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Book Chapter
Effects of Composition, Processing, and Structure on Properties of Engineering Plastics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006915
EISBN: 978-1-62708-395-9
... Abstract This article provides practical information and data on property development in engineering plastics. It discusses the effects of composition on submolecular and higher-order structure and the influence of plasticizers, additives, and blowing agents. It examines stress-strain curves...
Abstract
This article provides practical information and data on property development in engineering plastics. It discusses the effects of composition on submolecular and higher-order structure and the influence of plasticizers, additives, and blowing agents. It examines stress-strain curves corresponding to soft-and-weak, soft-and-tough, hard-and-brittle, and hard-and-tough plastics and temperature-modulus plots representative of polymers with different degrees of crystallinity, cross-linking, and polarity. It explains how viscosity varies with shear rate in polymer melts and how processes align with various regions of the viscosity curve. It discusses the concept of shear sensitivity, the nature of viscoelastic properties, and the electrical, chemical, and optical properties of different plastics. It also reviews plastic processing operations, including extrusion, injection molding, and thermoforming, and addresses related considerations such as melt viscosity and melt strength, crystallization, orientation, die swell, melt fracture, shrinkage, molded-in stress, and polymer degradation.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006759
EISBN: 978-1-62708-295-2
... of corrosion products, the geometry of fracture surfaces, or inaccessibility of the component making chemical analysis a challenge. The investigator must take every precaution to avoid delivering misleading compositional information, and engineering/scientific judgement is key in providing the best possible...
Abstract
Chemical analysis is a critical part of any failure investigation. With the right planning and proper analytical equipment, a myriad of information can be obtained from a sample. This article presents a high-level introduction to techniques often used for chemical analysis during failure analysis. It describes the general considerations for bulk and microscale chemical analysis in failure analysis, the most effective techniques to use for organic or inorganic materials, and examples of using these techniques. The article discusses the processes involved in the chemical analysis of nonmetallics. Advances in chemical analysis methods for failure analysis are also covered.
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Specific wear rate as a function of fiber composition in hybrid composite (...
Available to PurchasePublished: 01 January 2002
Fig. 20 Specific wear rate as a function of fiber composition in hybrid composite ( L 93 N, velocity V ) 0.5 m/s, nominal V f 0.57 with dotted curve for calculated values as per equation in Ref 59 . IROM, inverse rule of mixture; LROM, linear rule of mixture. Source: Ref 59
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X-ray elemental composition maps made with the electron microprobe using a ...
Available to PurchasePublished: 01 January 2002
Fig. 18 X-ray elemental composition maps made with the electron microprobe using a region of copper penetration shown in Fig. 16 and 17 . All 270×
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X-ray elemental composition maps made with the electron microprobe of a cop...
Available to PurchasePublished: 01 January 2002
Fig. 5 X-ray elemental composition maps made with the electron microprobe of a copper penetration crack in a failed locomotive axle. 270×
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Published: 01 January 2002
Fig. 3 EDS scans from particles detected in Fig. 1 showing composition differences. (a) Portion of EDS scan obtained from one of the (bright) iron based particles in Fig. 1(b) . Some traces of carbon are also seen here, probably an oily residue on the flake. The silicon may be due to a dirt
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Materials performance as a result of the interactions among composition, pr...
Available to PurchasePublished: 01 January 2002
Fig. 37 Materials performance as a result of the interactions among composition, processing, structure, and properties. Source: Ref 40
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in Hot Cracking of a Pump Impeller From a Nuclear Plant
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1992
Fig. 8 EDS scan of polished specimen for alloy composition. Element Composition, % Iron 84.66 Chromium 12.61 Nickel 0.98 Silicon 0.27 Manganese 1.48 Molybdenum 0.00
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in Hot Cracking of a Pump Impeller From a Nuclear Plant
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1992
Fig. 9 EDS scan of weld metal for constituents. Element Composition, % Iron 84.33 Chromium 13.68 Nickel 0.36 Silicon 0.35 Manganese 1.25 Molybdenum 0.03
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Composition changes by EDS across bond/substrate interface (a) 721ES, (b) w...
Available to Purchase
in Degradation of Thermal Barrier Coated Superalloy Component During Service
> Handbook of Case Histories in Failure Analysis
Published: 01 December 2019
Fig. 5 Composition changes by EDS across bond/substrate interface (a) 721ES, (b) welded, and (c) normal region of inner root area, (d) Aluminum line profile of (a) to (c)
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SEM micrograph and Auger spectrum show surface composition film on FCI site...
Available to Purchase
in Failure Analyses of Six Cylinder Aircraft Engine Crankshafts
> Handbook of Case Histories in Failure Analysis
Published: 01 December 2019
Fig. 12 SEM micrograph and Auger spectrum show surface composition film on FCI site of LF14 tension-to-tension fatigue test fracture. (A number of Auger analyses on this FCI film are listed in Table 3 .) 6,000×
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X-ray elemental composition maps made with the electron microprobe of a cop...
Available to PurchasePublished: 15 January 2021
Fig. 6 X-ray elemental composition maps made with the electron microprobe of a copper penetration crack in a failed locomotive axle. Original magnification: 270×
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Infrared spectra of nylon 11. Composition: nylon 11, polyundecal lactam. Us...
Available to PurchasePublished: 15 May 2022
Fig. 3 Infrared spectra of nylon 11. Composition: nylon 11, polyundecal lactam. Used for plastics of all kinds. Preparation: multiple internal reflection, pressed film; far infrared, film from formic acid solution
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 13 Microstructure at center of Bolt 23 (AXR; type E composition)
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 14 Microstructure at center of Bolt 24 (Wriggle; type A composition)
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 15 Microstructure at center of Bolt 14 (AVH; type D composition)
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 16 Microstructure at center of Bolt 4 (Threadbar; type B composition)
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 17 Microstructure at center of Bolt 28 (Tempcore X; type E composition)
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 18 Microstructure at center of Bolt 1 (HPC; type C composition)
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Effect of composition on microstructure, radial sections in groove, etch: P...
Available to Purchase
in Cracked Bearing Caps Made of Cast Iron
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 8 Effect of composition on microstructure, radial sections in groove, etch: Picral. Cap of hypoeutectic cast iron. 3 ×
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