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Book Chapter
Forms of Corrosion
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003548
EISBN: 978-1-62708-180-1
... treated with copper preservatives can be corrosive to certain nails. Aluminum cladding can also be at risk. (g) Contact of two metals through a fluid trap can be avoided by using a drain, collection tray, or a deflector. Where dissimilar materials are to be joined, it is advisable to use a more...
Abstract
This article addresses the forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. It describes the mechanisms of corrosive attack for specific forms of corrosion such as galvanic corrosion, uniform corrosion, pitting and crevice corrosion, intergranular corrosion, and velocity-affected corrosion. The article contains a table that lists combinations of alloys and environments subjected to selective leaching and the elements removed by leaching.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006783
EISBN: 978-1-62708-295-2
..., copper ions from the copper heater coil could deposit on the aluminum stirrer. A nonmetallic stirrer would be better. At right, the distance from a metal container to a heater coil should be increased to minimize ion transfer. (f) Wood treated with copper preservatives can be corrosive to certain nails...
Abstract
Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.
Image
Design details that can affect galvanic corrosion. (a) Fasteners should be ...
Available to PurchasePublished: 01 January 2002
is possible if a coated component is cut. When necessary, the cathodic component of a couple should be coated. (e) Ion transfer through a fluid can result in galvanic attack of less noble metals. In the example shown at left, copper ions from the copper heater coil could deposit on the aluminum stirrer
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Image
Design details that can affect galvanic corrosion. (a) Fasteners should be ...
Available to PurchasePublished: 15 January 2021
deposit on the aluminum stirrer. A nonmetallic stirrer would be better. At right, the distance from a metal container to a heater coil should be increased to minimize ion transfer. (f) Wood treated with copper preservatives can be corrosive to certain nails. Aluminum cladding can also be at risk. (g
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Book Chapter
Failure of 17-4 PH Stainless Steel Bolts on a Titan Space Launch Vehicle
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c9001727
EISBN: 978-1-62708-225-9
.... The formation of rust spots could be prevented by covering bolts with a suspension of graphite in grease (Lox-Safe). It became apparent that the presence of aluminum accelerated the stress-corrosion cracking of the stainless. Aluminum is anodic to stainless in the galvanic series — it can be used...
Abstract
Several stainless steel bolts used on a Titan Space Launch Vehicle broke at the shank and failure was attributed to stress-corrosion cracking. But results could not be duplicated in the laboratory with salt-solution immersion tests until the real culprit was established: the secondary effect of galvanic coupling, hydrogen embrittlement.
Book Chapter
Aluminum/Refrigerant Reaction Resulting in the Failure of a Centrifugal Compressor
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001364
EISBN: 978-1-62708-215-0
... aluminum parts in centrifugal compressors have been well documented ( Ref 1 ). The reaction dissociates the refrigerant into carbon and hydrochloric and hydrofluoric acids, which consume aluminum. The reaction requires the presence of a film-free aluminum surface, which can result from either melting...
Abstract
An investigation of the impeller and deposit samples from a centrifugal compressor revealed that an aluminum IR-12 refrigerant reaction had occurred, causing extensive damage to the second-stage impeller and contaminating the internal compressor components. The spherical surface morphology of the impeller fragments suggested that the aluminum had melted and resolidified. The deposits were similar in composition and were identified by XRD as consisting primarily of aluminum trifluoride. In addition, EDS analysis detected major amounts of chlorine and iron. Results of a combustion test indicated that the compressor deposit was comprised of a 9. 8 wt% carbon and that the condenser deposit contained 8.7 wt% carbon. It was concluded that the primary cause of failure was the rubbing of the impeller against the casting and that a self-sustaining Freon fire had occurred in the failed compressor
Book Chapter
Microfractography and Metallography for Failure Analysis
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006760
EISBN: 978-1-62708-295-2
... dimples Brittle Failures Brittle failures do not show necking or elongation. The fracture surface can be transgranular/cleavage or intergranular, depending on the material and conditions ( Fig. 6 ). Fig. 6 (a) Brittle fracture of cast aluminum tensile bar. (b) Brittle fracture...
Abstract
Visual examination, using the unaided eye or a low-power optical magnifier, is typically one of the first steps in a failure investigation. This article presents the guidelines for selecting samples for scanning electron microscope examination and optical metallography and for cleaning fracture surfaces. It discusses damage characterization of metals, covering various factors that influence the damage, namely stress, aggressive environment, temperature, and discontinuities.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003529
EISBN: 978-1-62708-180-1
... and Technology or the Collaborative Testing Service. Please note that the competent chemist can take advantage of this usually problematic differential solubility to gain additional information about some materials. For example, aluminum is often added to steel to create conditions conducive to maintaining...
Abstract
This article describes some of the common elemental composition analysis methods and explains the concept of referee and economy test methods in failure analysis. It discusses different types of microchemical analyses, including backscattered electron imaging, energy-dispersive spectrometry, and wavelength-dispersive spectrometry. The article concludes with information on specimen handling.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006778
EISBN: 978-1-62708-295-2
... ( Fig. 1a , b ). Parabolic or elongated shear dimples occur from torsional loading ( Fig. 1c ) or from mode II (in-plane) shear. However, metallic materials can behave in a ductile manner but not exhibit the classical dimple-rupture morphology, as shown in Fig. 1(d) for a cast aluminum alloy...
Abstract
This article aims to identify and illustrate the types of overload failures, which are categorized as failures due to insufficient material strength and underdesign, failures due to stress concentration and material defects, and failures due to material alteration. It describes the general aspects of fracture modes and mechanisms. The article briefly reviews some mechanistic aspects of ductile and brittle crack propagation, including discussion on mixed-mode cracking. Factors associated with overload failures are discussed, and, where appropriate, preventive steps for reducing the likelihood of overload fractures are included. The article focuses primarily on the contribution of embrittlement to overload failure. The embrittling phenomena are described and differentiated by their causes, effects, and remedial methods, so that failure characteristics can be directly compared during practical failure investigation. The article describes the effects of mechanical loading on a part in service and provides information on laboratory fracture examination.
Book Chapter
Degradation of Thermal Barrier Coated Superalloy Component During Service
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001829
EISBN: 978-1-62708-241-9
... with that in the spalled area, the concentration of aluminum in the bond coat was also decreased to 2 to ~3 wt.% and that of tungsten was increased to 3 to ~5 wt.%. Based on these findings, the chemical composition of substrate as well as the spallation of top coat can affect diffusion, including the rate of aluminum...
Abstract
An investigation was conducted to better understand the time-dependent degradation of thermal barrier coated superalloy components in gas turbines. First-stage vanes are normally subjected to the highest gas velocities and temperatures during operation, and were thus the focus of the study. The samples that were analyzed had been operating at 1350 °C in a gas turbine at a combined-cycle generating plant. They were regenerated once, then used for different lengths of time. The investigation included chemical analysis, scanning electron microscopy, SEM/energy dispersive spectroscopy, and x-ray diffraction. It was shown that degradation is driven by chemical and mechanical differences, oxide growth, depletion, and recrystallization, the combined effect of which results in exfoliation, spallation, and mechanical thinning.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c9001640
EISBN: 978-1-62708-235-8
... to the casting. The wide-head arrows show the ratchet marks—an indication here that the crack has started in multiple locations along the inside surface. Aluminum die castings can be rather brittle, and brittle castings can be very difficult fractography subjects, because their fatigue fracture surfaces...
Abstract
A new supplier for aluminum die castings was being evaluated, and the castings failed to meet the durability test requirements. Specifically, the fatigue life of the castings was low. Initial inspection of the fatigue fracture surfaces revealed large-scale porosity visible to the naked eye. New castings with reduced porosity also failed the durability tests. The fatigue fracture surfaces of additional casting fragments were very rough and contained multiple ratchet marks along the inner fillet. These observations indicated the fatigue process was heavily influenced by the presence of surface imperfections. Improving the surface finish or choosing a stronger alloy, were more likely to improve part durability than reducing the porosity.
Book Chapter
Failure Analysis of Pressurized Aluminum Cylinders and Its Applications to a Safer Design
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c9001140
EISBN: 978-1-62708-227-3
... Abstract Several pressurized air containers (i.e., diving tanks) made of non-heat-treatable Al-5Mg aluminum alloy failed catastrophically. Catastrophic failure occurred when a subcritical stress corrosion crack reached a critical size. Critical crack size for unstable propagation was reached...
Abstract
Several pressurized air containers (i.e., diving tanks) made of non-heat-treatable Al-5Mg aluminum alloy failed catastrophically. Catastrophic failure occurred when a subcritical stress corrosion crack reached a critical size. Critical crack size for unstable propagation was reached prior to wall penetration, which could have led to subsequent loss of pressure, resulting in explosion of the cylinder. It was recommended that more stress corrosion resistant alloys be used for sea diving applications. Furthermore, cylinders should have a reduced wall thickness that can be determined employing the “leak-before-break” design philosophy, developed using fracture mechanics, to eliminate the possibility of catastrophic ruptures.
Book Chapter
Failures of Structures and Components by Metal-Induced Embrittlement
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001812
EISBN: 978-1-62708-241-9
... as low as 10% of those required for fast fracture in air ( Fig. 2 ) [ 12 – 14 ]. Fig. 1 Delayed-failure curve (time-to-failure versus applied stress as a percentage of the yield stress) for aluminium-alloy weld (5083) specimens exposed to liquid mercury at 20 °C. Note that failure can be almost...
Abstract
Several cases of embrittlement failure are analyzed, including liquid-metal embrittlement (LME) of an aluminum alloy pipe in a natural gas plant, solid metal-induced embrittlement (SMIE) of a brass valve in an aircraft engine oil cooler, LME of a cadmium-plated steel screw from a crashed helicopter, and LME of a steel gear by a copper alloy from an overheated bearing. The case histories illustrate how LME and SMIE failures can be diagnosed and distinguished from other failure modes, and shed light on the underlying causes of failure and how they might be prevented. The application of LME as a failure analysis tool is also discussed.
Book Chapter
Intergranular Corrosion of an Aluminum Alloy Ship Hull
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c0091350
EISBN: 978-1-62708-227-3
... Abstract Cracks occurred in a new ship hull after only three months in service. It was noted that the 5xxx series of aluminum alloys are often selected for weldability and are generally very resistant to corrosion. However, if the material has prolonged exposure at slightly elevated...
Abstract
Cracks occurred in a new ship hull after only three months in service. It was noted that the 5xxx series of aluminum alloys are often selected for weldability and are generally very resistant to corrosion. However, if the material has prolonged exposure at slightly elevated temperatures of 66 to 180 deg C (150 to 350 deg F), an alloy such as 5083 can become susceptible to intergranular corrosion. Investigation (visual inspection, corrosion testing, SEM images) supported the conclusion that the cracks occurred because during exposures to chloride solutions like seawater, galvanic couples formed between precipitates and the alloy matrix, leading to severe intergranular attack. No recommendations were made.
Book Chapter
Failure Analysis of a Crimping Mechanism
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001783
EISBN: 978-1-62708-241-9
... Abstract An aluminum bronze bushing that serves as a guide in a crimping machine began to fail after 50,000 cycles or approximately two weeks of operation. Until then, typical run times had been on the order of months. Although the bushings are replaceable and relatively inexpensive, the cost...
Abstract
An aluminum bronze bushing that serves as a guide in a crimping machine began to fail after 50,000 cycles or approximately two weeks of operation. Until then, typical run times had been on the order of months. Although the bushings are replaceable and relatively inexpensive, the cost of downtime adds up quickly while operators troubleshoot and swap out worn components. Initially, the quality of the bushings came into question, but after a detailed analysis of the entire crimping mechanism, several other issues emerged that were not previously considered. As a result, the investigation provides information on not only better materials, but also design changes intended to reduce wear and increase service life.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c9001691
EISBN: 978-1-62708-234-1
... be electrically insulated from the stainless steel system to minimize galvanic corrosion [ 3 ]. The DI cooling water, the filtration, and the DI heating water should all be improved. The protective oxide layer on the 6063 aluminum that was formed in service can be seen in Figure 12 . Fig. 12 Uniform...
Abstract
The Advanced Photon Source (APS) is a state-of-the-art synchrotron light source. The storage ring vacuum chamber is fabricated from 6061 extruded aluminum. Water connections to the vacuum chambers that were fabricated from 3003 aluminum had developed water leaks, which were subsequently remedied after considerable investigations.
Book Chapter
Failure Analysis of a Cracked Gasoline Engine Cylinder Head
Available to PurchaseSeries: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001760
EISBN: 978-1-62708-241-9
... Abstract This article presents a failure analysis of an aluminum cylinder head on an automotive engine. During an endurance test, a crack initiated from the interior wall of a hole in the center of the cylinder head, then propagated through the entire thickness of the component. Metallurgical...
Abstract
This article presents a failure analysis of an aluminum cylinder head on an automotive engine. During an endurance test, a crack initiated from the interior wall of a hole in the center of the cylinder head, then propagated through the entire thickness of the component. Metallurgical examination of the crack origin revealed that casting pores played a role in initiating the crack. Stress components, identified by finite element analysis, also played a role, particularly the stresses imposed by the bolt assembly leading to plastic strain. It was concluded that the failure can be prevented by eliminating the bolt hole, using a different type of bolt, or adjusting the fastening torque.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003540
EISBN: 978-1-62708-180-1
..., and it has been demonstrated that cracking can be prevented by deoxidizing with titanium or zirconium or by combined titanium and aluminum ( Ref 18 ). Thermal Embrittlement of Maraging Steels Thermal embrittlement of maraging steels occurs when they have been heated above 1095 °C (2000 °F...
Abstract
This article briefly reviews the various metallurgical or environmental factors that cause a weakening of the grain boundaries and, in turn, influence the occurrence of intergranular (IG) fractures. It discusses the mechanisms of IG fractures, including the dimpled IG fracture, the IG brittle fracture, and the IG fatigue fracture. The article describes some typical embrittlement mechanisms that cause the IG fracture of steels.
Book Chapter
Failures Related to Castings
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
... specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance. aluminum casting defects castings copper ductile iron failure analysis gray iron melting solidification steel Introduction...
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003556
EISBN: 978-1-62708-180-1
... the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling...
Abstract
This article focuses on the mechanisms of microbially induced or influenced corrosion (MIC) of metallic materials as an introduction to the recognition, management, and prevention of microbiological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It discusses the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling and analysis of conditions usually achieved by the installation of removable coupons in the target system. The article also explains the prevention and control strategies of MIC in industrial systems.
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