Two AISI type 316 stainless steel components intended for use in a reducer section for sodium piping in a fast breeder test reactor were found to be severely corroded—the first soon after pickling, and the second after passivation treatments. Metallographic examination revealed that one of the components was in a highly sensitized condition and that the pickling and passivation had resulted in severe intergranular corrosion. The other component was fabricated from thick plate and, after machining, the outer surface represented the transverse section of the original plate. Pickling and passivation resulted in severe pitting because of end-grain effect. Strict control of heat treatment parameters to prevent sensitization and modification of pickling and passivating conditions for machined components were recommended.

Several stainless steel bolts used on a Titan Space Launch Vehicle broke at the shank and failure was attributed to stress-corrosion cracking. But results could not be duplicated in the laboratory with salt-solution immersion tests until the real culprit was established: the secondary effect of galvanic coupling, hydrogen embrittlement.

This article provides an overview of the electrochemical nature of corrosion and analyzes corrosion-related failures. It describes corrosion failure analysis and discusses corrective and preventive approaches to mitigate corrosion-related failures of metals. These include: change in the environment; change in the alloy or heat treatment; change in design; use of galvanic protection; use of inhibitors; use of nonmetallic coatings and liners; application of metallic coatings; use of surface treatments, thermal spray, or other surface modifications; corrosion monitoring; and preventive maintenance.

An aircraft engine in which an in-flight fire had occurred was dismantled and examined. A bracket assembly fabricated from 2024 aluminum, one of several failed components, was of prime interest because of apparent heat damage. Scanning electron microscopy was used to compare laboratory-induced fractures made at room and elevated temperatures with the bracket failure. The service failure exhibited grain separation and loss of delineation of the grain boundaries due to melting. SEM revealed deep voids between grains and tendrils that connected grains, which resulted from surface tension during melting. Microscopic examination of polished, etched section through the fractured surface verified intergranular separation and breakdown of grain facets. The absence of any reduction of thickness on the bracket assembly at the point of fracture, along with evidence of intense heat at this point, indicated that little stress had been applied to the part. Comparisons of the service failure and laboratory-induced failures in conjunction with macroscopic and metallographic observations showed that the bracket assembly failed because an intense, localized flame had melted the material.

Work rolls made of indefinite chill double-poured (ICDP) iron are commonly used in the finishing trains of hot-strip mills (HSMs). In actual service, spalling, apart from other surface degeneration modes, constitutes a major mechanism of premature roll failures. Although spalling can be a culmination of roll material quality and/or mill abuse, the microstructure of a broken roll can often unveil intrinsic inadequacies in roll material quality that possibly accentuate failure. This is particularly relevant in circumstances when rolls, despite operation under similar mill environment, exhibit variations in roll life. The paper provides an insight into the microstructural characteristics of spalled ICED HSM work rolls, which underwent failure under similar mill operating environment in an integrated steel plant under the Steel Authority of India Limited. Microstructural features influencing ICDP roll quality, viz. characteristics of graphite, carbides, martensite, etc., have been extensively studied through optical microscopy, quantitative image analysis (QIA), and electron-probe microanalysis (EPMA). These are discussed in the context of spalling propensity and roll life.

An extensive metallurgical investigation was carried out on samples of a failed roller bearing from the support and tilting system of a basic oxygen furnace converter used in the steel melting shop of an integrated steel plant. The converter bearing was fabricated from low-carbon, carburizing grade steel and had failed in service within a year of fitting to a repaired shaft. Microscopic observations of both the broken roller and inner-race samples revealed subsurface cracking and preponderance of brittle oxide and other macroinclusions. Electron probe microanalysis studies confirmed that the brittle oxides that formed stringers were alumina, and the other macroinclusions were complex silicates. Both the alumina and silicate inclusions were deleterious to contact-fatigue properties. Microstructurally, the carburized regions of the broken roller and of inner-race samples contained high-carbon tempered martensite. Microhardness measurements revealed that. Although the core hardness of the roller and the inner-race samples were similar, the surface hardness of the roller was approximately 8.5 HRC units harder than that of the inner-race. SEM observations of the roller fracture surface revealed striations indicative of fatigue, and EDS analyses corroborated a high incidence of silicate inclusions at crack sites. The study suggests that the failure of the bearing occurred because the hardness difference between the roller bearing and the inner-race surfaces resulted in wear of the inner-race. The wear led to shaft misalignment and play during service. The misalignment, coupled with the presence of inclusions, caused fatigue failure of the roller bearing.

Although a precise understanding of roll failure genesis is complex, the microstructure of a broken roll can often unravel intrinsic deficiencies in material quality responsible for its failure. This is especially relevant in circumstances when, even under a similar mill-operating environment, the failure involves a particular roll or a specific batch of rolls. This paper provides a microstructural insight into the cause of premature breakage of a second-intermediate Sendzimir mill drive roll used at a stainless steel sheet rolling plant under the Steel Authority of India Limited. Microstructural issues influencing roll quality, such as characteristics of carbides, tempered martensite, retained austenite, etc., have been extensively studied through optical and scanning electron microscopy, electron-probe microanalysis, image analysis, and x-ray diffractometry. These are discussed to elucidate specific microstructural inadequacies that accentuated the failure. The study reveals that even through retained austenite content is low (6.29 vol%) and martensite is non-acicular, the roll breakage is a consequence of intergranular cracking caused by improper carbide morphology and distribution.

This paper describes an investigation on the failure of a large leaded bronze bearing that supports a nine-ton roller of a plastic calendering machine. At the end of the normal service life of a good bearing, which lasted for seven years, a new bearing was installed. However the new one failed catastrophically within a few days, generating a huge amount of metallic wear debris and causing pitting on the surface of the cast iron roller. Following the failure, samples were collected from both good and failed bearings. The samples were analyzed chemically and their microstructures examined. Both samples were subjected to accelerated wear tests in a laboratory type pin-on-disk apparatus. During the tests, the bearing materials acted as pins, which were pressed against a rotating cast iron disk. The wear behaviors of both bearing materials were studied using weight loss measurement. The worn surfaces of samples and the wear debris were examined by light optical microscope, SEM, and energy-dispersive x-ray microanalyzer. It was found that the laboratory pin-on-disk wear data correlated well with the plant experience. It is suggested that the higher lead content ~18%) of the good bearing compared with 7% lead of the failed bearing helped to establish a protective transfer layer on the worn surface. This transfer layer reduced metal-to-metal contact between the bearing and the roller and resulted in a lower wear rate. The lower lead content of the failed bearing does not allow the establishment of a well-protected transfer layer and leads to rapid wear.

The damage to a screw on the head of a 1.8 liter personal car engine was nucleated as the result of common disadvantageous environmental influences and reversed loads leading to corrosion fatigue.

Crane collapse due to bolt fatigue and fatigue failure of a crane support column, crane tower, overhead yard crane, hoist rope, and overhead crane drive shaft are described. The first four examples relate to the structural integrity of cranes. However, equipment such as drive and hoist-train components are often subject to severe fatigue loading and are perhaps even more prone to fatigue failure. In all instances, the presence of fatigue cracks at least contributed to the failure. In most instances, fatigue was the sole cause. Further, in each case, with regular inspection, fatigue cracks probably would have been detected well before final failure.

Following a fracture mechanics “fitness-for-purpose” analysis of petroleum industry cold service pressure vessels, using the British Standard PD 6493, it was realized that an analogous approach could be used for the failure analysis of a similar pressure vessel dome which had failed in service some years previously. The failed pressure vessel, with a diam of 2.5 m and several meters tall, had been made of 12 mm thick IZETT steel plate of the same type and heat treatment as used in the earlier fitness-for-purpose already measured. Examination of the fracture surfaces suggested, from fatigue striations manifested by SEM, that the vessel was subject to significant fatigue cracking, which was probably corrosion assisted. From COD measurements at the operating temperature of -130 deg C (-202 deg F), and a finite stress analysis, a fracture mechanics evaluation using BS PD6493 yielded realistic critical flaw sizes (in the range 51 to 150 mm). These sizes were consistent with the limited fracture surface observations and such flaws could well have been present in the vessel dome prior to catastrophic failure. For similar pressure vessels, an inspection program based on a leak-before-break philosophy was consequently regarded as acceptable.

Locked coil wire ropes, by virtue of their unique design and construction, have specialized applications in aerial ropeways, mine hoist installations, suspension bridge cables, and so forth. In such specialty ropes, the outer layer is constructed of Z-profile wires that provide not only effective interlocking but also a continuous working surface for withstanding in-service wear. The compact construction and fill-factor of locked coil wire ropes make them relatively impervious to the ingress of moisture and render them less vulnerable to corrosion. However, such ropes are comparatively more rigid than conventional wire ropes with fiber cores and therefore are more susceptible to the adverse effects of bending stresses. The reasons for premature in-service wire rope failures are rather complex but frequently may be attributed to inappropriate wire quality and/or abusive operating environment. In either case, a systematic investigation to diagnose precisely the genesis of failure is desirable. This article provides a microstructural insight into the causes of wire breakages on the outer layer of a 40 mm diam locked coil wire rope during service. The study reveals that the breakages of Z-profile wires on the outer rope layer were abrasion induced and accentuated by arrays of fine transverse cracks that developed on a surface martensite layer.

To determine the effect of severe service on cast 357 aluminum pistons, a metallurgical evaluation was made of four pistons removed from the engine of the Hawk-Offenhauser car which had been driven by Rich Muther in the first Ontario, California 500 race. The pistons were studied by visual inspection, hardness traverses, radiography, dye penetrant inspection, chemical analysis, macrometallography, optical microscopy, and electron microscopy. The crown of one piston had a rough, crumbly deposit, which was detachable with a knife. Two pistons had remains of carbonaceous deposits. The fourth was severely hammered. It was concluded that the high temperatures developed in this engine created an environment too severe for 357 aluminum. Surfaces were so hot that the low-melting constituent melted. Then, the alloy oxidized rapidly to form Al2O3, an abrasive which further aggravated problems. The temperature in much of the piston was high enough to cause softening by overaging, lowering strength.

A fracture mechanics based failure analysis and life prediction of a large centrifugal fan made from low-carbon, medium-strength steel was undertaken following shortcomings in attempts to explain its fatigue life from start stop cycles alone. Measurements of the fracture toughness and flaw size at failure, coupled with quantitative SEM fractography using striation spacing methods, revealed that the cyclic stress amplitudes just prior to failure were much larger than expected, in this particular case. Subsequent improvements in fan design and fabrication have effectively alleviated the problem of slow, high cycle fatigue crack growth, at normal operating stresses in similar fans.

A brass (CDA alloy 230) pipe nipple that was part of a domestic cold water bath system failed two weeks after installation. Macrofractography, SEM examination, metallography, and chemical analyses were performed on specimens cut through the main fracture surface. The physical and background evidence obtained indicated failure due to cracking initiated by stamped markings on the pipe wall and extended by high circumferential residual stresses. It was recommended that annealed pipe be used.

The source of cracking in the circumferential weld seam in a JIS-SM50B carbon-manganese steel pipe used in a CO2 absorber was investigated, the absorber had been in service for 18 years. The seam had been weld-repaired twice, and the repair welds had been locally stress relieved. Longitudinal seams in the same vessel, which had been stress relieved in a furnace, showed no tendency toward cracking. The solution passing through the vessel contained CO2-CO-H20, KHCO, and Cl− ions. Nondestructive testing revealed that the cracks originated in the heat-affected zone and propagated into the base metal and weld. Severe branching of the cracks characteristic of stress-corrosion cracking was observed. Microexamination revealed that crack propagation was transgranular further supporting the possibility of stress-corrosion cracking. Simulation tests carried out in the vessel confirmed this mode of cracking. It was recommended that weld seams be furnace heat treated at a temperature of 600 to 640 deg C (1110 to 1180 deg F) for a minimum of 1 h per inch of section thickness.

A stainless steel flexible connector failed after a short period of service. Visual examination of the failed part revealed that a fracture had occurred in the thin-walled stainless steel bellows brazed into the flanges at each end. Surface examination by SEM fractography showed that failure of the bellows occurred via fatigue. The crack in the bellows had widened considerably after the fracture, and the bellows had been severely compressed on the fracture side prior to failure. Based on these observations, it was concluded that bellows had been damaged prior to installation. The damage resulted in high mean tensile stresses upon which were superimposed cyclic stresses, with fatigue failure the final result.

An ASTM A193-83a grade B7 (AISI 4140) steel turbine impeller shaft fractured after 2 months of service. Failure had initiated at three separate points around the periphery of the shaft, each associated with one of three keyways. SEM fractography, metallography, and chemical analysis indicated that the mechanism of fracture initiation was torsional fatigue. Intermittent deceleration and acceleration resulting from power surges during operation of the turbine caused torsional vibration and was considered the most probable source of the required cyclic stress. Final failure took place by torsional shear.

An AISI 4320 H transfer gear shaft that was part of a transmission sustained severe surface damage after 12 h of dynamometer testing at various gearing and torque loads. The damage was characterized by generalized wear and spalling. Examination of a cross section of the shaft that intersected undamaged, burnished, and surface-spalled zones revealed no anomalies in the chemistry, microstructure, or hardness that could have caused the damage. The physical evidence suggested that the operable mechanism was contact fatigue caused by misalignment of the shaft in the assembly.

An ASTM A 504 carbon steel railway car wheel that was used on a train in a metropolitan railway system failed during service, causing derailment. The wheel was completely fractured from rim to hub. Macrofractography of the fracture surface showed road grime, indicating that the crack had existed for a considerable time prior to derailment and initiated in the flange. Failure propagated from the flange across the rim and down the plate to the bore of the hub. Two zones that exhibited definite signs of heating were observed. The fracture initiation site was typical of fatigue fracture. No defects were found that could have contributed to failure. The wheel conformed to the chemical, microstructural, and hardness requirements for class A wheels. Failure was attributed to repeated severe heating and cooling of the rim and flange due to brake locking or misapplication of the hand brake. It was recommended that the brake system on the car be examined and replaced if necessary.