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aluminum-magnesium alloys
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Book Chapter
Brittle Fracture of an Aluminum Alloy Lifting-Sling Member
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.matlhand.c0048095
EISBN: 978-1-62708-224-2
... 5083 or 5086. Analysis of the weld metal indicated that aluminum alloy 4043 filler metal had been used. The silicon content was lower and the magnesium and manganese contents were higher than normal for alloy 4043 filler metal. These differences were attributed to dilution of the weld metal by the base...
Abstract
The T-section cross member of the lifting sling failed in service while lifting a 966 kg (2130 lb) load. The L-section sling body and the cross member were made of aluminum alloy 5083 or 5086 and were joined by welding using aluminum alloy 4043 filler metal. The fracture was found by visual examination to have occurred at the weld joining the sling body and the cross member. Inadequate joint penetration and porosity was revealed by macrographic examination of the weld. Lower silicon content and a higher magnesium and manganese content than the normal for alloy 4043 filler metal were found during chemical analysis. It was revealed by examination of the ends of the failed cross member that a rotational force that had been applied on the cross member caused it to fracture near the sling body. It was concluded that brittle fracture at the weld was caused by overloading which was attributed to the misalignment of the sling during loading. Aluminum alloy 5183 or 5356 filler metal was recommended to be used to avoid brittle welds.
Book Chapter
Intergranular Corrosion Failure in Zn-Al Alloy Solenoid Valve Seats
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001123
EISBN: 978-1-62708-214-3
... that the actual composition with respect to aluminum, lead, and magnesium was different from the specified alloy. Scanning electron microscopy showed intergranular failure with enhanced aluminum and segregation of lead at grain boundaries. In this type of alloy, aluminum is used for strengthening through grain...
Abstract
Extensive cracking was found in a batch of die-cast ZAMAK 3 solenoid valve seats during commissioning of the system in which they were installed. Scanning electron microscopic and chemical analyses conducted on one of the failed valve seats showed that the composition of the alloy was different from that specified. The presence of excess aluminum and lead impurities that had segregated to the grain boundaries, coupled with an inadequate amount of magnesium, resulted in intergranular corrosion and subsequent intergranular failure. Corrosion was accelerated by storage in a humid environment in a coastal area. It was recommended that proper chemical analysis of the zinc-aluminum alloy be carried out as a quality control procedure.
Book Chapter
Failure of a Steel Pot Used for Melting Magnesium Alloys
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.steel.c9001490
EISBN: 978-1-62708-232-7
... , the following areas (starting from the inside surface) were identified: An aluminum-iron oxide scale or dross (area 1 in Figure 6 ). An aluminum-magnesium-iron oxide constituent penetrating along grain boundaries (area 6). A carbide-free iron-aluminum alloy layer (area 2). Several rows of small...
Abstract
A steel pot used as crucible in a magnesium alloy foundry developed a leak that resulted in a fire and caused extensive damage. Hypotheses as to the cause of the leak included a defect in the pot, overuse, overheating, and poor foundry practices. Scanning electron microscopy, transmission electron microscopy, optical microscopy, and x-ray microanalysis in conjunction with dimensional analysis, phase diagrams and thermodynamics considerations were employed to evaluate the various hypotheses. All evidence pointed to an oxide mass in the area where the hole developed, likely introduced during the steelmaking process.
Image
Corrosion rates in 3% NaCl solution of magnesium alloy AZ31B coupled with a...
Available to PurchasePublished: 01 January 2002
Fig. 7 Corrosion rates in 3% NaCl solution of magnesium alloy AZ31B coupled with aluminum containing varying amounts of iron and magnesium. The corrosion rate of uncoupled AZ31B is shown for comparison.
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Image
Corrosion rates in 3% NaCl solution of magnesium alloy AZ31B coupled with a...
Available to PurchasePublished: 15 January 2021
Fig. 7 Corrosion rates in 3% NaCl solution of magnesium alloy AZ31B coupled with aluminum containing varying amounts of iron and magnesium. The corrosion rate of uncoupled AZ31B is shown for comparison.
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Book Chapter
Failure of Aircraft Wing Leading Edge Panel
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.aero.c0006421
EISBN: 978-1-62708-217-4
... Abstract Cracks were found on the wing leading edge of a test aircraft made from AZ31B magnesium alloy. Crack lengths were approximately 230 mm (9 in.) long on the left side and approximately 130 mm (5 in.) long on the right side. The cracks ran parallel to the leading edge. The 230-mm (9...
Abstract
Cracks were found on the wing leading edge of a test aircraft made from AZ31B magnesium alloy. Crack lengths were approximately 230 mm (9 in.) long on the left side and approximately 130 mm (5 in.) long on the right side. The cracks ran parallel to the leading edge. The 230-mm (9-in.) crack was received for examination. Visual examination of the submitted panel revealed two cracks. One crack ran through six adjacent fastener holes. Sections of the beveled edges of the holes were missing and corrosion was evident. Visual examination of the fastener holes after separation of the crack showed that the fracture faces were corroded. Optical examination of either side of the middle group of fastener holes showed that the area of suspected crack initiation had suffered excessive corrosion. Examination of the holes on the end of the crack showed fracture characteristics typical of fatigue and/or corrosion fatigue. It was concluded that crack propagation of the fracture in the wing panel occurred by a combination of corrosion and high-cycle fatigue in the end fastener holes. It was recommended that future panels be manufactured of 2024 aluminum.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003553
EISBN: 978-1-62708-180-1
... analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium. aluminum alloys austenitic stainless steel carbon...
Abstract
This article commences with a discussion on the characteristics of stress-corrosion cracking (SCC) and describes crack initiation and propagation during SCC. It reviews the various mechanisms of SCC and addresses electrochemical and stress-sorption theories. The article explains the SCC, which occurs due to welding, metalworking process, and stress concentration, including options for investigation and corrective measures. It describes the sources of stresses in service and the effect of composition and metal structure on the susceptibility of SCC. The article provides information on specific ions and substances, service environments, and preservice environments responsible for SCC. It details the analysis of SCC failures, which include on-site examination, sampling, observation of fracture surface characteristics, macroscopic examination, microscopic examination, chemical analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium.
Book Chapter
Stress-Corrosion Cracking of a Die-Cast Zinc Alloy Nut
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c0048620
EISBN: 978-1-62708-225-9
.... Fasteners Intergranular corrosion Zinc-aluminum die casting alloy Stress-corrosion cracking The two nuts shown in Fig. 1(a) and (b) were used to secure the water-supply pipes to the threaded connections on hot-water and cold-water taps. The nut used on the cold-water tap ( Fig. 1a ) fractured...
Abstract
Two nuts were used to secure the water-supply pipes to the threaded connections on hot-water and cold-water taps. The nut used on the cold-water tap fractured about one week after installation. Examination of the fracture surfaces of the coldwater nut did not reveal any obvious defects to account for the fracture, but there were indications of excessive porosity in the nut. The fracture had occurred through the root of the first thread that was adjacent to the flange of the tap. It was found that the nut from the cold-water tap failed by SCC. Apparently, sufficient stress was developed in the nut to promote this type of failure by normal installation because there was no evidence of excessive tightening of the nut. Corrosion testing of the nuts indicated that the fractured nut was highly susceptible to intergranular corrosion because of either a deficiency in magnesium content or excessive impurities, such as lead, tin, or cadmium. This composition problem with zinc alloys was recognized many years ago, and particular attention has been directed toward ensuring that high-purity zinc is used. This corrective measure reportedly resulted in virtual elimination of this type of defect.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006785
EISBN: 978-1-62708-295-2
... caustic solutions High-nickel alloys High-purity steam Alpha brass Ammoniacal solutions, chloramine, amine Aluminum alloys Aqueous chloride, bromide, and iodide solutions Titanium alloys Aqueous chloride, bromide, and iodide solutions; organic liquids; N 2 O 4 Magnesium alloys Aqueous...
Abstract
Stress-corrosion cracking (SCC) is a form of corrosion and produces wastage in that the stress-corrosion cracks penetrate the cross-sectional thickness of a component over time and deteriorate its mechanical strength. Although there are factors common among the different forms of environmentally induced cracking, this article deals only with SCC of metallic components. It begins by presenting terminology and background of SCC. Then, the general characteristics of SCC and the development of conditions for SCC as well as the stages of SCC are covered. The article provides a brief overview of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions commonly associated with the development of SCC, although not all, and numerous case studies.
Book Chapter
Cavitation Erosion of a Water-Cooled Aluminum Alloy 6061-T6 Combustion Chamber
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c0046418
EISBN: 978-1-62708-234-1
... Abstract Equipment in which an assembly of in-line cylindrical components rotated in water at 1040 rpm displayed excessive vibration after less than one hour of operation. The malfunction was traced to an aluminum alloy 6061-T6 combustion chamber that was part of the rotating assembly. Analysis...
Abstract
Equipment in which an assembly of in-line cylindrical components rotated in water at 1040 rpm displayed excessive vibration after less than one hour of operation. The malfunction was traced to an aluminum alloy 6061-T6 combustion chamber that was part of the rotating assembly. Analysis (visual inspection, 100x/500x/800x micrographic examination, spectrographic analysis, and hardness testing) supported the conclusions that, as a result of improper heat treatment, the combustion-chamber material was too soft for successful use in this application. Misalignment of the combustion chamber and one or both of the mating parts resulted in eccentric rotation and the excessive vibration that caused malfunction of the assembly. Irregularities in the housing around the combustion chamber and temperature variation relating to the combustion pattern in the chamber were considered to be possible contributing factors to localization of the cavitation erosion. Recommendations included adopting inspection procedures to ensure that the specified properties of aluminum alloy 6061-T6 were obtained and that the combustion chamber and adjacent components were aligned within specified tolerances. In a similar situation, consideration should also be given to raising the pressure in the coolant in order to suppress the formation of cavitation bubbles.
Book Chapter
Failures of Structures and Components by Metal-Induced Embrittlement
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001812
EISBN: 978-1-62708-241-9
... of LME as a failure analysis tool is also discussed. fasteners nozzles valves fracture mercury lead cadmium zinc structural alloys cracking cleavage radiography fracture toughness 5083-O (wrought aluminum magnesium alloy) UNS A95083 10Zn-2Pb (free-machining brass) Introduction...
Abstract
Several cases of embrittlement failure are analyzed, including liquid-metal embrittlement (LME) of an aluminum alloy pipe in a natural gas plant, solid metal-induced embrittlement (SMIE) of a brass valve in an aircraft engine oil cooler, LME of a cadmium-plated steel screw from a crashed helicopter, and LME of a steel gear by a copper alloy from an overheated bearing. The case histories illustrate how LME and SMIE failures can be diagnosed and distinguished from other failure modes, and shed light on the underlying causes of failure and how they might be prevented. The application of LME as a failure analysis tool is also discussed.
Book Chapter
Failure Analysis Case Study on a Fractured Tailwheel Fork
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001753
EISBN: 978-1-62708-241-9
... ], as he indicates that “the tensile properties of the aluminum–zinc–magnesium alloys in the as-cast (F temper) condition change rapidly during the first few weeks of room temperature aging, because of natural precipitation hardening. Additional hardening continues thereafter at a progressively slower rate...
Abstract
A failure analysis investigation was conducted on a fractured aluminum tailwheel fork which failed moments after the landing of a privately owned, 1955 twin-engine airplane. Nondestructive evaluation via dye-penetrant inspection revealed no discernible surface cracks. The chemical composition of the sand-cast component was identified via optical emission spectroscopy and is comparable to an aluminum sand-cast alloy, AA 712.0. Metallographic evaluation via optical microscopy and scanning electron microscopy revealed a high degree of porosity in the microstructure as well as the presence of deleterious intermetallic compounds within interdendritic regions. Macrohardness testing produced hardness values which are noticeably higher than standard hardness values for 712.0. The primary fracture surfaces indicate evidence of mixed-mode fracture, via intergranular cracking, cleaved intermetallic particles, and dimpled cellular regions in the matrix. The secondary fracture surface demonstrates similar features of intergranular fracture.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001284
EISBN: 978-1-62708-215-0
..., presented in Table 1 , showed that the compositions of both risers conformed to requirements for alloy AM60A (ASTM B94). Results of chemical analysis Table 1 Results of chemical analysis Element Failed Failed Alloy AM60A riser 1 riser 2 requirements (ASTM B94) Aluminum 5.80 6.35...
Abstract
Compound bow handle risers that had failed in service and during assembly along with an unassembled riser were submitted for analysis. The risers were die cast from magnesium-base alloy AM60A. Inspection of the failed risers and metallurgical investigations conducted on the stock riser revealed the presence of cold shuts at the same site in all specimens. It was recommended that all risers be thoroughly inspected and that the bow company work with their die casting shop to design a mold with acceptable filling characteristics.
Book Chapter
Failure by Blowout of Aluminum Alloy 6061-T6 Connector Tubes From a Water-Cooling System
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c0047080
EISBN: 978-1-62708-235-8
... Abstract Several of the aluminum alloy 6061-T6 drawn seamless tubes (ASTM B 234, 2.5 cm (1.0 in.) OD with wall thickness of 1.7 mm (0.065 in.)) connecting an array of headers to a system of water-cooling pipes failed. The tubes were supplied in the O temper. They were bent to the desired...
Abstract
Several of the aluminum alloy 6061-T6 drawn seamless tubes (ASTM B 234, 2.5 cm (1.0 in.) OD with wall thickness of 1.7 mm (0.065 in.)) connecting an array of headers to a system of water-cooling pipes failed. The tubes were supplied in the O temper. They were bent to the desired curvature, preheated, then solution treated, water quenched, and then aged for 8 to 10 h. Analysis (visual inspection, slow-bend testing, 65x macrographic analysis, macroetching, spectrographic analysis, hardness tests, microhardness tests, tension tests, and microscopic examination) supported the conclusions that bending of the connector tubes in the annealed condition induced critical strain near the neutral axis of the tube, which resulted in excessive growth of individual grains during the subsequent solution treatment. Recommendations included bending the connector tubes in the T4 temper as early as possible after being quenched from the solution temperature. The tubes should be stored in dry ice after the quench until bending can be done. The tubes should be aged immediately after being formed. Flattening and slow-bend tests should be specified to ensure that the connector tubes had satisfactory ductility.
Book Chapter
Fatigue Fracture of Aluminum Wires in High-Voltage Electrical Cables in Alaska
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001124
EISBN: 978-1-62708-214-3
... Abstract Several wires in aluminum conductor cables fractured within 5 to 8 years of, service in Alaskan tundra. The cables were comprised of 19-wire strands; the wires were aluminum alloy 6201-T81. Visual and metallographic examinations of the cold-upset pressure weld joints in the wires...
Abstract
Several wires in aluminum conductor cables fractured within 5 to 8 years of, service in Alaskan tundra. The cables were comprised of 19-wire strands; the wires were aluminum alloy 6201-T81. Visual and metallographic examinations of the cold-upset pressure weld joints in the wires established that the fractures were caused by fatigue loading attributable to wind/thermal factors at the joints. The grain flow at the joints was transverse to the wire axis, rendering the notches of the joints sensitive to fatigue loading. An additional contributory factor was intergranular corrosion, which assisted fatigue crack initiation/propagation. The failure was attributed to the departure of conductor quality from the requirements of ASTM B 398 and B 399, which specify that “no joints shall be made during final drawing or in the finished wire” and that the joints should not be closer than 15 m (50 ft). The failed cable did not meet either criterion. It was recommended that the replacement cable be inspected for strict compliance to ASTM requirements.
Book Chapter
Fatigue Cracking That Originated at a Material Defect in a Forged Aircraft Wheel Half
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.aero.c0047125
EISBN: 978-1-62708-217-4
... Abstract A commercial aircraft wheel half, machined from an aluminum alloy 2014 forging that had been heat treated to the T6 temper, was removed from service because a crack was discovered in the area of the grease-dam radius during a routine inspection. Neither the total number of landings nor...
Abstract
A commercial aircraft wheel half, machined from an aluminum alloy 2014 forging that had been heat treated to the T6 temper, was removed from service because a crack was discovered in the area of the grease-dam radius during a routine inspection. Neither the total number of landings nor the roll mileage was reported, but about 300 days had elapsed between the date of manufacture and the date the wheel was removed from service. The analysis (visual inspection, macrographs, micrographs, electron microprobe) supported the conclusions that the wheel half failed by fatigue. The fatigue crack originated at a material imperfection and progressed in more than one plane because changes in the direction of wheel rotation altered the direction of the applied stresses. Recommendations included rewriting the inspection specifications to require sound forgings.
Book Chapter
Fatigue Failure of an Aluminum Turbine Impeller
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001366
EISBN: 978-1-62708-215-0
... Abstract An AMS 4126 (7075-T6) aluminum alloy impeller from a radial inflow turbine fractured during commissioning. Initial examination showed that two adjacent vanes had fractured through airfoils in the vicinity of the vane leading edges, and one vane fractured through an airfoil near the hub...
Abstract
An AMS 4126 (7075-T6) aluminum alloy impeller from a radial inflow turbine fractured during commissioning. Initial examination showed that two adjacent vanes had fractured through airfoils in the vicinity of the vane leading edges, and one vane fractured through an airfoil near the hub in the vicinity of the vane trailing edge. Some remaining vanes exhibited radial and transverse cracks in similar locations. Binocular and scanning electron microscope examinations showed that the cracks had been caused by high-cycle fatigue and had progressed from multiple origins on the vane surface. Structural analysis indicated that the fatigue loading probably had been caused by forced excitation, resulting in the impeller vibrating at its resonant frequency. It was recommended that the impeller design, control systems, and material of construction be changed.
Book Chapter
Forms of Corrosion
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003548
EISBN: 978-1-62708-180-1
.... Performance of Alloy Groupings Magnesium Magnesium occupies an extremely active position in most galvanic series and is therefore highly susceptible to galvanic corrosion. Metals that combine active potentials with higher hydrogen overvoltages, such as aluminum, zinc, cadmium, and tin, are much less...
Abstract
This article addresses the forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. It describes the mechanisms of corrosive attack for specific forms of corrosion such as galvanic corrosion, uniform corrosion, pitting and crevice corrosion, intergranular corrosion, and velocity-affected corrosion. The article contains a table that lists combinations of alloys and environments subjected to selective leaching and the elements removed by leaching.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006783
EISBN: 978-1-62708-295-2
... that combine active potentials with higher hydrogen overvoltages, such as aluminum, zinc, cadmium, and tin, are much less damaging, although not fully compatible with magnesium. Aluminum alloys that contain small percentages of copper (7000 and 2000 series and 380 die-casting alloy) may cause serious...
Abstract
Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003540
EISBN: 978-1-62708-180-1
... are as follows: Base alloy Liquid embrittlers Aluminum Hg, Ga, Zn, In, Na Steel Hg, Ga, Cd, Zn, In, Li Copper Hg, In, Li, Na Magnesium Zn, In Titanium Hg, Cd Silver Hg, Ga Intergranular SCC and Hydrogen Embrittlement Grain boundaries can become weakened or embrittled...
Abstract
This article briefly reviews the various metallurgical or environmental factors that cause a weakening of the grain boundaries and, in turn, influence the occurrence of intergranular (IG) fractures. It discusses the mechanisms of IG fractures, including the dimpled IG fracture, the IG brittle fracture, and the IG fatigue fracture. The article describes some typical embrittlement mechanisms that cause the IG fracture of steels.
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