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Published: 30 August 2021
Image
Variation of elastic modulus with the temperature for a typical amorphous p...
Available to PurchasePublished: 15 May 2022
Fig. 1 Variation of elastic modulus with the temperature for a typical amorphous polymer. T g is the glass-transition temperature, and the horizontal dashed line shows the effect of slight cross-linking.
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in Effects of Composition, Processing, and Structure on Properties of Engineering Plastics
> Characterization and Failure Analysis of Plastics
Published: 15 May 2022
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006944
EISBN: 978-1-62708-395-9
... crazing and fracture in polymeric materials, with a review of the behavior of the elastic modulus as a function of temperature or time parameters, emphasizing the importance of the viscoelastic nature of their deformation and fracture. The discussion covers the behavior of polymers under stress, provides...
Abstract
The discussion on the fracture of solid materials, both metals and polymers, customarily begins with a presentation of the stress-strain behavior and of how various conditions such as temperature and strain-rate affect the mechanisms of deformation and fracture. This article describes crazing and fracture in polymeric materials, with a review of the behavior of the elastic modulus as a function of temperature or time parameters, emphasizing the importance of the viscoelastic nature of their deformation and fracture. The discussion covers the behavior of polymers under stress, provides information on ductile and brittle behaviors, and describes craze initiation in polymers and crack formation and fracture by crazing. Macroscopic permanent deformation of polymeric materials caused by shear-yielding and crazing, which eventually can result in fracture and failure, is also covered.
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Spring and dashpot models. (a) Linear elastic material with constant modulu...
Available to PurchasePublished: 15 May 2022
Fig. 1 Spring and dashpot models. (a) Linear elastic material with constant modulus slope, E. (b) Dashpot with linear liquid viscosity slope, η. Reprinted under the Creative Commons CC BY license from Ref 1
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A comparison of the DMA results, showing a loss of over 60% in the elastic ...
Available to PurchasePublished: 01 January 2002
Fig. 31 A comparison of the DMA results, showing a loss of over 60% in the elastic modulus as a result of the effects of the solvent
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A comparison of the DMA results, showing a loss of over 60% in the elastic ...
Available to Purchase
in Cracking of a Polyethylene Chemical Storage Vessel
> ASM Failure Analysis Case Histories: Chemical Processing Equipment
Published: 01 June 2019
Fig. 3 A comparison of the DMA results, showing a loss of over 60% in the elastic modulus as a result of the effects of the solvent
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Correlation between stretch-zone width (SZW, or δ) and fracture toughness n...
Available to PurchasePublished: 15 January 2021
Fig. 66 Correlation between stretch-zone width (SZW, or δ) and fracture toughness normalized by the elastic modulus, E . Source: Ref 2
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The correlation between the stretch zone width (SZW or δ) and fracture toug...
Available to PurchasePublished: 01 January 2002
Fig. 56 The correlation between the stretch zone width (SZW or δ) and fracture toughness normalized by the elastic modulus, E . Source: Ref 25
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Book Chapter
Fatigue Failures of Austenitic Stainless Steel Orthopedic Fixation Devices
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.med.c9001606
EISBN: 978-1-62708-226-6
... weeks or months, the fixation implant is usually surgically removed, because the presence of the higher-elastic-modulus metal support may hinder the repaired bone development if it is retained in place. From the mechanical/metallurgical perspective, in addition to the basic requirement of excellent...
Abstract
Failures of four different 300-series austenitic stainless steel biomedical fixation implants were examined. The device fractures were observed optically, and their surfaces were examined by scanning electron microscopy. Fractography identified fatigue to be the failure mode for all four of the implants. In every instance, the fatigue cracks initiated from the attachment screw holes at the reduced cross sections of the implants. Two fixation implant designs were analyzed using finite-element modeling. This analysis confirmed the presence of severe stress concentrations adjacent to the attachment screw holes, the fatigue crack initiation sites. Conclusions were reached regarding the design of these types of implant fixation devices, particularly the location of the attachment screw holes. The use of austenitic stainless steel for these biomedical implant devices is also addressed. Recommendations to improve the fixation implant design are suggested, and the potential benefits of the substitution of titanium or a titanium alloy for the stainless steel are discussed.
Book Chapter
Cracking of a Polyethylene Chemical Storage Vessel
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.chem.c0090454
EISBN: 978-1-62708-220-4
... was analyzed in two conditions. Material samples representing the vessel material in the as-molded condition as well as material from the failed vessel were evaluated. A comparison of the DMA results showed that in the saturated, equilibrium state, the HDPE resin lost over 60% of its elastic modulus at room...
Abstract
A chemical storage vessel failed while in service. The failure occurred as cracking through the vessel wall, resulting in leakage of the fluid. The tank had been molded from a high-density polyethylene (HDPE) resin. The material held within the vessel was an aromatic hydrocarbon-based solvent. Investigation (visual inspection, stereomicroscopic examination, 20x/100x SEM images, micro-FTIR in the ATR mode, and analysis using DSC and TGA) supported the conclusion that the chemical storage vessel failed via a creep mechanism associated with the exertion of relatively low stresses. The source of the stress was thought to be molded-in residual stresses associated with uneven shrinkage. This was suggested by obvious distortion evident on cutting the vessel. Relatively high specific gravity and the elevated heat of fusion indicated that the material had a high level of crystallinity. In general, increased levels of crystallinity result in higher levels of molded-in stress and the corresponding warpage. The significant reduction in the modulus of the HDPE material, which accompanied the saturation of the resin with the aromatic hydrocarbon-based solvent, substantially decreased the creep resistance of the material and accelerated the failure.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006941
EISBN: 978-1-62708-395-9
... ultimately, one of fracture. If the material is a solid, then the simplest relationship between force and deformation is one in which the applied stress is proportional to the total resultant strain. The proportionality factor is referred to as a modulus of elasticity in the solid material; it may be used...
Abstract
This article describes the viscoelastic behavior of plastics in their solid state only, from the standpoint of the material deforming without fracturing. The consequences of viscoelasticity on the mechanical properties of plastics are described, especially in terms of time-dependencies, as well as the dependence of the viscoelastic character of a plastic on chemical, physical, and compositional variables. By examining the viscoelastic behavior of plastics, the information obtained are then applied in situations in which it may be important to anticipate the long-term properties of a material. This includes assessing the extent of stress decay in materials that are pre-stressed, the noise and vibration transmission characteristics of a material, the amount of heat build-up in a material subjected to cyclic deformation, and the extent a material can recover from any prior deformation. Several qualitative graphs are presented, which highlights the possible differences in the viscoelastic behavior that can exist among plastics.
Book Chapter
Failure Analysis of Gas Turbine Last Stage Bucket Made of Udimet 500 Superalloy
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.power.c9001602
EISBN: 978-1-62708-229-7
... of columnar grains, the crack is propagated along a continuous straight line without any element that retards propagation. In addition, the columnar grains present an elastic modulus (E), 30 to 40% lower than the equiaxial grains in the orientation parallel to the solidification direction <001>. 9...
Abstract
This article presents a failure analysis of 37.5 mW gas turbine third stage buckets made of Udimet 500 superalloy. The buckets experienced repetitive integral tip shroud fractures assisted by a low temperature (type II) hot corrosion. A detailed analysis was carried out on elements thought to have influenced the failure process: a) the stress increase from the loss of a load bearing cross-sectional area of the bucket tip shroud by the conversion of metal to the corrosion product (scale), b) influence of the tip shroud microstructure (e.g., a presence of equiaxed and columnar grains, their distribution and orientation), c) evidence of the transgranular initiation, and d) intergranular creep mechanism propagation. The most probable cause of the bucket damage was the combination of increased stresses due to corrosion-induced thinning of the tip shroud and unfavorable microstructures in the tip shroud region.
Book Chapter
Creep, Stress Relaxation, and Yielding Mechanisms
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006934
EISBN: 978-1-62708-395-9
... equation: (Eq 1) σ = E ε where E is the modulus of elasticity ( Fig. 1a ). Fig. 1 Creep-recovery response of (a) Hookean model and (b) Newtonian model On the other hand, the deformation of an ideal viscous material occurs as the stress is maintained. In this case, the strain...
Abstract
This article describes the general aspects of creep, stress relaxation, and yielding for homogeneous polymers. It then presents creep failure mechanisms in polymers. The article discusses extrapolative methods for the prediction of long-term creep failure in polymer materials. Then, the widely used models to simulate the service life of polymers are highlighted. These include the Burgers power-law model, the Findley power-law model, the time-temperature superposition (or equivalence) principle (TTSP), and the time-stress superposition principle (TSSP). The Larson-Miller parametric method, one of the most common to describe the material deformation and rupture time, is also discussed.
Book Chapter
Analysis of Distortion and Deformation
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003573
EISBN: 978-1-62708-180-1
...) side ( Fig. 2 ). Fig. 2 Buckled flange (lower arrow) of an extruded aluminum section deliberately loaded with a lateral force (upper arrow). Source: Ref 3 . The buckling load depends only on the dimensions of the part and the modulus of elasticity of the material. Therefore, buckling...
Abstract
Distortion failure occurs when a structure or component is deformed so that it can no longer support the load it was intended to carry. Every structure has a load limit beyond which it is considered unsafe or unreliable. Estimation of load limits is an important aspect of design and is commonly computed by classical design or limit analysis. This article discusses the common aspects of failure by distortion with suitable examples. Analysis of a distortion failure often must be thorough and rigorous to determine the root cause of failure and to specify proper corrective action. The article summarizes the general process of distortion failure analysis. It also discusses three types of distortion failures that provide useful insights into the problems of analyzing unusual mechanisms of distortion. These include elastic distortion, ratcheting, and inelastic cyclic buckling.
Book Chapter
Analysis of Distortion and Deformation
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006797
EISBN: 978-1-62708-295-2
... section deliberately loaded with a lateral force (upper arrow). Source: Ref 4 . (b) Medium-length tube tested to buckling instability on special-purpose-designed test machine. Source: Ref 3 The buckling load depends only on the dimensions of the part and the modulus of elasticity...
Abstract
Distortion often is observed in the analysis of other types of failures, and consideration of the distortion can be an important part of the analysis. This article first considers that true distortion occurs when it was unexpected and in which the distortion is associated with a functional failure. Then, a more general consideration of distortion in failure analysis is introduced. Several common aspects of failure by distortion are discussed and suitable examples of distortion failures are presented for illustration. The article provides information on methods to compute load limits, errors in the specification of the material, and faulty process and their corrective measures to meet specifications. It discusses the general process of material failure analysis and special types of distortion and deformation failure.
Book Chapter
Mechanical Testing and Properties of Plastics—An Introduction
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006928
EISBN: 978-1-62708-395-9
... properties of plastics Material(a) Tensile strength Elongation, % Modulus of elasticity Compressive strength Modulus of rupture Hardness MPa ksi GPa 10 6 psi MPa ksi MPa ksi Thermosets EP, reinforced with glass cloth 350 51 … 175 25 410 59 485 70 … MF, alpha...
Abstract
This article briefly introduces some commonly used methods for mechanical testing. It describes the test methods and provides comparative data for the mechanical property tests. In addition, creep testing and dynamic mechanical analyses of viscoelastic plastics are also briefly described. The article discusses the processes involved in the short-term and long-term tensile testing of plastics. Information on the strength/modulus and deflection tests, impact toughness, hardness testing, and fatigue testing of plastics is also provided. The article describes tension testing of elastomers and fibers. It covers two basic methods to test the mechanical properties of fibers, namely the single-filament tension test and the tensile test of a yarn or a group of fibers.
Book Chapter
Effects of Composition, Processing, and Structure on Properties of Engineering Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006915
EISBN: 978-1-62708-395-9
..., and addresses related considerations such as melt viscosity and melt strength, crystallization, orientation, die swell, melt fracture, shrinkage, molded-in stress, and polymer degradation. composition elastic modulus engineering plastics polymer properties polymer structure shear rate...
Abstract
This article provides practical information and data on property development in engineering plastics. It discusses the effects of composition on submolecular and higher-order structure and the influence of plasticizers, additives, and blowing agents. It examines stress-strain curves corresponding to soft-and-weak, soft-and-tough, hard-and-brittle, and hard-and-tough plastics and temperature-modulus plots representative of polymers with different degrees of crystallinity, cross-linking, and polarity. It explains how viscosity varies with shear rate in polymer melts and how processes align with various regions of the viscosity curve. It discusses the concept of shear sensitivity, the nature of viscoelastic properties, and the electrical, chemical, and optical properties of different plastics. It also reviews plastic processing operations, including extrusion, injection molding, and thermoforming, and addresses related considerations such as melt viscosity and melt strength, crystallization, orientation, die swell, melt fracture, shrinkage, molded-in stress, and polymer degradation.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006930
EISBN: 978-1-62708-395-9
... = σ 0 sin ( ω t + δ ) τ = τ 0 sin ( ω t + δ ) P a ( = N / m 2 ) Storage modulus (elasticity) G ′ = ( σ 0 / γ 0 ) cos ( δ ) E ′ − ( τ 0 / γ 0 ) cos ( δ ) Pa Loss modulus (viscous nature...
Abstract
Rheology is defined as the study of the flow and deformation of matter. This article begins with an examination of flow behavior. It describes the geometries and methods employed for rheological testing of polymers in their molten state. It also discusses materials that are predominantly in the solid state and the methods employed for solids testing. Examples of unidirectional and dynamic oscillatory testing are provided for different mechanical behaviors.
Book
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.9781627081801
EISBN: 978-1-62708-180-1
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