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Friedrich Karl Naumann, Ferdinand Spies
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Friedrich Karl Naumann, Ferdinand Spies
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Friedrich Karl Naumann, Ferdinand Spies
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Friedrich Karl Naumann, Ferdinand Spies
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George M. Goodrich, Richard B Gundlach, Robert B. Tuttle, Charles V. White
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Michel Rigaud
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Robert B. Pond, Jr., David A. Shifler
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Roger Lewis, Mohanad Zalzalah, Tom Slatter
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Donald E. Duvall
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David A. Shifler, Robert B. Pond, Jr.
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Michael E. Finn, John M. Tartaglia
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Paresh Haribhakti, P.B. Joshi
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Luis A. Ganhao, Jorge J. Perdomo, James McVay, Antonio Seijas
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Jeffrey A. Hawk, Rick D. Wilson, Daniel R. Danks, Matthew T. Kiser
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Book Chapter
Cracked Bearing Caps Made of Cast Iron
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.conag.c9001198
EISBN: 978-1-62708-221-1
...) Eliminate the grooves; 2) Remove the ferritic bright border; 3) Avoid undercooling in the mold and therefore the formation of granular graphite; 4) Inoculate with finely powdered ferrosilicon into the melt for the same purpose; and, 5) Anneal at lower temperature or eliminate subsequent treatment...
Abstract
Cast iron bearing caps in tractor engines fractured repeatedly after only short operating periods. The fracture originated in a cast-in groove and ran approximately radially to the shaft axis. The smallest cross section was at the point of fracture. The core structure of the caps consisted of graphite in pearlitic-ferritic matrix. Casting stresses did not play a decisive role because of the simple shape of the pieces that were without substantial cross sectional variations. Two factors exerted an unfavorable effect in addition to comparatively low strength. First, the operating stress was raised locally by the sharp-edged groove, and second, the fracture resistance of the cast iron was lowered at this critical point by the existence of a ferritic bright border. To avoid such damage in the future it was recommended to observe one or more of the following precautions: 1) Eliminate the grooves; 2) Remove the ferritic bright border; 3) Avoid undercooling in the mold and therefore the formation of granular graphite; 4) Inoculate with finely powdered ferrosilicon into the melt for the same purpose; and, 5) Anneal at lower temperature or eliminate subsequent treatment in consideration of the uncomplicated shape of the castings.
Book Chapter
Corroded Pump Impeller
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c9001165
EISBN: 978-1-62708-234-1
... corrosion resistance. Etching of the core structure showed a selective form of cast iron corrosion (spongiosis or graphitic corrosion) which lowered the strength of the cast iron enough that a knife could scrape off a black powder (10.85% C, 1.8% S, 1.45% P). Analysis showed that some of the “sulfate” found...
Abstract
After operating for six months, a pump impeller (of nickel-containing cast iron) showed considerable corrosion. Cross sections showed substantial penetration of the wall thickness without loss of material. The observed supercooled structure implied low strength but would not affect corrosion resistance. Etching of the core structure showed a selective form of cast iron corrosion (spongiosis or graphitic corrosion) which lowered the strength of the cast iron enough that a knife could scrape off a black powder (10.85% C, 1.8% S, 1.45% P). Analysis showed that some of the “sulfate” found in the scrubbing water was actually sulfide (including hydrogen sulfide) and was the main cause of corrosion.
Book Chapter
Worn Cast Iron Pump Parts
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c9001226
EISBN: 978-1-62708-234-1
.... In order to prevent a repetition, the use of hypoeutectic or eutectic iron, slower cooling of the casting, inoculation of the melt with finely powdered ferrosilicon, and possibly rounding-off the edges or machining of the surfaces are recommended. Galling Materials selection Pumps Gray iron...
Abstract
A slide and the two guideways of a pump had to be disassembled already during run-in time after approximately 20 h because they had galled completely, before the rated speed of 800 rpm was reached. Chemical analysis of the slide showed the following composition: 3.60C, 3.22Graphite, 2.49Si, 0.51Mn, 0.485P, and 0.112S. The iron was thus distinctly hypereutectic. The galling of the pump parts therefore was favored by an unsuitable structure caused by improper composition and fast cooling. Distortion by casting stresses may have been contributory or may have played the principal part. In order to prevent a repetition, the use of hypoeutectic or eutectic iron, slower cooling of the casting, inoculation of the melt with finely powdered ferrosilicon, and possibly rounding-off the edges or machining of the surfaces are recommended.
Book Chapter
Cracks in Cylinder Blocks and in Cast Iron Cylinder Head
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.conag.c9001200
EISBN: 978-1-62708-221-1
... Abstract During the operation of tractors with cantilevered body, the lateral wall of the hypoeutectic cast iron cylinder blocks cracked repeatedly. Three of the blocks were examined. The grain structure of the thick-walled part consisted of uniformly distributed graphite of medium flake size...
Abstract
During the operation of tractors with cantilevered body, the lateral wall of the hypoeutectic cast iron cylinder blocks cracked repeatedly. Three of the blocks were examined. The grain structure of the thick-walled part consisted of uniformly distributed graphite of medium flake size in a basic mass of pearlite with little ferrite. But the thin-walled part showed a structure of dendrites of precipitated primary solid solution grains with pearlitic-ferritic structure and a residual liquid phase with granular graphite in the ferritic matrix. The structure was formed by undercooling of the residual melt. In this case, it was promoted by fast cooling of the thin wall and had comparatively low strength. The fracture formation in the cylinder blocks was ascribed primarily to casting stresses. They could be alleviated by better filleting of the transition cross sections. The fracture was promoted by the formation of undercooled microstructure of low strength in the thin-walled part. Similar damage appeared in a cylinder head, in which case, the cracks were promoted by a supercooled structure.
Book Chapter
Grinding Plate Wear Failure Analysis
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.machtools.c0091853
EISBN: 978-1-62708-223-5
..., showing placement of the attrition mill wear plates In Fig. 2 , a new, unused grinding plate (left) is a 230 mm (9 in.) diameter and 25 mm (1 in.) thick disk of gray cast iron with a hardness of 338 HV and 0.1 mm (0.004 in.) graphite flakes, which are an excellent absorber of vibrations during...
Abstract
A 230 mm (9 in.) diameter disk attrition mill was scheduled to grind 6.35 mm (0.25 in.) diameter quartz particles to a 0.075 mm (0.003 in.) diameter powder. Due to severe wear on the grinding plates, however, the unit was unable to complete the task of grinding the rock. The mill consisted of a heavy gray cast iron frame, a gravity feeder port, a runner, and a heavy-duty motor. The frame and gravity feeder weighed over 200 kg (440 lb) and, in some areas, was over 25 mm (1 in.) thick. To obtain the operating speed of 200 rpm, a gear system was used to transmit the torque from the 2-hp motor. The runner consisted of a 50 mm (2 in.) diameter shaft and two gray cast iron grinding plates. Investigation (visual inspection, historical review, photographs, model testing of new plates, chemical analysis, hardness testing, optical macrographs, and optical micrographs) supported the conclusion that the primary feed material was harder than the grinding plates, causing wear and eventual failure. Recommendations included reducing the clearance between the flutes and possible material changes.
Book Chapter
Failures Related to Castings
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
... of ductile cast iron Black spots G 142 (a) Inclusions in the form of oxide skins, most often causing a localized seam Oxide inclusion or skins, seams G 143 (a) Folded films of graphitic luster in the wall of the casting Lustrous carbon films, or kish tracks G 144 Hard inclusions...
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Book
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.9781627083294
EISBN: 978-1-62708-329-4
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006778
EISBN: 978-1-62708-295-2
... images of dimple-rupture fractures. (a) Fracture of low-alloy medium-carbon steel bolt (SAE grade 5). Original magnification: 1750×. (b) Equiaxed tensile dimples originating around the graphite nodules of ASTM 60-45-10 ductile iron. Original magnification: 350×. (c) Parabolic shear dimples in cast Ti-6Al...
Abstract
This article aims to identify and illustrate the types of overload failures, which are categorized as failures due to insufficient material strength and underdesign, failures due to stress concentration and material defects, and failures due to material alteration. It describes the general aspects of fracture modes and mechanisms. The article briefly reviews some mechanistic aspects of ductile and brittle crack propagation, including discussion on mixed-mode cracking. Factors associated with overload failures are discussed, and, where appropriate, preventive steps for reducing the likelihood of overload fractures are included. The article focuses primarily on the contribution of embrittlement to overload failure. The embrittling phenomena are described and differentiated by their causes, effects, and remedial methods, so that failure characteristics can be directly compared during practical failure investigation. The article describes the effects of mechanical loading on a part in service and provides information on laboratory fracture examination.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003543
EISBN: 978-1-62708-180-1
... by cleavage in second-phase (silicon) particles and other second phases. Fig. 1 SEM images of dimple-rupture fractures. (a) Fracture of low-alloy medium-carbon steel bolt (SAE grade 5). 1750×. (b) Equiaxed tensile dimples originating around the graphite nodules of ASTM 60-45-10 ductile iron. 350×. (c...
Abstract
Overload failures refer to the ductile or brittle fracture of a material when stresses exceed the load-bearing capacity of a material. This article reviews some mechanistic aspects of ductile and brittle crack propagation, including a discussion on mixed-mode cracking, which may also occur when an overload failure is caused by a combination of ductile and brittle cracking mechanisms. It describes the general aspects of fracture modes and mechanisms. The article discusses some of the material, mechanical, and environmental factors that may be involved in determining the root cause of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals.
Book Chapter
Corrosion Failures of Industrial Refractories and Technical Ceramics
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003551
EISBN: 978-1-62708-180-1
... additions. With the new generations of “black refractories,” which contain 7% or more carbon materials (mainly natural graphite), adding one or two metallic additions to act as “antioxidants” or to protect carbon is mandatory. The technical ceramics, on the other hand, constitute an ill-defined class...
Abstract
This article provides a discussion on the structural ceramics used in gas turbine components, the automotive and aerospace industries, or as heat exchangers in various segments of the chemical and power generation industries. It covers the fundamental aspects of chemical corrosion and describes the corrosion resistance characteristics of specific classes of refractories and structural ceramics. The article also examines the prevention strategies that minimize corrosion failures of both classes of materials.
Book Chapter
High-Temperature Corrosion-Related Failures
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003555
EISBN: 978-1-62708-180-1
... in the nickel-iron matrix Deposition of graphite on the alloy surface in different orientations Growth of graphite into the metal phase by carbon atoms from the solid solution, attaching to graphite planes growing vertical to the metal surface Destruction of the metal phase by the inward-growing...
Abstract
High temperature corrosion may occur in numerous environments and is affected by factors such as temperature, alloy or protective coating composition, time, and gas composition. This article explains a number of potential degradation processes, namely, oxidation, carburization and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay coatings, thermal barrier coatings, and ceramic coatings.
Book Chapter
Impact Wear Failures
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006793
EISBN: 978-1-62708-295-2
... can promote wear. The increased use of a type of cast iron known as compacted graphite iron (CGI) often results from this conundrum, because it can offer increased strength, when compared to aluminum alloys, and reduced weight, when compared to other cast irons. Although denser than aluminum...
Abstract
Impact or percussive wear is defined as the wear of a solid surface that is due to percussion, which is a repetitive exposure to dynamic contact by another body. Impact wear, however, has many analogies to the field of erosive wear. The main difference is that, in impact wear situations, the bodies tend to be large and contact in a well-defined location in a controlled way, unlike erosion where the eroding particles are small and interact randomly with the target surface. This article describes some generic features and modes of impact wear of metals, ceramics, and polymers. It discusses the processes involved in testing and modeling of impact wear, and includes two case studies.
Book Chapter
Thermal Stresses and Physical Aging of Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006932
EISBN: 978-1-62708-395-9
...(a) 65 Polyphenylene sulfide(a) 49 Polyethylene, branched(a) 100–220 Polypropylene(a) 81–100 Polystyrene(a) 50–83 Polyvinyl chloride(a) 50–100 Glass(b) 8.3–9.7 Gold(b) 14.3 Cast iron(b) 10.6 Carbon graphite(b) 7.9 Hardened stainless steel(b) 17.3 (a) Source...
Abstract
Engineering plastics, as a general class of materials, are prone to the development of internal stresses which arise during processing or during servicing when parts are exposed to environments that impose deformation and/or temperature extremes. Thermal stresses are largely a consequence of high coefficients of thermal expansion and low thermal diffusivities. Although time-consuming techniques can be used to analyze thermal stresses, several useful qualitative tests are described in this article. The classification of internal stresses in plastic parts is covered. The article describes the effects of low thermal diffusivity and high thermal expansion properties, and the variation of mechanical properties with temperature. It discusses the combined effects of thermal stresses and orientation that result from processing conditions. The article also describes the effect of aging on properties of plastics. It explains the use of high-modulus graphite fibers in amorphous polymers.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001816
EISBN: 978-1-62708-180-1
... to form iron oxide: (Eq 1) 4 H 2 O + 3 Fe → 3 Fe 3 O 4 + 4 H 2 Furnace walls may also have other deposits from impurities in the boiler feedwater. Because these deposits and scale have a lower thermal conductivity than the steel tube, the net effect is an increase...
Abstract
This article explains the main types and characteristic causes of failures in boilers and other equipment in stationary and marine power plants that use steam as the working fluid with examples. It focuses on the distinctive features of each type that enable the failure analyst to determine the cause and suggest corrective action. The causes of failures include tube rupture, corrosion or scaling, fatigue, erosion, and stress-corrosion cracking. The article also describes the procedures for conducting a failure analysis.
Book Chapter
High-Temperature Corrosion-Related Failures
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006787
EISBN: 978-1-62708-295-2
..., which functions as a barrier for further carbon transfer Graphite nucleation and deposition, lowering the carbon activity to unity at the Fe 3 C-graphite interface and initiating cementite decomposition into graphite and iron, which is said to diffuse outward through the graphite to the graphite-gas...
Abstract
High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.
Book Chapter
Prevention of Machining-Related Failures
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006826
EISBN: 978-1-62708-329-4
... in a matrix of ferrite microstructure. Cutting tool life increased and short broken chips formed while machining the dual-phase low-carbon piston cups ( Ref 6 ). Often during dry machining of gray cast iron, graphite particles are pulled from the matrix microstructure. These graphite particles leave...
Abstract
The first part of this article focuses on two major forms of machining-related failures, namely machining workpiece (in-process) failures and machined part (in-service) failures. Discussion centers on machining conditions and metallurgical factors contributing to (in-process) workpiece failures, and undesired surface layers and metallurgical factors contributing to (in-service) machined part failures. The second part of the article discusses the effects of microstructure on machining failures and their preventive measures.
Book Chapter
Failure of Boilers and Related Equipment
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006825
EISBN: 978-1-62708-329-4
... to overheating, creep, graphitization, and situations having dissimilar-metal welds are generally characterized as sudden tube rupture or stress-rupture failures. An upset in any component of the heat-flow path across the tube during the course of boiler operation can disturb the heat balance, amounting...
Abstract
Failures in boilers and other equipment taking place in power plants that use steam as the working fluid are discussed in this article. The discussion is mainly concerned with failures in Rankine cycle systems that use fossil fuels as the primary heat source. The general procedure and techniques followed in failure investigation of boilers and related equipment are discussed. The article is framed with an objective to provide systematic information on various damage mechanisms leading to the failure of boiler tubes, headers, and drums, supplemented by representative case studies for a greater understanding of the respective damage mechanism.
Book Chapter
Failures of Pressure Vessels and Process Piping
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006812
EISBN: 978-1-62708-329-4
Abstract
This article discusses pressure vessels, piping, and associated pressure-boundary items of the types used in nuclear and conventional power plants, refineries, and chemical-processing plants. It begins by explaining the necessity of conducting a failure analysis, followed by the objectives of a failure analysis. Then, the article discusses the processes involved in failure analysis, including codes and standards. Next, fabrication flaws that can develop into failures of in-service pressure vessels and piping are covered. This is followed by sections discussing in-service mechanical and metallurgical failures, environment-assisted cracking failures, and other damage mechanisms that induce cracking failures. Finally, the article provides information on inspection practices.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006788
EISBN: 978-1-62708-295-2
..., identifying and applying preventive and mitigative measures, and monitoring the effectiveness of mitigation” ( Ref 3 ). The Scope of Microbial Activity Microorganisms can directly or indirectly affect the integrity of many materials. Most metals, including iron, copper, nickel, aluminum...
Abstract
This article focuses on the mechanisms of microbiologically influenced corrosion as a basis for discussion on the diagnosis, management, and prevention of biological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It begins with an overview of the scope of microbial activity and the corrosion process. Then, various mechanisms that influence corrosion in microorganisms are discussed. The focus is on the incremental activities needed to assess the role played by microorganisms, if any, in the overall scenario. The article presents a case study that illustrates opportunities to improve operating processes and procedures related to the management of system integrity. Industry experience with corrosion-resistant alloys of steel, copper, and aluminum is reviewed. The article ends with a discussion on monitoring and preventing microbiologically influenced corrosion failures.
Book Chapter
Abrasive Wear Failures
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003560
EISBN: 978-1-62708-180-1
... crushers, and earth-moving tools, the manganese steels have been partially displaced by low-alloy quenched-and-tempered steels and martensitic white irons ( Ref 10 ). High-Stress, Or Grinding, Abrasion High-stress, or grinding, abrasion occurs when abrasive particles are compressed between two solid...
Abstract
Wear, a form of surface deterioration, is a factor in a majority of component failures. This article is primarily concerned with abrasive wear mechanisms such as plastic deformation, cutting, and fragmentation which, at their core, stem from a difference in hardness between contacting surfaces. Adhesive wear, the type of wear that occurs between two mutually soluble materials, is also discussed, as is erosive wear, liquid impingement, and cavitation wear. The article also presents a procedure for failure analysis and provides a number of detailed examples, including jaw-type rock crusher wear, electronic circuit board drill wear, grinding plate wear failure analysis, impact wear of disk cutters, and identification of abrasive wear modes in martensitic steels.
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