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ferrite-martensite microstructure
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Published: 01 June 2019
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.auto.c9001156
EISBN: 978-1-62708-218-1
... affected zone. Figure 9 shows the ferrite/martensite microstructure in H. A. Z. near the fracture surface. This structure has a hardness of 425 HV whereas a significantly lower reading of 250 HV was obtained from a comparable position of the unbroken piston where the structure (see Fig. 10 ) was ferrite...
Abstract
The piston rod of a steering damper on a single decker bus fractured after 100,000 miles of service in the fully-extended left full-lock position. The steering damper, which is similar in shape and operation to a telescopic shock absorber, was secured by ball joints locked with slotted nuts. The steel piston rod fractured at the axle end leaving approximately 5 mm of rod welded to a securing ferrule. The failure was caused by a fatigue mechanism. Small surface cracks formed during welding in the heat-affected zone close to an unradiused shoulder in the piston. Under alternating stresses in normal service these cracks propagated through the piston rod made less tough by the extended weld heat-affected zone.
Image
in Fatigue Failure of a Steering Spindle on a Tricycle Agricultural Field Chemical Applicator
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1992
Fig. 9 Microstructure of the spindle, showing tempered martensite with some ferrite. Nital etch, 100×.
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Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c0048289
EISBN: 978-1-62708-234-1
.... The microstructure near the rupture edge was revealed by metallographic examination to consist of ferrite and acicular martensite or bainite. The microstructure and the observed lack of cold work indicated a temperature above the transformation temperature of 727 deg C had been reached. Swelling of the tubes...
Abstract
The center portions of two adjacent low-carbon steel boiler tubes (made to ASME SA-192 specifications) ruptured during a start-up period after seven months in service. It was indicated by reports that there had been sufficient water in the boiler two hours before start-up. The microstructure near the rupture edge was revealed by metallographic examination to consist of ferrite and acicular martensite or bainite. The microstructure and the observed lack of cold work indicated a temperature above the transformation temperature of 727 deg C had been reached. Swelling of the tubes was disclosed by the wall thickness and OD of the tubing. The tubes were concluded to have failed due to rapid overheating.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.aero.c0092142
EISBN: 978-1-62708-217-4
... islands in a matrix of tempered martensite. The microstructure of the opposite end contained no ferrite. Conclusions Bending had occurred in a portion of the slat track because service stresses had exceeded the strength of the material in a region of mixed martensite and ferrite. It was determined...
Abstract
During a routine inspection on an aircraft assembly line, an airframe attachment bolt was found to be broken. The bolt was one of 12 that attach the lower outboard longeron to the wing carry-through structure. Failure occurred on the right-hand forward bolt in this longeron splice attachment. The bolt was fabricated from PH13-8Mo stainless steel heat treated to have an ultimate tensile strength of 1517 to 1655 MPa (220 to 240 ksi). A water-soluble coolant was used in drilling the bolt hole where this fastener was inserted. Investigation (visual inspection, 265 SEM images, hardness testing, auger emission spectroscopy and secondary imaging spectroscopy, tensile testing, and chemical analysis) supported the conclusion that failure of the attachment bolt was caused by stress corrosion. The source of the corrosive media was the water-soluble coolant used in boring the bolt holes. Recommendations included inspecting for corrosion all the bolts that were installed using the water-soluble coolant at the spliced joint areas, rinsing all machined bolt holes with a noncorrosive agent, and installing new PH13-8Mo stainless steel bolts with a polysulfide wet sealant.
Series: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001077
EISBN: 978-1-62708-214-3
... associated with the fatigue initiation areas, mounted, polished, and etched. A thin band of ferrite below the wedge surface in both teeth was revealed in an otherwise martensitic structure ( Fig. 5 ). This microstructural inhomogeneity extended into the carburized case in the form of coarse martensite...
Abstract
The failure of a spiral bevel gear from the transmission of a helicopter was discovered when the transmission was removed after an in-flight incident. Two adjacent teeth from the carburized AISI 9310 steel gear were found to have undergone fatigue failure. Internal initiation occurred in a region depleted of chromium and nickel. This condition coincides with a microstructural inhomogeneity consisting of large, soft ferrite grains. Its origin was probably contamination of the solidifying ingot during the consumable vacuum arc remelting operation.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.steel.c9001159
EISBN: 978-1-62708-232-7
... coarse-grained and acicular, and the microstructure of the welding seam had become predominantly martensitic as a result of the mixing of the weld metal with the fused pipe material. The chrome steel pipe had become partially transformed to martensite or bainite at the transition to the weld. Thus...
Abstract
A recuperator used for preheating the combustion air for a rolling mill furnace failed after a relatively short service time because of leakage of the pipes in the colder part. The 6 % chrome steel pipes used for the warmer part connected by means of welding with austenitic electrodes to the unalloyed mild steel pipe of larger diam. Visual inspection showed corrosion and deep, trench-like erosion over the entire circumference of the seam on the side of the thicker mild steel pipe. Examination using the V2-A solution for picral etch showed the microstructure of the unalloyed pipe had become coarse-grained and acicular, and the microstructure of the welding seam had become predominantly martensitic as a result of the mixing of the weld metal with the fused pipe material. The chrome steel pipe had become partially transformed to martensite or bainite at the transition to the weld. Thus, the failure occurred due to typical contact corrosion wherein the alloyed welding seam represented the less noble electrode. The martensitic structure may have contributed to the failure as well. Due to the typical nature of the failure, no recommendations were made.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.petrol.c9001592
EISBN: 978-1-62708-228-0
... a weaker resistance to corrosion affecting the rod life. Non-metallic inclusions are a pitting preferential site leading to fatigue crack initiation. Heterogeneous microstructure as banded martensite and ferrite/pearlite decreases the ductility of the material affecting the fatigue propagation resistance...
Abstract
Sucker-rod pumps are operating in very aggressive environments in oil well production. The combined effect of a corrosive environment and significant mechanical loads contribute to frequent cases of failure of the rod string during operation. Standards and recommendations have been developed to control and avoid those failures. This study presents various failure cases of sucker rods in different applications. The heat treatment of the steel material and the resulting microstructure are an important factor in the behavior of the sucker rod. A spheroidized microstructure presents a weaker resistance to corrosion affecting the rod life. Non-metallic inclusions are a pitting preferential site leading to fatigue crack initiation. Heterogeneous microstructure as banded martensite and ferrite/pearlite decreases the ductility of the material affecting the fatigue propagation resistance.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001336
EISBN: 978-1-62708-215-0
.... It was discovered that the new stock pipes were not solution annealed after forming. The new vendor had incorrectly ascertained that their new-generation forming equipment would not cold work the pipe outer bends enough to form martensitic areas. The austenite-ferrite microstructurally induced galvanic corrosion...
Abstract
Catastrophic pitting corrosion occurred in type 304L stainless steel pipe flange assemblies in an industrial food processor. During regular service the pumped medium was pureed vegetables. In situ maintenance procedures included cleaning of the assemblies with a sodium hypochlorite solution. It was determined that the assemblies failed due to an austenite-martensite galvanic couple activated by a chlorine bearing electrolyte. The martensitic areas resulted from a transformation during cold-forming operations. Solution annealing after forming, revision of the design of the pipe flange assemblies to eliminate the forming operation, and removal of the source of chlorine were recommended.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c9001207
EISBN: 978-1-62708-235-8
... in Fig. 6 is free of ferrite, thus approximately eutectoid; the microstructure consists of pearlite and martensite with remnants of austenite. Figure 7 reproduces the microstructure of a location with hyper-eutectoid carbon content. It consists of secondary cementite in the shape of long needles...
Abstract
Pipes made of low-carbon Thomas steel had been welded longitudinally employing the carbon-arc process with bare electrode wire made for argon-shielded arc welding. Difficulties were encountered during the cutting of threads because of the presence of hard spots. Microstructural examination showed welding conditions were such that a carburizing atmosphere developed, which led to an increase in carbon content and hardening at certain locations such as terminal bells and lap joints. This explained the processing difficulties during the threading operation.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001333
EISBN: 978-1-62708-215-0
... of tempered martensite and ferrite ( Fig. 6 ), indicating that this area of the tube had been heated to a high enough temperature to fully austenitize, and then had been rapidly quenched to form martensite. No evidence of melting was observed. The microstructure changed gradually with distance from...
Abstract
A low-carbon steel (St35.8) tube in a phthalic anhydride reactor system failed. Visual and stereomicroscopic examination of fracture surfaces revealed heavy oxide/deposits on the outer surface of the tube, tube wall thinning in the area of the fracture, and discolorations and oxides/deposits on the inner surface. Cross sections from the fracture surface were metallographically examined, and the deposits were analyzed. It was determined that the tube had thinned from the inner surface because of a localized overheating condition (probably resulting from a runaway chemical reaction within the tube) and then fractured, which allowed molten salt to flow into the tube.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.usage.c9001249
EISBN: 978-1-62708-236-5
... through flange Smeared metal on the inner wall. Etched (CuSO 4 + HCl + H 2 O). 15 × The microstructure shows that the cast material is relatively pure and that all the inclusions are oxidic (essentially chromium oxide). The original microstructure outside the heat affected zone consists of ferrite...
Abstract
The flanged bearing bush carrying the drive shaft of a feed pump suddenly fractured after about two years of service. The chemical composition was normal for high chromium ledeburitic cast steel, which was corrosion and wear resistant as well as refractory. For unknown reasons the rotating shaft came into direct contact with the flange. Mechanical friction caused a rise in temperature on both contact surfaces. This mutual contact lasted long enough for the temperature in the contact zone to exceed 1200 deg C, at which the flange material became softened or molten. As a result, considerable structural changes took place on the inner wall of the flange. Thermal stresses and excessive mechanical loads due to smearing of the flange material then led to fracture of the flange.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006816
EISBN: 978-1-62708-329-4
... 7 shows experimentally measured Ac 3 temperatures for 4130 steel with three starting microstructures produced by annealing (ferrite and widely dispersed carbides) or by quenching and tempering at either 205 or 675 °C (400 or 1250 °F) to produce two different degrees of tempered martensite...
Abstract
This article introduces some of the general sources of heat treating problems with particular emphasis on problems caused by the actual heat treating process and the significant thermal and transformation stresses within a heat treated part. It addresses the design and material factors that cause a part to fail during heat treatment. The article discusses the problems associated with heating and furnaces, quenching media, quenching stresses, hardenability, tempering, carburizing, carbonitriding, and nitriding as well as potential stainless steel problems and problems associated with nonferrous heat treatments. The processes involved in cold working of certain ferrous and nonferrous alloys are also covered.
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Published: 01 December 1993
Fig. 6 Photomicrographs showing the typical microstructure of the impeller at an undamaged area. The microstructure consists of tempered martensite, alloy carbides, ferrite, and nonmetallic inclusions. Etched in Vilella's reagant. (a) 77×. (b) 616×
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Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001800
EISBN: 978-1-62708-241-9
... and decreasing grain size inward from the surface Fig. 6 SEM image of a remelted, arc-damage area at one fracture origin (arrow) Fig. 7 Detail of one remelt area at a fatigue origin Fig. 4 Longitudinal microstructure of a typical spring wire, exhibiting highly deformed ferrite...
Abstract
An electric transport vehicle, similar to an electric trolley or subway rail car, experienced frequent breakdowns due to in-service fractures of torsion springs that support the weight of an overhead electric pickup assembly. Scanning electron microscopy and metallographic examinations determined that the fractures stemmed from electric arc damage. Intergranular quench cracks in the transformed untempered martensite on the surface of the spring provided crack initiations that propagated during operation causing fatigue fracture.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c0047991
EISBN: 978-1-62708-225-9
... in the metal being relatively soft. The microstructure of the material in the outer ring adjacent to the raceway ( Fig. 1c ) was a mixture of white ferrite, scattered patches of pearlite, and martensite, which showed that the steel had been improperly austenitized, producing very low hardness...
Abstract
Deformation, surface cracking, and spalling on the raceway of the outer ring (made of 4140 steel) of a large bearing caused it to be replaced from a radar antenna. The raceway surfaces were to be flame hardened to 55 HRC minimum and 50 HRC 3.2 mm below the surface, according to specifications. Samples from both the inner and outer rings were examined. A much lower hardness (25.2 to 18.9 HRC) was indicated during a vertical traverse 4.1 cm from the outer surface of the outer ring while slightly lower hardness values (46.8 to 54.8 HRC) were seen on the hardness traverse on the inner ring raceway. The lower hardness values were attributed to improper flame hardening. It was confirmed by metallographic examination of a 3% nital etched sample that the inner ring (tempered martensite and ferrite) and the outer ring (ferrite, scattered patches of pearlite, and martensite) were not properly austenitized. Displacement of metal on the outer raceway was revealed by elongation of grain structure. It was concluded that the failure of the raceway surface was due to incomplete austenitization caused by the improper heat treatment during flame hardening process.
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in Hydrogen-Assisted Fracture of a 17-4PH Airplane Wing Component
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1992
Fig. 8 Micrograph of microetched heat-treated microstructure, showing tempered martensite and ferrite stringers.
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in Corrosion Fatigue Failure of Stainless Steel Load Cells in a Milk Storage Tank
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1993
Fig. 8 Microstructure of load cell, showing tempered martensite containing carbides and/or ferrite. Etched with Kelling's reagent
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Published: 01 December 1993
Fig. 6 Microstructure of region A in Fig. 5 , consisting of tempered martensite and ferrite. Nital etch. (a) 268×. (b) 610×
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in Alloy 430 Ferritic Stainless Steel Welds Fail due to Stress-Corrosion Cracking in Heat-Recovery Steam Generator
> ASM Failure Analysis Case Histories: Power Generating Equipment
Published: 01 June 2019
Fig. 6 Autogenous weld microstructure, ASTM A-268, Grade 430 tubing; light phase—ferrite, dark phase—martensite, Vilella's etch, (a) 50× and (b) 500× 11
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