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Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.steel.c9001233
EISBN: 978-1-62708-232-7
... Sulfurization X10CrAl 7 Fe-0.37C-26Cr Fe-0.29C-26Cr High-temperature corrosion and oxidation Pipes 42.25 × 3.25 mm from a blast furnace gas fired recuperator for the preheating of air were heavily oxidized and perforated in places. Depending on the load the temperature of the combustion gas in the flue...
Abstract
High-chromium steel pipes 42.25 x 3.25 mm from a blast furnace gas fired recuperator for the preheating of air were heavily oxidized and perforated in places. It was found that the blast furnace gas had a high sulfur content. Both the carburization and the formation of sulfide proved that in addition, from time to time at least, combustion was incomplete and the operation was carried out in a reducing atmosphere, with the result that oxygen deficiency prevented the formation or maintenance of a protective surface layer on the external surface of the pipes. The sulfur would probably not have damaged the nickel-free steel used here at the given temperatures if it had been present as sulfur dioxide in an oxidizing atmosphere. The damage was therefore caused primarily by an incorrectly conducted combustion process.
