This article briefly introduces some commonly used methods for mechanical testing. It describes the test methods and provides comparative data for the mechanical property tests. In addition, creep testing and dynamic mechanical analyses of viscoelastic plastics are also briefly described. The article discusses the processes involved in the short-term and long-term tensile testing of plastics. Information on the strength/modulus and deflection tests, impact toughness, hardness testing, and fatigue testing of plastics is also provided. The article describes tension testing of elastomers and fibers. It covers two basic methods to test the mechanical properties of fibers, namely the single-filament tension test and the tensile test of a yarn or a group of fibers.

This article reviews the applied aspects of creep and stress-rupture failures. It discusses the microstructural changes and bulk mechanical behavior of classical and nonclassical creep behavior. The article provides a description of microstructural changes and damage from creep deformation, including stress-rupture fractures. It also describes metallurgical instabilities, such as aging and carbide reactions, and evaluates the complex effects of creep-fatigue interaction. The article concludes with a discussion on thermal fatigue and creep fatigue failures.

The article commences with an overview of short-term and long-term mechanical properties of polymeric materials. It discusses plasticization, solvation, and swelling in rubber products. The article further describes environmental stress cracking and degradation of polymers. It illustrates how surface degradation of a plain strain tension specimen alters the ductile brittle transition in polyethylene creep rupture. The article concludes with information on the effects of temperature on polymer performance.

This article presents a failure analysis of 37.5 mW gas turbine third stage buckets made of Udimet 500 superalloy. The buckets experienced repetitive integral tip shroud fractures assisted by a low temperature (type II) hot corrosion. A detailed analysis was carried out on elements thought to have influenced the failure process: a) the stress increase from the loss of a load bearing cross-sectional area of the bucket tip shroud by the conversion of metal to the corrosion product (scale), b) influence of the tip shroud microstructure (e.g., a presence of equiaxed and columnar grains, their distribution and orientation), c) evidence of the transgranular initiation, and d) intergranular creep mechanism propagation. The most probable cause of the bucket damage was the combination of increased stresses due to corrosion-induced thinning of the tip shroud and unfavorable microstructures in the tip shroud region.

This article describes the general aspects of creep, stress relaxation, and yielding for homogeneous polymers. It then presents creep failure mechanisms in polymers. The article discusses extrapolative methods for the prediction of long-term creep failure in polymer materials. Then, the widely used models to simulate the service life of polymers are highlighted. These include the Burgers power-law model, the Findley power-law model, the time-temperature superposition (or equivalence) principle (TTSP), and the time-stress superposition principle (TSSP). The Larson-Miller parametric method, one of the most common to describe the material deformation and rupture time, is also discussed.

The principal types of elevated-temperature mechanical failure are creep and stress rupture, stress relaxation, low- and high-cycle fatigue, thermal fatigue, tension overload, and combinations of these, as modified by environment. This article briefly reviews the applied aspects of creep-related failures, where the mechanical strength of a material becomes limited by creep rather than by its elastic limit. The majority of information provided is applicable to metallic materials, and only general information regarding creep-related failures of polymeric materials is given. The article also reviews various factors related to creep behavior and associated failures of materials used in high-temperature applications. The complex effects of creep-fatigue interaction, microstructural changes during classical creep, and nondestructive creep damage assessment of metallic materials are also discussed. The article describes the fracture characteristics of stress rupture. Information on various metallurgical instabilities is also provided. The article presents a description of thermal-fatigue cracks, as distinguished from creep-rupture cracks.

With any polymeric material, chemical exposure may have one or more different effects. Some chemicals act as plasticizers, changing the polymer from one that is hard, stiff, and brittle to one which is softer, more flexible, and sometimes tougher. Often these chemicals can dissolve the polymer if they are present in large enough quantity and if the polymer is not crosslinked. Other chemicals can induce environmental stress cracking (ESC), an effect in which brittle fracture of a polymer will occur at a level of stress well below that required to cause failure in the absence of the ESC reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface embrittlement and temperature on polymer performance.

A chemical storage vessel failed while in service. The failure occurred as cracking through the vessel wall, resulting in leakage of the fluid. The tank had been molded from a high-density polyethylene (HDPE) resin. The material held within the vessel was an aromatic hydrocarbon-based solvent. Investigation (visual inspection, stereomicroscopic examination, 20x/100x SEM images, micro-FTIR in the ATR mode, and analysis using DSC and TGA) supported the conclusion that the chemical storage vessel failed via a creep mechanism associated with the exertion of relatively low stresses. The source of the stress was thought to be molded-in residual stresses associated with uneven shrinkage. This was suggested by obvious distortion evident on cutting the vessel. Relatively high specific gravity and the elevated heat of fusion indicated that the material had a high level of crystallinity. In general, increased levels of crystallinity result in higher levels of molded-in stress and the corresponding warpage. The significant reduction in the modulus of the HDPE material, which accompanied the saturation of the resin with the aromatic hydrocarbon-based solvent, substantially decreased the creep resistance of the material and accelerated the failure.

A pressure vessel failed causing an external fire on a nine-story coke gasifier in a refinery power plant. An investigation revealed that the failure began as cracking in the gasifier internals, which led to bulging and stress rupture of the vessel shell, and the escape of hot syngas, setting off the fire. The failure mechanisms include stress relaxation cracking of a large diameter Incoloy 825 tube, stress rupture of a 4.65 in. thick chromium steel shell wall, and the oxidation of chromium steel exposed to hot syngas. The gasifier process and operating conditions that contributed to the high-temperature degradation were also analyzed and are discussed.

This article describes the viscoelastic behavior of plastics in their solid state only, from the standpoint of the material deforming without fracturing. The consequences of viscoelasticity on the mechanical properties of plastics are described, especially in terms of time-dependencies, as well as the dependence of the viscoelastic character of a plastic on chemical, physical, and compositional variables. By examining the viscoelastic behavior of plastics, the information obtained are then applied in situations in which it may be important to anticipate the long-term properties of a material. This includes assessing the extent of stress decay in materials that are pre-stressed, the noise and vibration transmission characteristics of a material, the amount of heat build-up in a material subjected to cyclic deformation, and the extent a material can recover from any prior deformation. Several qualitative graphs are presented, which highlights the possible differences in the viscoelastic behavior that can exist among plastics.

The lifetime assessment of polymeric products is complicated, and if the methodology utilized leads to inaccurate predictions, the mistakes could lead to financial loss as well as potential loss of life, depending on the service application of the product. This article provides information on the common aging mechanisms of polymeric materials and the common accelerated testing methods used to obtain relevant data that are used with the prediction models that enable service life assessment. Beginning with a discussion of what constitutes a product failure, this article then reviews four of the eight major aging mechanisms, namely environmental stress cracking, chemical degradation, creep, and fatigue, as well as the methods used in product service lifetime assessment for them. Later, several methods of service lifetime prediction that have gained industry-wide acceptance, namely the hydrostatic design basis approach, Miner's rule, the Arrhenius model, and the Paris Law for fatigue crack propagation, are discussed.

This article reviews analytical techniques that are most often used in plastic component failure analysis. The description of the techniques is intended to familiarize the reader with the general principles and benefits of the methodologies, namely Fourier transform infrared spectroscopy, energy-dispersive x-ray spectroscopy, differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. The article describes the methods for molecular weight assessment and mechanical testing to evaluate plastics and polymers. The descriptions of the analytical techniques are supplemented by a series of case studies to illustrate the significance of each method. The case studies also include pertinent visual examination results and the corresponding images that aided in the characterization of the failures.

This paper describes the analysis of the failure of a Zr-2.5Nb pressure tube in a CANDU reactor. The failure sequence was established as: (1) the existence of an undetected manufacturing flaw in the form of a lamination, (2) in-service development of the flaw by oxidation of the lamination, (3) delayed hydride cracking, which extended the flaw through the wall of the tube, resulting in leakage, and (4) rupture of the tube by cold pressurization while the reactor was shut down. The comprehensive failure analysis led to a remedial action plan that permitted the reactor to be returned to full-power operation and ensured a low probability of a similar occurrence for all CANDU reactors.

There are many reasons why plastic materials should not be considered for an application. It is the responsibility of the design/materials engineer to recognize when the expected demands are outside of what the plastic can provide during the expected life-time of the product. This article reviews the numerous considerations that are equally important to help ensure that part failure does not occur. It provides a quick review of thermoplastic and thermoset plastics. The article focuses primarily on thermoset materials that at room temperature are below their glass transition temperature. It describes the motivation for material selection and the goal of the material selection process. The use of material datasheets for material selection as well as the processes involved in plastic material selection and post material selection is also covered.

A heavily worked 304 stainless steel wire basket recrystallized and distorted while in service at 650 deg C (1200 deg F). This case study demonstrates that heavily cold worked austenitic stainless steel components can experience large losses in creep strength, and potentially structural collapse, under elevated temperature service, even at temperatures more than 300 deg C (540 deg F) below the normal solution annealing temperature. The creep strength of the recrystallized 304/304L steel was more than 1000 times less than that achievable with solution annealed 304H. These observations are consistent with limitations (2000 Addendum to ASME Boiler and Pressure Vessel Code) on the use of cold worked austenitic stainless steels for elevated temperature service.

This article reviews the mechanical behavior and fracture characteristics that discriminate structural polymers from metals, including plastic deformation. It provides overviews of crack propagation and fractography. The article presents the distinction between ductile and brittle fracture modes. Several case studies of field failure in various polymers are also presented to illustrate the applicability of available analytical tools in conjunction with an understanding of failure mechanisms.

Overload failures refer to the ductile or brittle fracture of a material when stresses exceed the load-bearing capacity of a material. This article reviews some mechanistic aspects of ductile and brittle crack propagation, including a discussion on mixed-mode cracking, which may also occur when an overload failure is caused by a combination of ductile and brittle cracking mechanisms. It describes the general aspects of fracture modes and mechanisms. The article discusses some of the material, mechanical, and environmental factors that may be involved in determining the root cause of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals.

A high-density polyethylene (HDPE) natural gas distribution pipe (Grade PE 3306) failed by slow, stable crack growth while in residential service. The leak occurred at a location where a squeeze clamp had been used to close the pipe during maintenance. Failure analysis showed that the origin of the failure was a small surface crack in the inner pipe wall produced by the clamping. Fracture mechanics calculations confirmed that the suspected failure process would result in a failure time close to the actual time to failure. It was recommended that: materials be screened for susceptibility to the formation of the inner wall cracks since it was not found to occur in pipe typical of that currently being placed in service; pipes be re-rounded after clamp removal to minimize residual stresses which caused failure; and a metal reinforcing collar be placed around the squeeze location after clamp removal.