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Cassio Barbosa, Ibrahim de Cerqueira Abud, Tatiana Silva Barros, Sheyla Santana de Carvalho, Ieda Maria Vieira Caminha
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Cássio Barbosa, Jôneo Lopes do Nascimento, José Luiz Fernandes, Ibrahim de Cerqueira Abud
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Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.matlhand.c9001453
EISBN: 978-1-62708-224-2
.... Furthermore, the welds were at the ends and not at the sides as is usual in the case of electrically-welded chains. A transverse section from one side of a link was examined microscopically. This showed the material to be wrought-iron of satisfactory quality. It was concluded this chain sling had been made...
Abstract
While a chain sling was being used to lift a casting one of the links ruptured. The sling, reputed to be of the electrically-welded steel type, was at least eight years old and had been overhauled several times during its working life. Examination showed the links were scarf-welded. Furthermore, the welds were at the ends and not at the sides as is usual in the case of electrically-welded chains. A transverse section from one side of a link was examined microscopically. This showed the material to be wrought-iron of satisfactory quality. It was concluded this chain sling had been made from wrought-iron, forge welded in the usual manner, and that it was not electrically-welded steel as had been supposed. Failure was attributed to embrittlement in service of the surface material of the links. If it had been realized that the sling was made from wrought-iron then it would doubtless have been subjected to periodical annealing in accordance with Statutory requirements, which would have restored the ductility of the surface material.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.bldgs.c9001147
EISBN: 978-1-62708-219-8
... Abstract The century-old Harvard bridge spans the Charles River between Boston and Cambridge. About half of the 23 spans are suspended by wrought iron eyebars. Recent failures of some of these eyebars were examined. The primary cause of failure was the seizure of the joints at the eyebar pin...
Abstract
The century-old Harvard bridge spans the Charles River between Boston and Cambridge. About half of the 23 spans are suspended by wrought iron eyebars. Recent failures of some of these eyebars were examined. The primary cause of failure was the seizure of the joints at the eyebar pin locations as a result of the intrusion of water and salt, and the consequent heavy corrosion of the joint. The seizure of these joints led to high edgewise bending stress in the bars as the bridge underwent thermal movement. The cracking was enhanced by the presence of the corrosive medium so that the cracks were initiated and caused to grow by some combination of corrosion fatigue and stress-corrosion cracking, the former probably being predominant.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.homegoods.c9001610
EISBN: 978-1-62708-222-8
... cobalt-chrome-molybdenum alloy ISO 5832-4 Wrought cobalt-chrome-tungsten- nickel alloy ISO 5832-5 Wrought cobalt-nickel-chrome- molybdenum alloy ISO 5832-6 Wrought cobalt-chrome-nickel- molybdenum-iron alloy ISO 5832-7 Wrought cobalt-nickel-chrome- molybdenum-tungsten-iron alloy ISO 5832...
Abstract
This investigation characterizes five surgical stainless steel piercings and one niobium piercing that caused adverse reactions during use, culminating with the removal of the jewelry. Chemical composition shows that none of the materials are in accordance with ISO standards for surgical implant materials. Additionally, none of the stainless steel piercings passed the pitting-resistance criterion of ISO 5832-1, which implies that [%Cr + 3.3(%Mo)] > 26. Under microscopic examination, most of the jewelry revealed the intense presence of linear irregularities on the surface. The lack of resistance to pitting corrosion associated with the poor surface finishing of the stainless steel jewelry may induce localized corrosion, promoting the release of cytotoxic metallic ions (such as Cr, Ni, and Mo) in the local tissue, which can promote several types of adverse effects in the human body, including allergic reactions. The adverse reaction to the niobium jewelry could not be directly associated with the liberation of niobium ions or the residual presence of cytotoxic elements such as Co, Ni, Mo, and Cr. The poor surface finish of the niobium jewelry seems to be the only variable of the material that may promote adverse reactions.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c9001683
EISBN: 978-1-62708-234-1
... that voids generally grew in the wrought material by uniform general corrosion. Tunneling or worm-holing was also observed, whereby void extension occurred by initiating daughter voids probably at flaws or other inhomogeneities. Selective attack occurred within the fusion zone, i.e., within the cast two...
Abstract
Corrosion in a closed-loop cooling water system constructed of austenitic stainless steel occurred during an extended lay up of the system with biologically contaminated water. The characteristics of the failure were those of microbiologically influenced corrosion (MIC). The corrosion occurred at welds and consisted of large subsurface void formations with pinhole penetrations of the surfaces. Corrosive attack initiated in the heat affected zones of the welds, usually immediately adjacent to fusion lines. Stepwise grinding, polishing, and etching through the affected areas revealed that voids generally grew in the wrought material by uniform general corrosion. Tunneling or worm-holing was also observed, whereby void extension occurred by initiating daughter voids probably at flaws or other inhomogeneities. Selective attack occurred within the fusion zone, i.e., within the cast two-phase structure of the weld filler itself. The result was a void wall which consisted of a rough and porous ferritic material, a consequence of preferential attack of the austenitic phase and slightly lower rate of corrosive attack of the ferrite phase. The three-dimensional spongy surface was studied optically and with the scanning electron microscope.
Book Chapter
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001804
EISBN: 978-1-62708-241-9
... electron microscopy fatigue strength ASTM F138 (wrought stainless steel) UNS S31673 Introduction In the last decades the noticeable aging of the world population has contributed to a considerable growth in the amount of surgeries of different types, in spite of the significant contribution...
Abstract
A stainless steel screw securing an orthopedic implant fractured and was analyzed to determine the cause. Investigators used optical and scanning electron microscopy to examine the fracture surfaces and the microstructure of the austenitic stainless steel from which the screw was made. The results of the study indicated that the screw failed due to fatigue fracture stemming from surface cracks generated by stress concentration likely caused by grooves left by improper machining.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.marine.c9001591
EISBN: 978-1-62708-227-3
... to the fracture of the rivets holding the hull plates together. The rivets were made from wrought iron. This implies that fracture of the plates would not have occurred as the iceberg raked the hull for 100 m. There were examples of fracture with no ductile behavior observed on the edges of the plates recovered...
Abstract
On 14 April 1912, at 11:40 p.m., Greenland Time, the Royal Mail Ship Titanic on its maiden voyage was proceeding westward at 21.5 knots (40 km/h) when the lookouts on the foremast sighted a massive iceberg estimated to have weighed between 150,000 to 300,000 tons at a distance of 500 m ahead. Immediately, the ship’s engines were reversed and the ship was turned to port (left) in an attempt to avoid the iceberg. In about 40 sec, the ship struck the iceberg below the waterline on its starboard (right) side near the bow. The iceberg raked the hull of the ship for 100 m, destroying the integrity of the six forward watertight compartments. Within 2 h 40 min the RMS Titanic sank. Metallurgical examination and chemical analysis of the steel taken from the Titanic revealed important clues that allow an understanding of the severity of the damage inflicted on the hull. Although the steel was probably as good as was available at the time the ship was constructed, it was very inferior when compared with modern steel. The notch toughness showed a very low value (4 J) for the steel at the water temperature (-2 deg C) in the North Atlantic at the time of the accident.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c9001684
EISBN: 978-1-62708-225-9
... a slightly different Zn content. The microstructure of the nut in Fig. 5 shows that it is in the wrought condition. It contains α and β, and lead particles are also present. These phases are discriminated by the EDS analysis ( Fig. 5 ). Fig. 4 Microstructure of the shaft. Fig. 5...
Abstract
The steam tug Hercules was an ocean-going and bay tug for 55 years before being retired. It is now being restored by the National Park Service. A broken steam valve was obtained for microstructural examination. The body was gray cast iron, and the stem and seat were brass. The examination centered on corrosion of the brass components. The seat and shaft were alpha brass, with a hardness of 64 and 79 DPH, respectively. A nut held the shaft onto the seat, and was alpha-beta brass with a hardness of 197 DPH. Welded on the end of the shaft was a ring of hard (DPH 294) alpha-beta brass, which seated against the nut. The brass seat and stem show little corrosion. However, the alpha-beta brass nut and welded tip showed extensive dezincification. This process of removal of Zn and the retention of Cu began in the high Zn beta phase, but eventually both phases were attacked. The depth of penetration was consistent with dezincification rates reported in the literature for such brasses in salt water if the valve had been in service about 55 years.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003508
EISBN: 978-1-62708-180-1
... cast iron low-alloy steel malleable irons pressure die casting semisolid casting squeeze casting FAILURES OF CASTINGS, like the failures of wrought materials, can occur from service conditions, improper design and/or materials selection, manufacturing deficiencies, or a combination...
Abstract
This article focuses on the general root causes of failure attributed to the casting process, casting material, and design with examples. The casting processes discussed include gravity die casting, pressure die casting, semisolid casting, squeeze casting, and centrifugal casting. Cast iron, gray cast iron, malleable irons, ductile iron, low-alloy steel castings, austenitic steels, corrosion-resistant castings, and cast aluminum alloys are the materials discussed. The article describes the general types of discontinuities or imperfections for traditional casting with sand molds. It presents the international classification of common casting defects in a tabular form.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003529
EISBN: 978-1-62708-180-1
... with 15% chromium. Another important characteristic that the chemist should be made aware of is whether the material has been wrought or is in an as-cast condition. As-cast products usually have more segregation than wrought products, so the sampling needs to be done from more layers of the material...
Abstract
This article describes some of the common elemental composition analysis methods and explains the concept of referee and economy test methods in failure analysis. It discusses different types of microchemical analyses, including backscattered electron imaging, energy-dispersive spectrometry, and wavelength-dispersive spectrometry. The article concludes with information on specimen handling.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
... to perform without failure. Castings are integral parts of many components and, like wrought components, they rarely fail to perform their intended functions. The failures that do occur result from service conditions, improper design and/or materials selection, manufacturing deficiencies, potential...
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006835
EISBN: 978-1-62708-329-4
... Abstract The primary purpose of this article is to describe general root causes of failure that are associated with wrought metals and metalworking. This includes a brief review of the discontinuities or imperfections that may be common sources of failure-inducing defects in the bulk working...
Abstract
The primary purpose of this article is to describe general root causes of failure that are associated with wrought metals and metalworking. This includes a brief review of the discontinuities or imperfections that may be common sources of failure-inducing defects in the bulk working of wrought products. The article addresses the types of flaws or defects that can be introduced during the steel forging process itself, including defects originating in the ingot-casting process. Defects found in nonferrous forgings—titanium, aluminum, and copper and copper alloys—also are covered.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001774
EISBN: 978-1-62708-241-9
... the formation of polythionic acid in the process gas. ring type pipe joint fracture polythionic acid stainless steel transgranular fracture fractography creep strength 347 (austenitic wrought stainless steel) UNS S34700 321 (austenitic wrought stainless steel) UNS S32100 Introduction...
Abstract
A ring-type joint in a reactor pipeline for a hydrocracker unit had failed. Cracks were observed on the flange and the associated ring gasket during an inspection following a periodic shutdown of the unit. The components were manufactured from stabilized grades of austenitic stainless steel; the flange from type 321, and the ring gasket from 347. Examination revealed that the failure occurred by transgranular stress-corrosion cracking, initiated by the presence of polythionic acid. Detailed metallurgical investigation was subsequently conducted to identify what may have caused the formation of polythionic acid in the process gas.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.9781627083294
EISBN: 978-1-62708-329-4
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.petrol.c9001638
EISBN: 978-1-62708-228-0
... used successfully in this application worldwide. During the 1960s, numerous failures of HK, HT, and HU cast headers and transfer lines were experienced. This was mainly due to lack of ductility of the cast alloys with an accompanying lack of resistance to thermal shock. Wrought Incoloy 800H, while...
Abstract
An Incoloy 800H (UNS N08810) transfer line on the outlet of an ethane-cracking furnace failed during decoking of the furnace tubes after nine years in service. A metallographic examination using optical and scanning electron microscopy as well as energy-dispersive x-ray spectroscopy revealed that the failure was due to sulfidation. The source of the sulfur in the furnace effluent was either dimethyl disulfide, injected into the furnace feed to prevent coke formation and carburization of the furnace tubes, or contamination of the feed with sulfur bearing oil.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001808
EISBN: 978-1-62708-241-9
... of poor operations or improper materials selection, and thus often preventable. heat exchangers drain lines corrosion bacterial growth copper stainless steel pitting perforations microscopy corrosion resistance 304L stainless steel (austenitic wrought stainless steel) UNS S30403 316L...
Abstract
Six cases of failure attributed to microbiologically influenced corrosion (MIC) were analyzed to determine if any of the failures could have been avoided or at least predicted. The failures represent a diversity of applications involving typical materials, primarily stainless steel and copper alloys, in contact with a variety of liquids, chemistries, and substances. Analytical techniques employed include stereoscopic examination, energy dispersive x-ray spectroscopy (EDS), temperature and pH testing, and metallographic analysis. The findings indicate that MIC is frequently the result of poor operations or improper materials selection, and thus often preventable.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003507
EISBN: 978-1-62708-180-1
... Abstract This article describes the general root causes of failure associated with wrought metals and metalworking. This includes a brief review of the discontinuities or imperfections that may be the common sources of failure-inducing defects in bulk working of wrought products. The article...
Abstract
This article describes the general root causes of failure associated with wrought metals and metalworking. This includes a brief review of the discontinuities or imperfections that may be the common sources of failure-inducing defects in bulk working of wrought products. The article discusses the types of imperfections that can be traced to the original ingot product. These include chemical segregation; ingot pipe, porosity, and centerline shrinkage; high hydrogen content; nonmetallic inclusions; unmelted electrodes and shelf; and cracks, laminations, seams, pits, blisters, and scabs. The article provides a discussion on the imperfections found in steel forgings. The problems encountered in sheet metal forming are also discussed. The article concludes with information on the causes of failure in cold formed parts.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006826
EISBN: 978-1-62708-329-4
..., or calcium can be added to hypoeutectic aluminum-silicon alloys to progressively change the silicon lamellae into rounded particles, and phosphorus refines the size of silicon particles in hypereutectic aluminum-silicon alloys ( Ref 26 ). Microsegregation in wrought alloys is a microstructural defect...
Abstract
The first part of this article focuses on two major forms of machining-related failures, namely machining workpiece (in-process) failures and machined part (in-service) failures. Discussion centers on machining conditions and metallurgical factors contributing to (in-process) workpiece failures, and undesired surface layers and metallurgical factors contributing to (in-service) machined part failures. The second part of the article discusses the effects of microstructure on machining failures and their preventive measures.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001329
EISBN: 978-1-62708-215-0
... of wrought aluminum bronze material (α phase). This microstructure was found in all of the specimens examined. The socket-weld material was dendritic in appearance ( Fig. 5 ), and no evidence of cracking was found in any of the sections examined. Fig. 4 Microstructure of pipe material, composed of α...
Abstract
Various aluminum bronze valves and fittings on the essential cooling water system at a nuclear plant were found to be leaking. The leakage was limited to small-bore socket-welded components. Four specimens were examined: three castings (an ASME SB-148 CA 952 elbow from a small-bore fitting and two ASME SB-148 CA 954 valve bodies) and an entire valve assembly. The leaks were found to be in the socket-weld crevice area and had resulted from dealloying. It was recommended that the weld joint geometry be modified.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.design.c9001424
EISBN: 978-1-62708-233-4
... the higher modulus of rigidity of the wrought compared with that of the cast material. It cannot be emphasised too strongly that a fabricated structure requires to be designed as such and to produce it simply as a lightened version of a casting that has given satisfactory service is most undesirable...
Abstract
Two examples concerning fabricated mild steel rotor spiders which failed due to lack of torsional rigidity, probably supplemented by the presence of high internal stress, are described. The machine concerned in the first case was a 3,000 hp three-phase slip-ring motor. In the second case the machine was a 200 kW alternator, direct-driven by a diesel engine running at 750 rpm. Both the foregoing failures reveal the same basic weakness, i.e., insufficient rigidity when subjected to variations or reversals of torque. In the first case, the bars welded to the arms were inadequately supported in a lateral direction, so that excessive stresses of a fluctuating nature were set up in the welds as a result of the frequent load changes that arose in service. This weakness was eliminated when designing the replacement spider. In the second example, failure also arose as a result of deficient torsional rigidity with the consequent development of excessive stresses in the welds at the junctions of the bars with the sleeve, the torque being of a fluctuating character due to the impulses imparted by the engine.
Book Chapter
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001819
EISBN: 978-1-62708-241-9
... Handbook , Becker W.T. and Shipley R.J. , Ed., ASM International , 1986 , p 459 – 482 . 10.31399/asm.hb.v11.a0001808 • Washlo S.D. and Aggen G. , Wrought Stainless Steels , Properties and Selection: Irons, Steels, and High-Performance Alloys , Vol 1 , ASM Handbook...
Abstract
The shafts on two centrifugal pumps failed during use in a petroleum refinery. Light optical microscopy and scanning electron microscopy were used to analyze the damaged materials to determine the cause of failure. The results showed that one shaft, made of duplex stainless steel, failed by fatigue fracture, and the other, made of 316 austenitic stainless steel, experienced a similar fracture, which was promoted by the presence of nonmetallic inclusion particles.
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