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cementite
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in “On-Load Corrosion” in Tubes of High Pressure Boilers
> ASM Failure Analysis Case Histories: Power Generating Equipment
Published: 01 June 2019
Fig. 22 Showing grain boundary cementite × 1250
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Image
in “On-Load Corrosion” in Tubes of High Pressure Boilers
> ASM Failure Analysis Case Histories: Power Generating Equipment
Published: 01 June 2019
Fig. 23 Fissuring associated with grain boundary cementite × 1250
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Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c9001186
EISBN: 978-1-62708-234-1
... of the fracture, but they had no effect on the breakage of the wire. Away from the fracture area, the wire had a normal structure of hyperfine lamellar pearlite (sorbite) of a “patented” and cold drawn steel wire. In the vicinity of the fracture, the cementite of the pearlite was partially spheroidized, while...
Abstract
A 2.3 mm diam steel wire broke during cable twisting. The fracture occurred obliquely to the longitudinal axis of the wire and showed a constriction at the end. Therefore it was a ductile fracture. File mark type work defects were noticeable on the wire surface at both sides of the fracture, but they had no effect on the breakage of the wire. Away from the fracture area, the wire had a normal structure of hyperfine lamellar pearlite (sorbite) of a “patented” and cold drawn steel wire. In the vicinity of the fracture, the cementite of the pearlite was partially spheroidized, while at the fracture itself it was completely spheroidized. Therefore the wire was locally annealed at this point. It was likely that the wire cracked at this point during the last drawing and then broke during twisting due to its lower strength in the weakened cross section after prior deformation.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c9001003
EISBN: 978-1-62708-227-3
... flux. The embrittlement was shown to be caused by the flow of corrosion generated hydrogen which converted the cementite to methane which nucleated voids in the steel. A thermodynamic estimate indicated that a small amount of chromium would stabilize the carbides against decomposition by hydrogen...
Abstract
Gross wastage and embrittlement were observed in plain carbon steel desuperheaters in five new Naval power plants. The gross wastage could be duplicated in laboratory bomb tests using sodium hydroxide solutions and was concluded to be caused by free caustic concentrated by high heat flux. The embrittlement was shown to be caused by the flow of corrosion generated hydrogen which converted the cementite to methane which nucleated voids in the steel. A thermodynamic estimate indicated that a small amount of chromium would stabilize the carbides against decomposition by hydrogen in this temperature range, and laboratory tests with 2-14% Cr steel verified this.
Series: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001037
EISBN: 978-1-62708-214-3
... pearlite with MnS inclusions (light gray). 2% nital etch. 200×. Fig. 4 Surface structure along a longitudinal axis of specimen 2. The dark matrix is tempered martensite; the light-colored grainboundary network is cementite. Nital etch. 200×. Fig. 5 Macrograph of sample 2 taken along...
Abstract
Six wrist pins in a high-performance six-cylinder automotive engine failed after 4800 km (3000 mi) of normal operation. The pins were made of low-carbon steel that had been carburized both inside and outside. Two failed pins were examined. One had fractured into three pieces. The other had not fractured, but exhibited circumferential cracks on the surface of the central zone. Visual surface examination and metallographic and chemical analyses were performed on the specimens. Cracking was attributed primarily to poor heat treatment, resulting in a brittle grain-boundary network of cementite, and to a design that had a raised central section of the inner diameter whose fillets were locations of high stress concentration. Rough machining of the inner diameter and an excessively deep case also contributed to failure. A double type of heat treatment after carburizing and change of the design to eliminate the raised central section were recommended.
Image
in Broken Back up Rolls from a Broad Strip Mill
> ASM Failure Analysis Case Histories: Steelmaking and Thermal Processing Equipment
Published: 01 June 2019
Fig. 8 Primary grain boundary with precipitates of ledeburite and secondary cementite. Etched in picral. 200 ×
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Image
in An Unusual Case of Hydrogen-Induced Failure in a Refinery Boiler Tube
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1993
Fig. 6 Optical micrograph of section of tube 2.300 mm (11.8 in.) away from fracture area showing ferrite and grain boundary cementite
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Image
Published: 01 December 1992
Fig. 4 Surface structure along a longitudinal axis of specimen 2. The dark matrix is tempered martensite; the light-colored grainboundary network is cementite. Nital etch. 200×.
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Image
Published: 01 December 1993
Fig. 8 (a) Microstructure of galvanized sheet. Longitudinal section. Microstructure consists of pearlite and primary ferrite. Note coarse pearlite and divorced cementite. (b) Higher magnification of Fig. 8 .
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in Graphitization in Low Alloy Steel Pressure Vessels and Piping
> Handbook of Case Histories in Failure Analysis
Published: 01 December 2019
Fig. 1 A graphitized medium carbon steel; ( a ) graphite nodule in pearlite, with uniform distribution of cementite particles in pearlite around it; ( b ) same steel overaged—complete graphitization and phases present are ferrite and graphite only
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Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001322
EISBN: 978-1-62708-215-0
... micrograph of section of tube 2 from fracture area showing intergranular cracks and fissuring. Note the decarburized microstructure. Fig. 6 Optical micrograph of section of tube 2.300 mm (11.8 in.) away from fracture area showing ferrite and grain boundary cementite Abstract A failed SAE...
Abstract
A failed SAE-192 carbon steel tube from a 6.2-MPa (900-psig), 200-Mg/h (180-ton/h) capacity refinery boiler was analyzed to determine its failure mode. Optical and SEM examination results were combined with knowledge of the boiler operating conditions to conclude that the failure was hydrogen-induced. The hydrogen was probably generated by the steam-iron reaction. The source of steam on the flue gas side could be traced to a cracked fillet weld in the boiler The failure mode was unusual in that the attack was found to originate from the flue gas side of the tube rather than the steam side.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c9001207
EISBN: 978-1-62708-235-8
... in Fig. 6 is free of ferrite, thus approximately eutectoid; the microstructure consists of pearlite and martensite with remnants of austenite. Figure 7 reproduces the microstructure of a location with hyper-eutectoid carbon content. It consists of secondary cementite in the shape of long needles...
Abstract
Pipes made of low-carbon Thomas steel had been welded longitudinally employing the carbon-arc process with bare electrode wire made for argon-shielded arc welding. Difficulties were encountered during the cutting of threads because of the presence of hard spots. Microstructural examination showed welding conditions were such that a carburizing atmosphere developed, which led to an increase in carbon content and hardening at certain locations such as terminal bells and lap joints. This explained the processing difficulties during the threading operation.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001307
EISBN: 978-1-62708-215-0
... the term “blackheart” malleable cast iron is used to describe this kind of material. The weld metal exhibits a microstructure characteristic of rapid solidification. The white phase is cementite, and its presence is reflected in its high microhardness ( Table 2 ). A somewhat similar microstructure can...
Abstract
The right front spring hanger on a dual rear axle of the tractor of a tractor-trailer combination failed, causing the vehicle to roll-over. The hanger was made from malleable cast iron that had been heat treated to produce a decarburized surface layer and a pearlitic transition layer. It had been repair welded after breaking into two pieces longitudinally in a prior incident, using cast iron as weld metal. The repair weld bead on both surfaces missed the fracture over 15 to 20% of their lengths. The incomplete repair weld and brittleness of the weld metal and heat-affected zones led to the failure.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.petrol.c9001592
EISBN: 978-1-62708-228-0
.... The metallurgy and heat treatment of the steel are important factors. 11 Both tubing and rod section #3 were heat treated with a fast cooling rate, leading to a soft material with a poorly formed pearlite. The lamellae of cementite in the pearlite were not long and thin to provide good corrosion resistance...
Abstract
Sucker-rod pumps are operating in very aggressive environments in oil well production. The combined effect of a corrosive environment and significant mechanical loads contribute to frequent cases of failure of the rod string during operation. Standards and recommendations have been developed to control and avoid those failures. This study presents various failure cases of sucker rods in different applications. The heat treatment of the steel material and the resulting microstructure are an important factor in the behavior of the sucker rod. A spheroidized microstructure presents a weaker resistance to corrosion affecting the rod life. Non-metallic inclusions are a pitting preferential site leading to fatigue crack initiation. Heterogeneous microstructure as banded martensite and ferrite/pearlite decreases the ductility of the material affecting the fatigue propagation resistance.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.power.c9001711
EISBN: 978-1-62708-229-7
... at temperatures ranging between 425 °C and 540 °C. In these conditions, the decomposition of cementite yields graphite, which reduces tensile strength. This effect is a faster strength reduction due to the globulization of carbides. Therefore, steels must include alloying elements with strong carbide-forming...
Abstract
Failures of 10Cr-Mo9-10 and X 20Cr-Mo-V12-1 superheated pipes during service in steam power generation plants are described. Through micrographic and fractographic analysis, creep and overheating were identified as the cause of failure. The Larson-Miller parameter is computed, as a function of oxidation thickness, temperature and time, confirming the creep failure diagnostic.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.rail.c9001531
EISBN: 978-1-62708-231-0
... side d γ and pearlite colony size d ρ on fatigue crack initiation life N i It has been shown in a previous investigation on fully pearlitic steels that the strength is determined by cementite interlamellar spacing, while the toughness and ductility are determined by austenite grain size. Ref...
Abstract
In this study, the failure modes of cartwheel and mechanical properties of materials have been analyzed. The results show that rim cracking is always initiated from stringer-type alumina cluster and driven by a combination effect of mechanical and thermal load. The strength, toughness, and ductility are mainly determined by the carbon content of wheel steels. The fatigue crack growth resistance is insensitive to composition and microstructure, while the fatigue crack initiation life increases with the decrease of austenite grain size and pearlite colony size. The dynamic fracture toughness, KID, is obviously lower than static fracture toughness, KIC, and has the same trend as KIC. The ratio of KID/sigma YD is the most reasonable parameter to evaluate the fracture resistance of wheel steels with different composition and yield strength. Decreasing carbon content is beneficial to the performance of cartwheel.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.design.c9001259
EISBN: 978-1-62708-233-4
... G the cementite was somewhat stronger spheroidized ( Fig. 1 ) than in that of shipments S1 ( Fig. 2 ) and S2 ( Fig. 3 ), whose lamellar pearlite structure was still recognizable. This is most likely connected with the fine grained steel's lower supercooling propensity of the austenitic...
Abstract
A bolt manufacturer observed that products made from certain shipments of steel 41 Cr4 wire were prone to the formation of quench cracks in their rolled threads. The affected wire was tested and found to be highly sensitive to overheating because of the metallurgical method by which it was produced. A stronger decarburization of the case was a contributing factor that could not be prevented by working because the thread was rolled. Hardening tests conducted by the bolt manufacturer showed that quench cracks did not occur in specimens that were turned down before hardening and when notches were machined instead of beaten with a chisel.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.steel.c9001255
EISBN: 978-1-62708-232-7
... responsible for the scaly fracture and the formation of primary grain boundary cracks. Fig. 7 Micro-shrinkage cavity with carbon segregation (ledeburite). Etched in picral. 50 × Fig. 8 Primary grain boundary with precipitates of ledeburite and secondary cementite. Etched in picral. 200...
Abstract
Several back up rolls of 1400 mm barrel diam from a broad strip mill broke after a relatively short operating time as a result of bending stresses when the rolls were dismantled. The fracture occurred in the conical region of the neck at about 600 mm diam. The rolls were shaped steel castings with 0.8 to 1.0% C, 1% Mn, 1% Cr, 0.5% Mo and 0.4% Ni and were heat treated to a tensile strength of 950 N/sq mm. Because the bending stress on mounting was only 42 N/sq mm in the fracture cross section, it was evident at the outset that material defects had promoted the fracture. In the case of this roll and the other broken rolls, the cracking and fracture were promoted by various casting defects. Investigation of the rolls showed that both the breaking off of the neck and the disintegration of the barrel edges was caused by material defects, more exactly casting defects. The fractures on the other rolls examined were so badly rusted or contaminated that they were incapable of yielding any information.
Book Chapter
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001813
EISBN: 978-1-62708-241-9
... Fig. 1 A graphitized medium carbon steel; ( a ) graphite nodule in pearlite, with uniform distribution of cementite particles in pearlite around it; ( b ) same steel overaged—complete graphitization and phases present are ferrite and graphite only Fig. 2 Stages of graphitization...
Abstract
Graphitization, the formation of graphite nodules in carbon and low alloy steels, contributes to many failures in high-temperature environments. Three such failures in power-generating systems were analyzed to demonstrate the unpredictable nature of this failure mechanism and its effect on material properties and structures. In general, the more randomly distributed the nodules, the less effect they have on structural integrity. In the cases examined, the nodules were found to be organized in planar arrays, indicating they might have an effect on material properties. Closer inspection, however, revealed that the magnitude of the effect depends on the relative orientation of the planar arrangement and principle tensile stress. For normal orientation, the effect of embrittlement tends to be most severe. Conversely, when the orientation is parallel, the nodules have little or no effect. The cases examined show that knowledge is incomplete in regard to graphitization, and the prediction of its occurrence is not yet possible.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.power.c9001396
EISBN: 978-1-62708-229-7
... in the atomic state is able to penetrate the lattice of the metal crystals where it reacts with carbon to form methane or other hydrocarbon gases; C + 4 H = CH 4 The microstructure of some of the tubes examined showed an appreciable amount of grain boundary cementite, as shown in Fig. 22...
Abstract
The phenomenon of on-load corrosion is directly associated with the production of magnetite on the water-side surface of boiler tubes. On-load corrosion may first be manifested by the sudden, violent rupture of a boiler tube, such failures being found to occur predominantly on the fire-side surface of tubes situated in zones exposed to radiant heat where high rates of heat transfer pertain. In most instances, a large number of adjacent tubes are found to have suffered, the affected zone frequently extending in a horizontal band across the boiler. In some instances, pronounced local attack has taken place at butt welds in water-wall tubes, particularly those situated in zones of high heat flux. To prevent on-load corrosion an adequate flow of water must occur within the tubes in the susceptible regions of a boiler. Corrosion products and suspended matter from the pre-boiler equipment should be prevented from entering the boiler itself. Also, it is good practice to reduce as far as possible the intrusion of weld flash and other impedances to smooth flow within the boiler tubes.
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