation was promoted by precipitation of metallic copper that had penetrated into the austenitic grain boundaries under the influence of tensile stresses that arose during bending. This phenomenon is known as “solder brittleness.”

Several of the welds in a hoist carriage tram-rail assembly fabricated by shielded metal arc welding the leg of a large T-section 1020 steel beam to the leg of a smaller T-section 1050 steel rail failed in one portion of the assembly. Four weld cracks and several indefinite indications were found by magnetic-particle inspection. The cracks were revealed by metallographic examination to have originated in the HAZs in the rail section. Cracks in welds and in HAZs resulting from arcing the electrode adjacent to the weld and weld spatter were also revealed. The tram-rail assembly was concluded to have failed by fatigue cracking in HAZs. The fatigue cracking was initiated and propagated by vibration of the tram rail by movement of the hoist carriage on the rail. As a corrective measure, welding procedures were improved and the replacement rail assemblies were preheated and postheated.

The failure of a 45 Mg (50 ton) rail crane bolster was investigated. Spectrochemical analysis indicated that the material was a 0.25C-1.24Mn-0.62Cr-0.24Mo cast steel. SEM examination revealed the presence of fatigue, as well as intergranular and ductile fractures. Microstructural analysis focused on an area where an antisway device had been welded to the structure and revealed the presence of coarse, untempered martensite that had resulted from faulty weld repair techniques. It was suggested that the use of proper welding procedures, including preheating and postheating, would have prevented the failure.

A 208 cm (82 in.) ID steel aqueduct (ASTM A572, grade 42, type 2 steel) fractured circumferentially at two points 152 m (500 ft) apart in a section above ground. A year later, another fracture occurred in a buried section 6.4 km (4 mi) away. Both pipes fractured during Jan at similar temperatures and pressures. The pipe had a 24 mm wall thickness, and the hydrostatic head was 331 m (1085 ft). The air temperature was approximately -13 deg C (9 deg F), the water temperature approximately 0.6 deg C (33 deg F), and the steel temperature approximately -4 deg C (25 deg F). The pipe had been shop-fabricated in 12 m (40 ft) lengths, then shop welded into 24 m (80 ft) lengths. Field assembly was with bell-and-spigot joints. Investigation (visual inspection and Charpy V-notch testing) supported the conclusion that brittle fracture of the aqueduct pipe was attributed to a combination of stress concentrations at the toes of the fillet welds due to poor welding technique, including shop welds made without preheat, and a brittle condition of the steel at winter temperatures. Recommendations included revised welding techniques, installation of expansion joints, and the use of steel plate rolled from fully killed ingots.

Two bolts from the stressed structure of a church building that had broken during stressing were examined to establish the cause of fracture. The fracture of one of the first bolt occurred in a double-vee groove weld whose root was not completely welded. The second bolt had cracked outside of the weld seam closely under the head. Neither one had been particularly deformed before fracture. The composition of the head pieces corresponded approximately to manganese steel (Material No. 1 0845), a weldable construction steel with increased yield point and strength, while the shafts were made from Cr-Mo steel (Material No. 1.7225) according to DIN 17200. It was found that the bolts were not made from a suitable alloy steel, but were welded together from two unsuitable steels, one of which lacked sufficient strength. The austenitic weld seams showed hot tears and were not welded through to the root. Also, the pieces were not preheated before welding, so that stress cracks occurred in the transition zones. The second bolt was overstressed during the impact caused by the breaking of the first bolt.

Steel pipes, used for years in a food factory soft water preheater, were found to leak as a result of corrosion. The pipes, made of 18/8 steel, were immersed in steam maintained at 0.5 atm and 150 deg C. They carried desalinated process water, heating it to approximately 100 deg C. Inspection revealed a reddish-brown coating on the outside of the pipe with a few flat pitting holes and incipient cracks. Corrosion was also observed on the inner walls of the pipe, consisting of rust patches with pitting scars, branching out to predominantly transcrystalline cracks. In this case, leaking appears to be the result of a combination of pitting and stress corrosion, most likely due to chlorides. The factory was recommended to use molybdenum-alloyed steels (type 18/10 or 18/12) which are more resistant to local disruption of passivating films and pitting than molybdenum-free types such as 18/8.

During the construction of a large-diam pipeline, several girth welds had to be cut out as a result of radiographic interpretation. The pipeline was constructed of 910 mm (36 in.) diam x 13 mm (0.5 in.) wall thickness grade X448 (x65) line pipe. The girth welds were fabricated using standard vertical down stove pipe-welding procedures with E7010 cellulosic electrodes. The crack started partially as a result of incomplete fusion on the pipe side wall, which in turn was a result of misalignment of the two pipes. The crack was typical of hydrogen cracking. Girth welds can be made using cellulosic electrodes. For high-risk girth welds, an increase in preheat and/or a reduction in the local stress by controlling lift height or depositing the hot pass locally before lifting may be required.

Carbon steel tubes from a boiler feedwater heater feeding a deaerator were treated to control scale formation, but the treatment instead produced more iron oxide. The additional iron oxide reduced the tubing to a totally corroded condition. Investigation showed that the chelate injected to control the scaling was added ahead of the preheater, where the boiler water still contained oxygen. As the chelate removed iron oxide, the O2 in the water continued to form more. Recommendations included moving the chelate addition to a point after the deaerator to stop the corrosion.

Two tubular AISI 1025 steel posts (improved design) in a carrier vehicle failed by cracking at the radius of the flange after five weeks of service. The posts were two of four that supported the chassis of the vehicle high above the wheels. The original design involved a flat flange of low-carbon low-alloy steel that was welded to an AISI 1025 steel tube, and the improved design included placing the welded joint of the flange farther away from the flange fillet. Investigation (visual inspection and chemical analysis) supported the conclusion that the failures in the flanges of improved design were attributed to fatigue cracks initiating at the aluminum oxide inclusions in the flange fillet. Recommendations included retaining the improved design of the flange with the weld approximately 50 mm (2 in.) from the fillet, but changing the metal to a forging of AISI 4140 steel, oil quenched and tempered to a hardness of 241 to 285 HRB. Preheating to 370 deg C (700 deg F) before and during welding with AISI 4130 steel wire was specified. It was also recommended that the weld be subjected to magnetic-particle inspection and then stress relieved at 595 deg C (1100 deg F), followed by final machining.

High-chromium steel pipes 42.25 x 3.25 mm from a blast furnace gas fired recuperator for the preheating of air were heavily oxidized and perforated in places. It was found that the blast furnace gas had a high sulfur content. Both the carburization and the formation of sulfide proved that in addition, from time to time at least, combustion was incomplete and the operation was carried out in a reducing atmosphere, with the result that oxygen deficiency prevented the formation or maintenance of a protective surface layer on the external surface of the pipes. The sulfur would probably not have damaged the nickel-free steel used here at the given temperatures if it had been present as sulfur dioxide in an oxidizing atmosphere. The damage was therefore caused primarily by an incorrectly conducted combustion process.

A recuperator used for preheating the combustion air for a rolling mill furnace failed after a relatively short service time because of leakage of the pipes in the colder part. The 6 % chrome steel pipes used for the warmer part connected by means of welding with austenitic electrodes to the unalloyed mild steel pipe of larger diam. Visual inspection showed corrosion and deep, trench-like erosion over the entire circumference of the seam on the side of the thicker mild steel pipe. Examination using the V2-A solution for picral etch showed the microstructure of the unalloyed pipe had become coarse-grained and acicular, and the microstructure of the welding seam had become predominantly martensitic as a result of the mixing of the weld metal with the fused pipe material. The chrome steel pipe had become partially transformed to martensite or bainite at the transition to the weld. Thus, the failure occurred due to typical contact corrosion wherein the alloyed welding seam represented the less noble electrode. The martensitic structure may have contributed to the failure as well. Due to the typical nature of the failure, no recommendations were made.

A spindle made of hardenable 13% chromium steel X40 Cr13 (Material No. 1.4034) that was fastened to a superheated steam push rod made of high temperature structural steel 13Cr-Mo44 (Material No. 1.7335) by means of a convex fillet weld, fractured at the first operation of the rod directly next to the weld bead. Investigation showed that the fracture of the superheated steam push rod spindle was caused by hardening and hardening crack formation in the weld seams and adjoining areas. It would have been preferable to avoid welding near the cross sectional transitions altogether in consideration of the crack sensitivity of high hardenability steels. If for some reason this was not possible, then all precautions should have been taken that are applicable to the particular steel, such as preheating, slow cooling and stress relief tempering after welding. The selection of an austenitic additive material should have been considered because it could have equalized stresses due to its high elongation. Most probably, however, a material of lower hardenability should have been selected for the spindle if high operating properties were of paramount importance.

The AISI 1080 steel crankshaft of a large-capacity double-action stamping press broke in service and was repair welded. Shortly after the crankshaft was returned to service, the repair weld fractured. The repair-weld fracture was examined ultrasonically which revealed many internal reflectors, indicating the presence of slag inclusions and porosity. A low-carbon steel flux-cored filler metal was used in repair welding the crankshaft, without any preweld or postweld heating. This resulted in the formation of martensite in the HAZ. The repair weld failed by brittle fracture, which was attributed to the combination of weld porosity, many slag inclusions and the formation of brittle martensite in the HAZ. A new repair weld was made using an E312 stainless steel electrode, which provides a weld deposit that contains considerable ferrite to prevent hot cracking. Before welding, the crankshaft was preheated to a temperature above which martensite would form. After completion, the weld was covered with an asbestos blanket, and heating was continued for 24 h. During the next 24 h, the temperature was slowly lowered. The result was a crack-free weld.

The shaft of an exciter that was used with a diesel-driven electric generator broke at a fillet after ten hours of service following resurfacing of the shaft by welding. The fracture surface contained a dull off-center region of final ductile fracture surrounded by regions of fatigue that had been subjected to appreciable rubbing. The fracture appeared to be typical of rotary bending fatigue under conditions of a low nominal stress with a severe stress concentration. It appeared that the fatigue cracks initiated in the surface-weld layer. The weld deposit in the original keyway displays a lack of fusion at the bottom corner. Fatigue fracture of the shaft resulted from stresses that were created by vibration acting on a crack or cracks formed in the weld deposit because of the lack of preheating and postheating. Rebuilding of exciter shafts should be discontinued, and the support plate of the exciter should be braced to reduce the amount of transmitted vibration. Also, the fillet in the exciter shaft should be carefully machined to provide an adequate radius.