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Tin bronze
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Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c9001530
EISBN: 978-1-62708-225-9
... tin bronzes appear to be the workhorses in bearing and bushing applications. These alloys mainly derive their strength and hardness from tin while lead, being present as insoluble, soft second phase in the microstructure, provides good antifrictional properties. These alloys may also contain zinc...
Abstract
This paper describes an investigation on the failure of a large leaded bronze bearing that supports a nine-ton roller of a plastic calendering machine. At the end of the normal service life of a good bearing, which lasted for seven years, a new bearing was installed. However the new one failed catastrophically within a few days, generating a huge amount of metallic wear debris and causing pitting on the surface of the cast iron roller. Following the failure, samples were collected from both good and failed bearings. The samples were analyzed chemically and their microstructures examined. Both samples were subjected to accelerated wear tests in a laboratory type pin-on-disk apparatus. During the tests, the bearing materials acted as pins, which were pressed against a rotating cast iron disk. The wear behaviors of both bearing materials were studied using weight loss measurement. The worn surfaces of samples and the wear debris were examined by light optical microscope, SEM, and energy-dispersive x-ray microanalyzer. It was found that the laboratory pin-on-disk wear data correlated well with the plant experience. It is suggested that the higher lead content ~18%) of the good bearing compared with 7% lead of the failed bearing helped to establish a protective transfer layer on the worn surface. This transfer layer reduced metal-to-metal contact between the bearing and the roller and resulted in a lower wear rate. The lower lead content of the failed bearing does not allow the establishment of a well-protected transfer layer and leads to rapid wear.
Series: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001078
EISBN: 978-1-62708-214-3
... were examined using SEM microscopy. Failure of the gears was attributed to heavy wear resulting from misalignment. A lack of adequate lubrication was also noted. Periodic alignment adjustment and lubrication were recommended. Catastrophic wear Gear teeth Nuclear reactor components Tin bronze...
Abstract
A gear belonging to a pressurized heavy-water reactor refueling machine failed after 10 years in service. The material specified for the gear was a type C90700 bronze. Macroscopic examination focused on three gear teeth that had fractured completely at the roots, and fracture zones were examined using SEM microscopy. Failure of the gears was attributed to heavy wear resulting from misalignment. A lack of adequate lubrication was also noted. Periodic alignment adjustment and lubrication were recommended.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001809
EISBN: 978-1-62708-180-1
... of the substrate. In some instances, a nickel barrier about 1 μm thick may be placed between the substrate and the overlay to prevent diffusion of tin from the overlay to the copper in the substrate. Bronze Bearing Materials Bronze bearing materials are either leaded bronze, tin bronze, or aluminum bronze...
Abstract
This article discusses the classification of sliding bearings and describes the major groups of soft metal bearing materials: babbitts, copper-lead bearing alloys, bronze, and aluminum alloys. It provides a discussion on the methods for fluid-film lubrication in bearings. The article presents the variables of interest for a rotating shaft and the load-carrying capacity and surface roughness of bearings. Grooves and depressions are often provided in bearing surfaces to supply or feed lubricant to the load-carrying regions. The article explains the effect of contaminants in bearings and presents the steps for failure analysis of sliding bearings. It also reviews the factors responsible for bearing failure with examples.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006806
EISBN: 978-1-62708-329-4
... Bearing Materials Bronze bearing materials are either leaded bronze, tin bronze, or aluminum bronze. Strength and high-temperature resistance increase in the order lead to tin to aluminum, but embeddability and scuff resistance decrease in that order. The leaded bronzes contain from 5 to 25% Pb...
Abstract
A mechanical part, which supports the moving part, is termed a mechanical bearing and can be classified into rolling (ball or roller) bearings and sliding bearings. This article discusses the failures of sliding bearings. It first describes the geometry of sliding bearings, next provides an overview of bearing materials, and then presents the various lubrication mechanisms: hydrostatic, hydrodynamic, boundary lubrication, elastohydrodynamic, and squeeze-film lubrication. The article describes the effect of debris and contaminant particles in bearings. The steps involved in failure analysis of sliding bearings are also covered. Finally, the article discusses wear-damage mechanisms from the standpoint of bearing design.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001822
EISBN: 978-1-62708-180-1
... and lead with a minor amount of tin. These elements are the major constituents of the bronze friction bearing. The copper-penetration failure occurred in the following sequence: The bearing surface was heated by friction because of loss of lubrication The babbitt metal lining melts between about...
Abstract
This article provides a background of friction-bearing failures due to overheating. The failures of locomotive axles caused by overheated traction-motor support bearings are discussed. The article also describes liquid-metal embrittlement (LME) in steel. It examines the results of various axle studies, with illustrations and concludes with information on the simulation of the LME mechanism.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.rail.c9001719
EISBN: 978-1-62708-231-0
... that has solidified after failure is often found in the crack. The best determinate of LME is the identification phase of metal that exists in the crack after failure. Low carbon steels are known to exhibit LME susceptibility to brass, aluminum bronze, copper, zinc, lead-tin solder, indium, and lithium...
Abstract
Metallography is an important component of failure analysis. In the case of a liquid metal embrittlement (LME) failure it is usually conclusive if a third phase constituent can be formed inside of the cracks after failure. In the case where it is necessary to characterize the third phase material, one can use various x-ray spectrographic techniques in conjunction with a scanning electron microscope (SEM). This study describes those metallographic and SEM analysis techniques for determining the mode of failure for a locomotive traction motor by LME.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003554
EISBN: 978-1-62708-180-1
... Titanium Hg, Cd, Ag, Au It should be pointed out that alloys of these embrittler metals can also be embrittling. In fact, for service failures, the embrittling metal is probably not pure but is impure or an alloy. For example, tin- and lead-base bearing alloys and solders also cause metal-induced...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or fracture stress of a solid metal is reduced by surface contact with another metal in either liquid or solid form. This article summarizes the characteristics of solid metal induced embrittlement (SMIE) and liquid metal induced embrittlement (LMIE). It describes the unique features that assist in arriving at a clear conclusion whether SMIE or LMIE is the most probable cause of the problem. The article briefly reviews some commercial alloy systems where LMIE or SMIE has been documented. It also provides some examples of cracking due to these phenomena, either in manufacturing or in service.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006786
EISBN: 978-1-62708-295-2
... of these embrittler metals can also be embrittling. In fact, for service failures, the embrittling metal is probably not pure but is impure or an alloy. For example, tin- and lead-base bearing alloys and solders also cause metal-induced embrittlement. Furthermore, some alloy additions to embrittling metals have been...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or the fracture stress of a solid metal is reduced by surface contact with another metal in either the liquid or solid form. This article summarizes some of the characteristics of liquid-metal- and solid-metal-induced embrittlement. This phenomenon shares many of these characteristics with other modes of environmentally induced cracking, such as hydrogen embrittlement and stress-corrosion cracking. The discussion covers the occurrence, failure analysis, and service failures of the embrittlement. The article also briefly reviews some commercial alloy systems in which liquid-metal-induced embrittlement or solid-metal-induced embrittlement has been documented and describes some examples of cracking due to these phenomena, either in manufacturing or in service.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.power.c9001521
EISBN: 978-1-62708-229-7
... . Nominal composition (in wt%) is 70Cu, 29Zn, 1Sn, and 0.03As. Tin and arsenic are added to inhibit dezincification. Brass was chosen for the tubes because of its excellent thermal conductivity. The tubes are furnished in the annealed condition and have minimum yield strength of 100 MPa (15 ksi) and tensile...
Abstract
Admiralty brass (Alloy C44300) cooling tubes which were part of a heat exchanger in a turbogenerator that provided electricity to a manufacturing plant failed. A mixture of non-recirculating city and “spring pit” water flowed through bundles of tubes to cool the oil in which they are immersed. However, a problem developed when several of the brass tubes cracked transversely, allowing cooling water to mix with the oil. The presence of a tensile stress, intergranular cracks, and a corrosion product suggested the tube failures resulted from stress-corrosion cracking. The main corrosion product was cupric hydroxychloride. In addition to switching to a more corrosion-resistant alloy, extreme care should be taken in the manufacturing of the replacement tube bundles to avoid imparting any residual tensile stresses in the tubing. Analyses of city and spring-pit water were recommended also, to determine which contained the least-harmful corrosive chemicals.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003548
EISBN: 978-1-62708-180-1
.... Performance of Alloy Groupings Magnesium Magnesium occupies an extremely active position in most galvanic series and is therefore highly susceptible to galvanic corrosion. Metals that combine active potentials with higher hydrogen overvoltages, such as aluminum, zinc, cadmium, and tin, are much less...
Abstract
This article addresses the forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. It describes the mechanisms of corrosive attack for specific forms of corrosion such as galvanic corrosion, uniform corrosion, pitting and crevice corrosion, intergranular corrosion, and velocity-affected corrosion. The article contains a table that lists combinations of alloys and environments subjected to selective leaching and the elements removed by leaching.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006783
EISBN: 978-1-62708-295-2
... that combine active potentials with higher hydrogen overvoltages, such as aluminum, zinc, cadmium, and tin, are much less damaging, although not fully compatible with magnesium. Aluminum alloys that contain small percentages of copper (7000 and 2000 series and 380 die-casting alloy) may cause serious...
Abstract
Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006820
EISBN: 978-1-62708-329-4
... from hardened steel alloys. With worm gears, the most common applications involve surface-hardened steel worms with bronze gears, although the use of steel worms with polymer gears is increasing. The two most common alloys for the gears are high-tin bronzes, C90700 and C91700. It is important...
Abstract
This article first reviews variations within the most common types of gears, namely spur, helical, worm, and straight and spiral bevel. It then provides information on gear tooth contact and gear metallurgy. This is followed by sections describing the important points of gear lubrication, the measurement of the backlash, and the necessary factors for starting the failure analysis. Next, the article explains various gear failure causes, including wear, scuffing, Hertzian fatigue, cracking, fracture, and bending fatigue, and finally presents examples of gear and reducer failure analysis.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c9001684
EISBN: 978-1-62708-225-9
... , Battelle, Columbus, Ohio , 1970 . 4. Leidheiser H. , The Corrosion of Copper, Tin, and Their Alloys , Wiley , New York , 1971 . 5. Metals Handbook , 10th ed. , Vol. 2 . Properties and Selection:Nonferrous Alloys and Special-Purpose Materials , ASM International , Materials Park...
Abstract
The steam tug Hercules was an ocean-going and bay tug for 55 years before being retired. It is now being restored by the National Park Service. A broken steam valve was obtained for microstructural examination. The body was gray cast iron, and the stem and seat were brass. The examination centered on corrosion of the brass components. The seat and shaft were alpha brass, with a hardness of 64 and 79 DPH, respectively. A nut held the shaft onto the seat, and was alpha-beta brass with a hardness of 197 DPH. Welded on the end of the shaft was a ring of hard (DPH 294) alpha-beta brass, which seated against the nut. The brass seat and stem show little corrosion. However, the alpha-beta brass nut and welded tip showed extensive dezincification. This process of removal of Zn and the retention of Cu began in the high Zn beta phase, but eventually both phases were attacked. The depth of penetration was consistent with dezincification rates reported in the literature for such brasses in salt water if the valve had been in service about 55 years.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001813
EISBN: 978-1-62708-180-1
... on their rustlike surface scale. The white deposit was 100% water soluble and had a pH of 9.6 (slightly alkaline). Spectrographic examination showed the surface scale to contain a high amount of sodium, a small amount of tin, a high trace of zinc, and traces of lead and calcium. Chemical analysis of the spring...
Abstract
This article discusses the common causes of failures of springs, with illustrations. Design deficiencies, material defects, processing errors or deficiencies, and unusual operating conditions are the common causes of spring failures. In most cases, these causes result in failure by fatigue. The article describes the operating conditions of springs, common failure mechanisms, and presents an examination of the failures that occur in springs.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003529
EISBN: 978-1-62708-180-1
... must specify what amount is being sought. For example, embrittlement from amounts of tin less than 0.001% can cause a problem, if the tin is in the “wrong places” in the microstructure. Many of the standard or economy methods simply will not detect these small amounts. Likewise, very high...
Abstract
This article describes some of the common elemental composition analysis methods and explains the concept of referee and economy test methods in failure analysis. It discusses different types of microchemical analyses, including backscattered electron imaging, energy-dispersive spectrometry, and wavelength-dispersive spectrometry. The article concludes with information on specimen handling.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006778
EISBN: 978-1-62708-295-2
... to the preexisting crack path provided by the grain boundaries, dimpled intergranular fracture requires less energy to effect separation than that for typical transgranular ductile rupture. The following example is a case history where this behavior was noted. Example 4: Overload Failure of a Bronze Worm Gear...
Abstract
This article aims to identify and illustrate the types of overload failures, which are categorized as failures due to insufficient material strength and underdesign, failures due to stress concentration and material defects, and failures due to material alteration. It describes the general aspects of fracture modes and mechanisms. The article briefly reviews some mechanistic aspects of ductile and brittle crack propagation, including discussion on mixed-mode cracking. Factors associated with overload failures are discussed, and, where appropriate, preventive steps for reducing the likelihood of overload fractures are included. The article focuses primarily on the contribution of embrittlement to overload failure. The embrittling phenomena are described and differentiated by their causes, effects, and remedial methods, so that failure characteristics can be directly compared during practical failure investigation. The article describes the effects of mechanical loading on a part in service and provides information on laboratory fracture examination.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006777
EISBN: 978-1-62708-295-2
... to eutectoid divorcement in low-carbon steels Grain-boundary hypereutecoid cementite in carburized or hypereutectoid steels Iron nitride grain-boundary films in nitrided steels Temper embrittlement in heat treated steels due to segregation of phosphorus, antimony, arsenic, or tin Embrittlement...
Abstract
This article briefly reviews the factors that influence the occurrence of intergranular (IG) fractures. Because the appearance of IG fractures is often very similar, the principal focus is placed on the various metallurgical or environmental factors that cause grain boundaries to become the preferred path of crack growth. The article describes in more detail some typical mechanisms that cause IG fracture. It discusses the causes and effects of IG brittle cracking, dimpled IG fracture, IG fatigue, hydrogen embrittlement, and IG stress-corrosion cracking. The article presents a case history on IG fracture of steam generator tubes, where a lowering of the operating temperature was proposed to reduce failures.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003543
EISBN: 978-1-62708-180-1
... of a Bronze Worm Gear A very large diameter worm gear that had been in service in a dam for more than 60 years exhibited cracks and was removed. It was reported that the cast bronze gear was only rarely stressed during service, associated with infrequent opening and closing of gates. Due to the age...
Abstract
Overload failures refer to the ductile or brittle fracture of a material when stresses exceed the load-bearing capacity of a material. This article reviews some mechanistic aspects of ductile and brittle crack propagation, including a discussion on mixed-mode cracking, which may also occur when an overload failure is caused by a combination of ductile and brittle cracking mechanisms. It describes the general aspects of fracture modes and mechanisms. The article discusses some of the material, mechanical, and environmental factors that may be involved in determining the root cause of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.9781627083294
EISBN: 978-1-62708-329-4
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