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Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001843
EISBN: 978-1-62708-241-9
... as the failure mechanism in the investigation. electrical connectors tin pest plating defect copper alpha tin x-ray diffraction temperature copper (copper contact alloy, general) tin-bismuth (tin-bismuth plating alloy, general) Introduction The element tin has three crystalline forms...
Abstract
The operator of an electric transit system purchased a large number of tin-plated copper connectors, putting some in service and others in reserve. Later, when some of the reserve connectors were inspected, the metal surfaces were covered with spots consisting of an ash-like powder and the plating material had separated from the substrate in many areas. Several connectors, including some that had been in service, were examined to determine what caused the change. The order stated that the connectors were to be coated with a layer of tin-bismuth (2% Bi) to guard against tin pest, a type of degradation that occurs at low temperatures. Based on the results of the investigation, which included SEM/EDS analysis, inductively coupled plasma spectroscopy, and x-ray diffraction, the metal surfaces contained less than 0.1% Bi and thus were not adequately protected against tin pest, which was confirmed as the failure mechanism in the investigation.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.design.c0091538
EISBN: 978-1-62708-233-4
... Abstract Electrical contact-finger retainers blanked and formed from annealed copper alloy C65500 (high-silicon bronze A) failed prematurely by cracking while in service in switchgear aboard seagoing vessels. In this service they were sheltered from the weather but subject to indirect exposure...
Abstract
Electrical contact-finger retainers blanked and formed from annealed copper alloy C65500 (high-silicon bronze A) failed prematurely by cracking while in service in switchgear aboard seagoing vessels. In this service they were sheltered from the weather but subject to indirect exposure to the sea air. About 50% of the contact-finger retainers failed after five to eight months of service aboard ship. Investigation (visual inspection, 250x images etched with equal parts NH4OH and H2O2, emission spectrographic analysis, and stereoscopic views) supported the conclusion that the cracking was produced by stress corrosion as the combined result of: residual forming and service stresses; the concentration of tensile stress at outer square corners of the pierced slots; and preferential corrosive attack along the grain boundaries as a result of high humidity and occasional condensation of moisture containing a fairly high concentration of chlorides (seawater typically contains about 19,000 ppm of dissolved chlorides) and traces of ammonia. Recommendations included redesign of the slots, shot-blasting the formed retainers, and changing the material to a different type of silicon bronze-copper alloy C64700.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.power.c9001484
EISBN: 978-1-62708-229-7
... Abstract Fusing of the switch contacts of a boiler feed pump drive motor led to the failure of a turbine. After rubbing of most of the Ni-Cr steel LP wheels had occurred, due to the admission of water carried over with the steam, a copper-rich alloy from the interstage gland rings melted...
Abstract
Fusing of the switch contacts of a boiler feed pump drive motor led to the failure of a turbine. After rubbing of most of the Ni-Cr steel LP wheels had occurred, due to the admission of water carried over with the steam, a copper-rich alloy from the interstage gland rings melted, penetrated the wheel material, and gave rise to radial and circumferential cracking in four of the LP wheels. It was concluded that when the rotor moved axially and the wheels came into contact with the diaphragms there was a tendency for the former to dish, with the development of both radial and circumferential tensile stresses on the side in contact with the adjacent diaphragm. In the presence of the molten copper-rich alloy, these stresses gave rise to severe hot cracking.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001809
EISBN: 978-1-62708-180-1
... Abstract This article discusses the classification of sliding bearings and describes the major groups of soft metal bearing materials: babbitts, copper-lead bearing alloys, bronze, and aluminum alloys. It provides a discussion on the methods for fluid-film lubrication in bearings. The article...
Abstract
This article discusses the classification of sliding bearings and describes the major groups of soft metal bearing materials: babbitts, copper-lead bearing alloys, bronze, and aluminum alloys. It provides a discussion on the methods for fluid-film lubrication in bearings. The article presents the variables of interest for a rotating shaft and the load-carrying capacity and surface roughness of bearings. Grooves and depressions are often provided in bearing surfaces to supply or feed lubricant to the load-carrying regions. The article explains the effect of contaminants in bearings and presents the steps for failure analysis of sliding bearings. It also reviews the factors responsible for bearing failure with examples.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001822
EISBN: 978-1-62708-180-1
... that molten copper, or copper alloys, will embrittle steels under the proper conditions. The steel must be austenitic with tensile stresses present. Carbon steels contacting liquid copper will be heated into the fully austenitic range. Liquid copper will penetrate the austenitic grain boundaries. The speed...
Abstract
This article provides a background of friction-bearing failures due to overheating. The failures of locomotive axles caused by overheated traction-motor support bearings are discussed. The article also describes liquid-metal embrittlement (LME) in steel. It examines the results of various axle studies, with illustrations and concludes with information on the simulation of the LME mechanism.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.rail.c9001719
EISBN: 978-1-62708-231-0
... are connected in series with the main generator. A wick assembly in each of the bearings lubricates the part of the axle that is in contact with the bearing. This wick assembly continually brushes lubricant onto the axle. A pinion gear from the traction motor connects to a mating gear on the axle causing...
Abstract
Metallography is an important component of failure analysis. In the case of a liquid metal embrittlement (LME) failure it is usually conclusive if a third phase constituent can be formed inside of the cracks after failure. In the case where it is necessary to characterize the third phase material, one can use various x-ray spectrographic techniques in conjunction with a scanning electron microscope (SEM). This study describes those metallographic and SEM analysis techniques for determining the mode of failure for a locomotive traction motor by LME.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001836
EISBN: 978-1-62708-241-9
... in the longitudinal direction of the pipe axis ( Fig. 9 ). Fig. 9 Golden-yellow color copper-alloy streaks on pipe OD surface The pipe OD surface which corresponds to the plate’s bottom surface comes in contact with the Cu-alloy plates used at the JCO mill. The plate is entered in the transverse...
Abstract
An investigation was conducted to determine why 16 out of 139 pipe bends cracked during hot induction bending. The pipe conformed to API 5L X65 PSL2 line pipe standards and measured 1016 mm (40 in.) in diam with a wall thickness of 18.5 mm. A metallurgical cross section was removed along a crack on the extrados to document the crack morphology using optical microscopy. In addition to cracking, golden-yellow streaks were visible at the extrados, and the composition was examined using scanning electron microscopy with energy dispersive spectroscopy. Based on the results, investigators concluded the pipe was contaminated with copper at the mill were it was produced.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006827
EISBN: 978-1-62708-329-4
.... In general, a narrow contact angle between the solder and the substrate is indicative of good wetting and could be used as a quick check for solderability. Note that these surface energies are not constant and are a function of various parameters, such as temperature, alloying elements, contaminants...
Abstract
Due to the recent requirement of higher integration density, solder joints are getting smaller in electronic product assemblies, which makes the joints more vulnerable to failure. Thus, the root-cause failure analysis for the solder joints becomes important to prevent failure at the assembly level. This article covers the properties of solder alloys and the corresponding intermetallic compounds. It includes the dominant failure modes introduced during the solder joint manufacturing process and in field-use applications. The corresponding failure mechanism and root-cause analysis are also presented. The article introduces several frequently used methods for solder joint failure detection, prevention, and isolation (identification for the failed location).
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006806
EISBN: 978-1-62708-329-4
... to a substantial increase in friction and wear. Bearing Materials This portion of the article provides an overview of bearing materials ( Ref 2 ). Metals such as tin alloy, copper alloy, lead-base Babbitt, and nodular cast iron have been used as bearing materials for a very long time. These materials have...
Abstract
A mechanical part, which supports the moving part, is termed a mechanical bearing and can be classified into rolling (ball or roller) bearings and sliding bearings. This article discusses the failures of sliding bearings. It first describes the geometry of sliding bearings, next provides an overview of bearing materials, and then presents the various lubrication mechanisms: hydrostatic, hydrodynamic, boundary lubrication, elastohydrodynamic, and squeeze-film lubrication. The article describes the effect of debris and contaminant particles in bearings. The steps involved in failure analysis of sliding bearings are also covered. Finally, the article discusses wear-damage mechanisms from the standpoint of bearing design.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003548
EISBN: 978-1-62708-180-1
... in galvanic couples with other metals or alloys. This effect is observed with gold and silver coatings on copper, nickel, aluminum, and their alloys. Uniform Corrosion Uniform corrosion, or general corrosion, is a corrosion process exhibiting uniform thinning that proceeds without appreciable localized...
Abstract
This article addresses the forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. It describes the mechanisms of corrosive attack for specific forms of corrosion such as galvanic corrosion, uniform corrosion, pitting and crevice corrosion, intergranular corrosion, and velocity-affected corrosion. The article contains a table that lists combinations of alloys and environments subjected to selective leaching and the elements removed by leaching.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001817
EISBN: 978-1-62708-180-1
...× Figure 7(a) and (b) show a section through a heat-exchanger tube made of copper alloy C71000 (copper nickel, 20%). Water passing through the tube and steam in contact with the outer surface caused denickelification of the alloy at both inner and outer surfaces. The dealloying occurred along the grain...
Abstract
This article describes the characteristics of tubing of heat exchangers with respect to general corrosion, stress-corrosion cracking, selective leaching, and oxygen-cell attack, with examples. It illustrates the examination of failed parts of heat exchangers by using sample selection, visual examination, microscopic examination, chemical analysis, and mechanical tests. The article explains corrosion fatigue of tubing of heat exchangers caused by aggressive environment and cyclic stress. It also discusses the effects of design, welding practices, and elevated temperatures on the failures of heat exchangers.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006783
EISBN: 978-1-62708-295-2
... such as copper, mercury, or lead. Some aluminum alloys are used for sacrificial anodes in seawater. An active, anodic alloy is used to clad aluminum, protecting it against pitting in some applications. Contact of aluminum with more cathodic metals should be avoided in any environment in which aluminum...
Abstract
Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006786
EISBN: 978-1-62708-295-2
... the simultaneous presence of: A susceptible structural metallic material Surface wetting by a specific embrittling metal or alloy Tensile stress, either applied or residual Some general characteristics of LMIE and SMIE are: Embrittlement is manifested as a loss in ductility and a decrease...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or the fracture stress of a solid metal is reduced by surface contact with another metal in either the liquid or solid form. This article summarizes some of the characteristics of liquid-metal- and solid-metal-induced embrittlement. This phenomenon shares many of these characteristics with other modes of environmentally induced cracking, such as hydrogen embrittlement and stress-corrosion cracking. The discussion covers the occurrence, failure analysis, and service failures of the embrittlement. The article also briefly reviews some commercial alloy systems in which liquid-metal-induced embrittlement or solid-metal-induced embrittlement has been documented and describes some examples of cracking due to these phenomena, either in manufacturing or in service.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003554
EISBN: 978-1-62708-180-1
... the indicated base metals Structural alloy base metal Embrittling metal Aluminum Hg, Ga, Na, In, Sn, Bi, Cd, Pb, Zn Copper Hg, Ga, In, Li, Bi, Cd, Pb Nickel Hg, In, Li, Sn, Pb, Zn, Ag Steels Ferritic/martensitic Hg, Ga, In, Li, Sn, Cd, Pb, Zn, Te, Cu Austenitic Hg, Li, Zn, Cu...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or fracture stress of a solid metal is reduced by surface contact with another metal in either liquid or solid form. This article summarizes the characteristics of solid metal induced embrittlement (SMIE) and liquid metal induced embrittlement (LMIE). It describes the unique features that assist in arriving at a clear conclusion whether SMIE or LMIE is the most probable cause of the problem. The article briefly reviews some commercial alloy systems where LMIE or SMIE has been documented. It also provides some examples of cracking due to these phenomena, either in manufacturing or in service.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c9001530
EISBN: 978-1-62708-225-9
... the establishment of a well-protected transfer layer and leads to rapid wear. Failure Leaded bronze bearing Metallic wear debris Cu-7.6Sn-17.4Pb Cu-6.6Sn-5.8Pb (Other, miscellaneous, or unspecified) wear 1. Introduction Copper-based alloys have been of great practical importance in industrial...
Abstract
This paper describes an investigation on the failure of a large leaded bronze bearing that supports a nine-ton roller of a plastic calendering machine. At the end of the normal service life of a good bearing, which lasted for seven years, a new bearing was installed. However the new one failed catastrophically within a few days, generating a huge amount of metallic wear debris and causing pitting on the surface of the cast iron roller. Following the failure, samples were collected from both good and failed bearings. The samples were analyzed chemically and their microstructures examined. Both samples were subjected to accelerated wear tests in a laboratory type pin-on-disk apparatus. During the tests, the bearing materials acted as pins, which were pressed against a rotating cast iron disk. The wear behaviors of both bearing materials were studied using weight loss measurement. The worn surfaces of samples and the wear debris were examined by light optical microscope, SEM, and energy-dispersive x-ray microanalyzer. It was found that the laboratory pin-on-disk wear data correlated well with the plant experience. It is suggested that the higher lead content ~18%) of the good bearing compared with 7% lead of the failed bearing helped to establish a protective transfer layer on the worn surface. This transfer layer reduced metal-to-metal contact between the bearing and the roller and resulted in a lower wear rate. The lower lead content of the failed bearing does not allow the establishment of a well-protected transfer layer and leads to rapid wear.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001385
EISBN: 978-1-62708-215-0
... for use with aluminum shall be coated to inhibit oxidation and contact with copper. The coating must be electrically conductive. Tin has been found to be acceptable. These standards also prescribe heat cycling tests, tightening torques for various types of screws, test currents, and pullout tests...
Abstract
Three instances involving the failure of aluminum wiring at the service entrance to single-family homes are discussed. Arcing led to a fire which severely damaged a home in one case. In a second, the failure sequence was initiated by water intrusion into the service entrance electrical box during construction of the home. In the third, failure was caused by a marginal installation. Strict adherence to all applicable electrical codes and standards is critical in the case of aluminum wiring. Electrical components not specifically designed for aluminum must never be used with this type of wiring. All doors, panels and similar portions of electrical boxes should be secured to prevent damage to surroundings in the event of an electrical fault. If symptoms of arcing are observed, professional service should be sought. The latest designs of connectors for use with aluminum wiring are less susceptible to deviations in installation practice.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006828
EISBN: 978-1-62708-329-4
..., mercury, zinc, and certain silver brazing alloys ( Ref 14 ). Silver and cadmium have also been demonstrated to cause SMIE in titanium. Recent studies in 2019 have shown that both Ti-8Al-1Mo-1V and Ti-6Al-2Sn-4Zr-2Mo are susceptible to SMIE in contact with copper, whereas SMIE was not observed with Ti-6Al...
Abstract
The various methods of furnace, torch, induction, resistance, dip, and laser brazing are used to produce a wide range of highly reliable brazed assemblies. However, imperfections that can lead to braze failure may result if proper attention is not paid to the physical properties of the material, joint design, prebraze cleaning, brazing procedures, postbraze cleaning, and quality control. Factors that must be considered include brazeability of the base metals; joint design and fit-up; filler-metal selection; prebraze cleaning; brazing temperature, time, atmosphere, or flux; conditions of the faying surfaces; postbraze cleaning; and service conditions. This article focuses on the advantages, limitations, sources of failure, and anomalies resulting from the brazing process. It discusses the processes involved in the testing and inspection required of the braze joint or assembly.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003553
EISBN: 978-1-62708-180-1
... blanked and formed from annealed copper alloy C65500 (high-silicon bronze A) failed prematurely by cracking while in service in switchgear aboard seagoing vessels. In this service they were sheltered from the weather but subject to indirect exposure to the sea air. About 50% of the contact-finger...
Abstract
This article commences with a discussion on the characteristics of stress-corrosion cracking (SCC) and describes crack initiation and propagation during SCC. It reviews the various mechanisms of SCC and addresses electrochemical and stress-sorption theories. The article explains the SCC, which occurs due to welding, metalworking process, and stress concentration, including options for investigation and corrective measures. It describes the sources of stresses in service and the effect of composition and metal structure on the susceptibility of SCC. The article provides information on specific ions and substances, service environments, and preservice environments responsible for SCC. It details the analysis of SCC failures, which include on-site examination, sampling, observation of fracture surface characteristics, macroscopic examination, microscopic examination, chemical analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006813
EISBN: 978-1-62708-329-4
... thickness and were made of copper alloy C70600 (copper nickel, 10%). This alloy is generally considered to have excellent corrosion resistance. Five of the tubes that were leaking were removed and sectioned lengthwise. One section of each tube was sent to the manufacturer of the cooler, and the other...
Abstract
Heat exchangers are devices used to transfer thermal energy between two or more fluids, between a solid surface and a fluid, or between a solid particulate and a fluid at different temperatures. This article first addresses the causes of failures in heat exchangers. It then provides a description of heat-transfer surface area, discussing the design of the tubular heat exchanger. Next, the article discusses the processes involved in the examination of failed parts. Finally, it describes the most important types of corrosion, including uniform, galvanic, pitting, stress, and erosion corrosion.
Series: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001103
EISBN: 978-1-62708-214-3
... by changing the bolt material to an alloy that offers more resistance to this failure mechanism. Although little guidance exists in the literature, it is generally true that resistance to SCC increases with an increase in copper content. Therefore, a high-tensile-strength nickel-aluminum bronze that does...
Abstract
An aluminum bronze propeller tap bolt from a twin-screw vessel fractured just below the bolt head. Liquid penetrant testing revealed a large network of cracks that extended radially from sites in and just below the bolthead. Metallographic analysis indicated that the tap bolt failed by stress-corrosion cracking. It was surmised that seawater or some other corrosive substance was present in sufficient quantity to induce intergranular cracking at regions of high stress concentration. It was recommended that all tap bolts be replaced with new bolts made from an alloy with a higher copper content and at least the same yield strength. Steps to exclude seawater and any possible source of ammonia from the bolt shank were also suggested.
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