Welds in two CMo steel catalytic gas-oil desulfurizer reactors cracked under hydrogen pressure-temperature conditions that would not have been predicted by the June 1977 revision of the Nelson Curve for that material. Evidence of severe cracking was found in five weld-joint areas during examination of a naphtha desulfurizer by ultrasonic shear wave techniques. Defect indications were found in longitudinal and circumferential seam welds of the ASTM A204, grade A, steel sheet. The vessel was found to have a type 405 stainless steel liner for corrosion protection that was spot welded to the base metal and all vessel welds were found to be overlaid with type 309 stainless steel. Long longitudinal cracks in the weld metal, as well as transverse cracks were exposed after the weld overlay was ground off. A decarburized region on either side of the crack was revealed by metallurgical examination of a cross section of a longitudinal crack. It was concluded that the damage was caused by a form of hydrogen attack. Installation of a used Cr-Mo steel vessel with a type 347 stainless steel weld overlay was suggested as a corrective action.

A spiral bevel gear set in the differential housing of a large front-end loader moving coal in a storage area failed in service. The machine had operated approximately 1500 h. Although the failure involved only the pinion teeth, magnetic particle inspection was performed on each part. The 4817 NiMo alloy steel pinion showed no indication of additional cracking, nor did the 4820 NiMo alloy steel gear. The mode of failure was tooth bending fatigue with the origin at the designed position: root radius at midsection of tooth. The load was well centered, and progression occurred for a long period of time. The cause of failure was a suddenly applied peak overload, which initiated a crack at the root radius. Progression continued by relatively low overstress from the crack, which was now a stress-concentration point. This was a classic tooth bending fatigue failure.

The repeated failure of rubber-covered rotors and volute liners in a flue gas desulfurization system after conversion from lime slurry reagent to limestone slurry reagent was investigated. The pump was a horizontal 50 x 65 mm (2 x 2.5 in.) Galiger pump with a split cast iron case and open rotor (impeller). Both the case and the ductile iron rotor core were covered by natural rubber. Analyses conducted included surface examination of wear patterns, chemical analysis of materials, measurement of mechanical properties, and in-place flow tests. It was determined that the proximate cause of failure was cavitation and vortexing between the rotor and the lining. The root cause of the failure was the conversion from lime to limestone slurry without appropriate modification of the pump. Conversion to the limestone slurry resulted in fluid dynamics outside the operational limits of the pump. The recommended remedial action was replacement with a pump appropriately sized for the desired pressures and flow rates for limestone slurry.

There are many different types of polymeric materials, ranging from glassy to semicrystalline polymers and even blends. Their mechanical properties range from pure elastic with very high strains to fracture (elastomers) to almost pure linear elastic (Hookian behavior) with low strains to fracture (glassy polymers). This article provides an overview of historical development of fracture behavior in polymers. It discusses the processes involved in three fracture test methods for polymers, namely linear elastic fracture mechanics, elastic-plastic fracture mechanics, and post-yield fracture mechanics.

Microbial degradation in the environment is initiated by abiotic (nonliving physical or chemical) processes. Mechanical weathering and other mechanical processes are the main drivers of the initial degradation. This article presents an overview of weathering and biodegradation. It summarizes the main synthetic polymers that are released and available for bacterial and fungal decomposition. The article also presents a detailed discussion on the enzymes that are involved in plastic degradation, and the measurement of polymer degradation.

This article provides the framework for the investigation of bridge failures. It explains the types of bridge loading and presents the regulatory provisions for bridges. Some bridge failures in the U.S. that resulted in significant changes in bridge manufacturing, design, regulation, and/or maintenance are also discussed. In addition, the article provides information on traffic damage and fatigue cracking that result in bridge failures. The need for steels with better fracture toughness in bridge design is also discussed.

In January 1965, a Reaction Control System (RCS) pressure vessel (titanium alloy Ti-6Al-4V) on an Apollo spacecraft cracked in six adjacent locations. It used N2O4 for vehicle attitude control through roll, pitch, and yaw engines, and was protected from the N2O4 by a Teflon positive expulsion bladder. Investigation (visual inspection, pressure testing of 10 similar vessels, and chemical testing of the N2O4) supported the conclusion that the failure was due to stress corrosion from the N2O4, and specifically from a specification change in the military specification MIL-P-26539. Recommendations included revising the specification to require a minimum NO content of 0.6%.

The failure of HP turbine blades in a low bypass turbofan engine was analyzed to determine the root cause. Forensic and metallurgical investigations were conducted on all failed blades as well as failed downstream components. It was found that one of the blades fractured in the dovetail region, causing extensive damage throughout the turbine. Remedial measures were suggested to prevent such failures in the future.

This article illustrates the defects, which result because of poor-quality welds in the bridge components. The cracks resulting from the use of low fatigue strength details are also discussed. The article describes the effect of out-of-plane distortion in floor-beam-girder connection plates, multiple-girder diaphragm connection plate, and tied-arch floor beams.

Personnel responsible for laboratory protection at some plants are required to participate in exercises simulating a breach of security at the site. This document reports a metallurgical investigation of blank firing adapters (BFA), one of which exploded during such a training exercise. Determination of the cause of the explosion was the primary objective of the examination. Metallographic studies included the examination of BFAs fabricated from two different types of alloys that were tested for shock reaction. Optical microscopy supported by electron microscopy and analytical methods were used. Our investigation supports the supposition that a live round of ammunition was inadvertently fired.

A large diameter steel pipe reinforced by stiffening rings with saddle supports was subjected to thermal cycling as the system was started up, operated, and shut down. The pipe functioned as an emission control exhaust duct from a furnace and was designed originally using lengths of rolled and welded COR-TEN steel plate butt welded together on site. The pipe sustained local buckling and cracking, then fractured during the first five months of operation. Failure was due to low cycle fatigue and fast fracture caused by differential thermal expansion stresses. Thermal lag between the stiffening rings welded to the outside of the pipe and the pipe wall itself resulted in large radial and axial thermal stresses at the welds. Redundant tied down saddle supports in each segment of pipe between expansion joints restrained pipe arching due to circumferential temperature variations, producing large axial thermal bending stresses. Thermal cycling of the system initiated fatigue cracks at the stiffener rings. When the critical crack size was reached, fast fracture occurred. The system was redesigned by eliminating the redundant restraints and by modifying the stiffener rings to permit free radial thermal breathing of the pipe.

A DC-10 in transit from Denver to Chicago experienced failure of the center engine. The titanium compressor disk burst and severed the hydraulics of the plane. Investigation supports the conclusion that the cause of the disk rupture was the presence of a large fatigue crack near the bore emanating from a hard alpha (HA) defect. Such defects can result from occasional upsets during the vacuum melting of titanium. These nitrogen-rich alpha titanium anomalies are brittle and often have associated microcracks and microvoids. A probabilistic damage tolerance approach was recommended to address the anomalies, with the objective of enhancing rotor life management practices. The ongoing work involves the use of fracture mechanics and software (called DARWIN.) optimized for damage tolerant design and analysis of metallic structural components.

The first-stage blades in a model 501D5 gas turbine had 16 cooling holes. After 32,000 h of service, the blades exhibited cracking at the cooling holes. The blade material was wrought Udimet 520 alloy, with nominal composition of 57Ni-19Cr-12Co-6Mo-1W-2Al-3Ti-0.05C-0.005B. The cooling holes' surface was not coated. Investigation supported the conclusions that the cracking at the cooling holes was due to grain-boundary oxidation and nitridation at the cooling hole surface, embrittlement and loss of local ductility of the base alloy, temperature gradient from the airfoil surface to the cooling holes, which led to relatively high thermal stresses at the holes located at the thicker sections of the airfoil, and stress concentration of 2.5 at the cooling hole and the presence of relatively high total strain (an inelastic strain of 1.2%) at the cooling hole surface. Recommendations include applying the specially designed methods given in this case study to estimate the metal temperature and stresses in order to predict the life of turbine blades under similar operating conditions.

An intergranular stress-corrosion cracking failure of 304 stainless steel pipe in 2000 ppm B as H3BO3 + H2O at 100 deg C was investigated. Constant extension rate testing produced an intergranular type failure in material in air. Chemical analysis was performed on both the base metal and weld material, in addition to fractography, EPR testing and optical microscopy in discerning the mode of failure. Various effects of Cl-, O2 and MnS are discussed. Results indicated that the cause of failure was the severe sensitization coupled with probable contamination by S and possibly by Cl ions.

Several type 304 stainless steel fire truck water tanks developed through-wall leaks after being in service for approximately two years. One representative tank underwent a comprehensive laboratory analysis, which included metallographic examinations and chemical analyses. The examinations revealed a classic case of microbiologically influenced corrosion (MIC), which preferentially attacked the heat affected zones of the tank welds, resulting in the leaks.

A 2–3 mm thick electroformed nickel mold showed early cracking under thermal load cycles. To determine the root cause, investigators obtained monotonic and cyclic properties of electroformed nickel at various temperatures and identified possible fatigue mechanisms. With the help of finite element modeling, they analyzed the material as well as the design and in-service application of the mold. They discovered that overconstraining the mold, while it was in service, caused excessive thermal stresses which accelerated crack initiation and propagation. Investigators also proposed remedies to prevent additional failures.

The assignment of financial liability for turbine blade failures in steam turbines rests on the ability to determine the damage mechanism or mechanisms responsible for the failure. A discussion is presented outlining various items to look for in a post-turbine blade failure investigation. The discussion centers around the question of how to determine whether the failure was a fatigue induced failure, occurring in accordance with normal life cycle estimates, or whether outside influences could have initiated or hastened the failure.

A failed spiral gear and pinion set made from 4320H Ni-Cr-Mo alloy steel operating in a high-speed electric traction motor gear unit driving a rapid transit train were submitted for analysis. The pinion was intact, but the gear had broken into two sections that resulted when two fractured areas went through the body of the gear. Wheel mileage of the assembly was 34,000 miles at the time of failure. All physical and metallurgical characteristics were well within specified standards, and both parts should have withstood normal loading conditions. The primary mode of failure was tooth bending fatigue of the gear from the reverse direction near the toe end. The cause of failure was a crossed-over tooth bearing condition that placed loads at the heel end when going forward and at the toe end when going in reverse. The condition was too consistent to be a deflection under load; therefore, it most likely was permanent misalignment within the assembly.