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Structure of unsaturated polyester resins. (a) Phthalate esters, (b) Bisphe...
Available to PurchasePublished: 15 May 2022
Fig. 15 Structure of unsaturated polyester resins. (a) Phthalate esters, (b) Bisphenol A/fumarate resins
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Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006929
EISBN: 978-1-62708-395-9
... in Fig. 15 include orthophthalic esters, isophthalic esters, and bisphenol A/fumarate resins. Figure 16 demonstrates the varying effect of 100 °C (212 °F) water exposure on glass laminates based on the three polyester types. Despite the orthophthalic polyester showing a dramatic loss of properties...
Abstract
This article provides an overview of the physics and math associated with moisture-related failures in plastic components. It develops key equations, showing how they are used to analyze the causes and effects of water uptake, diffusion, and moisture concentration in polymeric materials and resins. It explains how absorbed moisture affects a wide range of properties, including glass transition temperature, flexural and shear modulus,creep, stress relaxation, swelling, tensile and yield strength, and fatigue cracking. It provides relevant data on common polymers, resins, and fiber-resin composites.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006923
EISBN: 978-1-62708-395-9
..., and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties. chemical composition elastomeric materials...
Abstract
This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006925
EISBN: 978-1-62708-395-9
.... Engineering plastics all have, as their principal constituent, one or more synthetic polymer resins and almost universally contain additives. Additives, which have much smaller molecules than polymers, provide color, flexibility, rigidity, flame resistance, weathering resistance, and/or processibility...
Abstract
This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.