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diffusional kinetics

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Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003546
EISBN: 978-1-62708-180-1
... kinetic equation (i.e., Eq. 1 ) applies. From an engineering point of view, Eq 3 can be represented by a set of parameters that can be experimentally derived from isothermal experiments: (Eq 4) N i = C 1 ( m , ν , T ) ⋅ exp B T eff ⋅ Δ ε p − β where C...
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006787
EISBN: 978-1-62708-295-2
... in corrosion mechanisms that complicate reaction kinetics and explanation of the reactions that occur. The reaction kinetics of high-temperature corrosion reactions are usually classified as linear, parabolic, logarithmic, or cubic ( Ref 1 ). However, high-temperature oxidation and corrosion processes can...
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003555
EISBN: 978-1-62708-180-1
... vol% O 2 . Alloys are protected, to varying degrees, by the oxide layer. The thickness of the oxide is proportional to the parabolic rate kinetics. Oxidation of carbon steels from air or steam forms an oxide scale along the metal surface that grows and thickens with time. Gas composition influences...