Tube sheets (found to be copper alloy C46400, or naval brass, and 5 cm (2 in.) thick) of an air compressor aftercooler were found to be cracked and leaking approximately 12 to 14 months after they had been retubed. Most of the tube sheets had been retubed several times previously because of unrelated tube failures. Sanitary (chlorinated) well water was generally used in the system, although filtered process make-up water (river water) containing ammonia was occasionally used. Investigation (visual inspection, chemical analysis, mercurous nitrate testing, unetched 5X micrographs, and 250X micrographs etched in 10% ammonium persulfate solution) supported the conclusion that the tube sheets failed by SCC as a result of the combined action of internal stresses and a corrosive environment. The internal stresses had been induced by retubing operations, and the environment had become corrosive when ammonia was introduced into the system by the occasional use of process make-up water. Recommendations included making a standard procedure to stress relieve tube sheets before each retubing operation. The stress relieving should be done by heating at 275 deg C (525 deg F) for 30 min and slowly cooling for 3 h to room temperature.

The source of cracking in the circumferential weld seam in a JIS-SM50B carbon-manganese steel pipe used in a CO2 absorber was investigated, the absorber had been in service for 18 years. The seam had been weld-repaired twice, and the repair welds had been locally stress relieved. Longitudinal seams in the same vessel, which had been stress relieved in a furnace, showed no tendency toward cracking. The solution passing through the vessel contained CO2-CO-H20, KHCO, and Cl− ions. Nondestructive testing revealed that the cracks originated in the heat-affected zone and propagated into the base metal and weld. Severe branching of the cracks characteristic of stress-corrosion cracking was observed. Microexamination revealed that crack propagation was transgranular further supporting the possibility of stress-corrosion cracking. Simulation tests carried out in the vessel confirmed this mode of cracking. It was recommended that weld seams be furnace heat treated at a temperature of 600 to 640 deg C (1110 to 1180 deg F) for a minimum of 1 h per inch of section thickness.

A number of AISI 347 stainless steel bellows intended for use in the control rod drive mechanism of a fast breeder reactor were found to be leaking before being placed in service. The bellows, which had been in storage for one year in a seacoast environment, exhibited a leak rate on the order of 1 x 10−7 cu cm/s (6 x 10−8 cu in./s). Optical metallography revealed numerous pits and cracks on the surfaces of the bellow convolutes, which had been welded to one another using an autogenous gas tungsten arc welding process. Microhardness measurements indicated that the bellows had not been adequately stress relieved. It was recommended that a complete stress-relieving treatment be applied to the formed bellows. Improvement of storage conditions to avoid direct and prolonged contact of the bellows with the humid, chloride-containing environment was also recommended.

Following the discovery numerous cracks at many of the welded seams of a mild steel CO2 absorber vessel, a sample for examination was removed from the worst affected area where repairs had been effected. A 12 in. long circumferential crack was visible. Specimens were taken to cover the several locations of cracking which, in all cases, were found to be similar and of the intergranular type filled with oxide or corrosion product. The association of the cracks with the weld seams indicated that contraction stresses from welding were primarily responsible. Failure of the absorber vessel was found to be due to stress corrosion. Although the active agent present was not positively identified, the aqueous solution of monoethanolamine was thought to be the most probable. The origin of the stresses was not elucidated but the association of the cracks with the welded seams indicated inherent residual stresses as being primarily responsible. Tests carried out tend to suggest that stress relief was not carried out. For the replacement plant, consideration of stress relieving or the use of an alternative material was advised.

Following disruption of the austenitic stainless steel basket of a hydro-extractor used for the separation of crystals of salt (sodium chloride) from glycerin, samples of the broken parts were analyzed. Examination revealed that the fish-plates joining the reinforcing hoops had broken, the shell had split from top to bottom adjacent to the weld, the top and bottom cover plates had become loose, all the rivets having pulled out, and the shaft was also found to be bent. Fracture took place in an irregular manner and was of the shear type towards both ends; it occurred immediately adjacent to the weld or a short distance from it and on alternate sides. Microscopical examination did not reveal any intergranular carbide precipitation, such as is well known to result in the weld-decay mode of failure. It was concluded that the primary cause of failure was stress-corrosion cracking arising from the combined effect of residual stresses and the corrosive effect of the material being centrifuged. If the shell had been stress-relieved after fabrication, the failure likely would not have occurred.

An agricultural tine, which is a relatively large double torsion spring with outer legs that are used to sweep through hay or other crops and turn them over, had failed. It was made hard-drawn carbon steel. Bending fatigue was revealed by visual examination to be almost certainly the cause of failure. The fatigue fracture origin was found on the inside surface of the legs at the point where they joined the coiled body of the spring. It was established that the tines after being wound up by loading with hay, sprung back through the neutral unloaded position and into the unwind direction. This movement into the unwind direction was concluded to be happening often enough to initiate fatigue. The stress relieving temperature was recommended to be increased to reduce the residual stresses from coiling and hence improve fatigue performance.

Two diesel engine crankshafts of similar dimensions, the journal diam being approximately 7 in., failed due to cracking originating in the fillet at the junction between the crankpin and the web nearest to the flywheel. The cracks were discovered before rupture occurred. Several small cracks originated in the fillet, ran together and developed as two main crack fronts that ultimately merged into one, a typical example of a fatigue failure. Electromagnetic crack detection revealed the presence of a number of discontinuities which were located at a position that would correspond to the vertical axis of the original ingot. The crankshaft had not been stress-relieved after a welding operation had been carried out. The only satisfactory course to follow when dealing with a highly stressed part in which defects of the type in question are revealed during machining is to scrap the forging.

A 150 cm ID boiler drum made form ASTM A515, grade 70, steel failed during final hydrotesting at a pressure of approximately 26 MPa. Brittle fractures were revealed in between two SA-106C nozzles and remainder was found to involve tearing. Short, flat segments of fracture area, indicative of pre-existing cracks, were revealed by examination of the fracture surface at the drain grooves arc gouged at the nozzle sites. A thin layer of material with a dendritic structure was observed at the groove surface. The dendritic layer was revealed by qualitative microprobe analysis to contain over 1% C, higher than the carbon content of the base metal. The cracks in the drain groove surface could have occurred after arc gouging, during subsequent stress-relieving, or during the hydrostatic test. Flame cutting is not recommended for the type of steel used in the boiler drum because it can lead to local embrittlement and stress raisers, potentially initiating major failures.

Two tubular AISI 1025 steel posts (improved design) in a carrier vehicle failed by cracking at the radius of the flange after five weeks of service. The posts were two of four that supported the chassis of the vehicle high above the wheels. The original design involved a flat flange of low-carbon low-alloy steel that was welded to an AISI 1025 steel tube, and the improved design included placing the welded joint of the flange farther away from the flange fillet. Investigation (visual inspection and chemical analysis) supported the conclusion that the failures in the flanges of improved design were attributed to fatigue cracks initiating at the aluminum oxide inclusions in the flange fillet. Recommendations included retaining the improved design of the flange with the weld approximately 50 mm (2 in.) from the fillet, but changing the metal to a forging of AISI 4140 steel, oil quenched and tempered to a hardness of 241 to 285 HRB. Preheating to 370 deg C (700 deg F) before and during welding with AISI 4130 steel wire was specified. It was also recommended that the weld be subjected to magnetic-particle inspection and then stress relieved at 595 deg C (1100 deg F), followed by final machining.

A segment of a stainless steel clad bottom cone of an acid sulfite pulping batch digester failed from severe corrosion loss. The digester was fabricated of 19 mm ( 3 4 in.) low-carbon steel with 3.8 mm (0.15 in.) type 317L stainless steel cladding. The manufacturing method for the cladding was unknown. Visual and metallographic analyses indicated that the failure was from transgranular stress-corrosion cracking (TGSCC), which caused extensive cracking and spalling of the cladding and was localized in a segment of the bottom cone. The remainder of the digester cladding was unaffected. The TGSCC was attributed to high, locked-in residual stresses from the cladding process. It was recommended that the bottom cone replacement segment be stress relieved prior to installation.

A fused-salt electrolytic-cell pot containing a molten eutectic mixture of sodium, potassium, and lithium chlorides and operating at melt temperatures from 500 to 650 deg C (930 to 1200 deg F) exhibited excessive corrosion after two months of service. The pot was a welded cylinder with 3-mm thick type 304 stainless steel walls and was about 305 mm (12 in.) in height and diam. Analysis (visual inspection and 500x micrographs etched with CuCl2) supported the conclusions that the pot failed by intergranular corrosion because an unstabilized austenitic stainless steel containing more than 0.03% carbon had been sensitized and placed in contact in service with a corrosive medium at temperatures in the sensitizing range. Recommendations included changing material for the pot from type 304 stainless steel to Hastelloy N (70Ni-17Mo-7Cr-5Fe). Maximum corrosion resistance and ductility are developed in Hastelloy N when the alloy is solution heat treated at 1120 deg C (2050 deg F) and is either quenched in water or rapidly cooled in air. An alternative, but less suitable, material for the pot was type 347 (stabilized grade) stainless steel. After welding, the 347 should be stress relieved at 900 deg C (1650 deg F) for 2 h and rapidly cooled to minimize residual stresses.

Two 38 mm (1.5 in.) diam threaded stud bolts that were part of a steel mold die assembly from a plastics molding operation were examined to determine their serviceability. Chemical analysis showed the material to be a plain carbon steel that approximated 1045. Visual examination revealed evidence of severe hammer blows to the clevis and boss areas and a gap between the die and the underside of the boss. Magnetic particle inspection showed cracks at the thread roots that, when examined metallographically, were found to contain MnS stringers. The cracking of the threads was attributed to a poor stud bolt design, which allowed a high stress concentration to occur at the base of the threads upon application of a lateral load. It was recommended that bolts of a new design that incorporated a stress-relieving groove be used. Threading of the bolt to eliminate the gap between the lower face of the boss and the die and an improved method of inserting or removing the bolt to avoid hammering (use of a wrench on a square or hexagonal boss) were also recommended.

Several compressor diaphragms from five gas turbines cracked after a short time in service. The vanes were constructed of type 403 stainless steel, and welding was performed using type 309L austenitic stainless steel filler metal. The fractures originated in the weld heat-affected zones of inner and outer shrouds. A complete metallurgical analysis was conducted to determine the cause of failure. It was concluded that the diaphragms had failed by fatigue. Analysis suggests that the welds contained high residual stresses and had not been properly stress relieved. Improper welding techniques may have also contributed to the failures. Use of proper welding techniques, including appropriate prewelding and postwelding heat treatments, was recommended.

The clapper in a 250 mm diam disk valve (made from ASTM A36 steel, stress relieved and cadmium plated) fractured at the welded joint between the clapper and a 20 mm diam support rod (also made of same material). The valve contained a stream of gas consisting of 55% H2S, 39% CO2, 5% H2, and 1% hydrocarbons at 40 deg C and 55 kPa during operation. Voids on the fracture surface and evidence of incomplete weld penetration were revealed by examination. Brittle fracture was indicated by the overall appearance through some fatigue beach marks were observed. Very narrow bands of high hardness were revealed at the edges of the weld metal. It was revealed by chemical analysis of this band that a stainless steel filler metal had been used which produced mixed composition at the weld boundaries. The plating material was revealed to be nickel by chemical analysis. It was concluded that clapper failed by fatigue and brittle fracture because it was welded with an incorrect filler metal. A clapper assembly was welded with a low-carbon steel filler metal, then cadmium plated.

Two leaks were discovered at a sulfur recovery unit in a refinery. The leaks were at pipe-to-elbow welds in a 152 mm (6 in.) (NPS 6) diam line, operating in lean amine service at 50 deg C (120 deg F) and 2.9 MPa (425 psig). Thickness measurements indicated negligible loss of metal, and the leaks were clamped. A year later, 15 additional leaks were discovered, again at pipe-to-elbow welds in lean amine lines. Further nondestructive testing located other cracks, giving a total of 35. These lines had been in service for approximately eight years. Investigation (visual inspection, hardness testing, and micrographic cross-sections) supported the conclusion that the failure was caused by lean amine SCC. It was considered unlikely that these pipe welds had received such a postweld heat treatment, although it is industry practice to postweld stress relieve piping and pressure vessels in lean amine service if the temperature is expected to be above 95 deg C (200 deg F). Recommendations included inspecting all welds using shear wave ultrasonic testing and postweld heat treating all welds in lean amine service.

A 10,890-kg coil hook torch cut from 1040 steel plate failed while lifting a load of 13,600 kg after eight years of service. The normal ironing (wear) marks were exhibited by the inner surface of the hook. It was revealed by visual examination that cracking had originated at the inside radius of the hook. Beach marks (typical of fatigue fracture) were found extending over approximately 20% of the fracture surface. Numerous cracks were revealed by macroscopic examination of the torch-cut surfaces. It was revealed by macrograph of an etched specimen that the cracks had initiated in a hardened martensitic zone at the torch-cut surface and had extended up to the coarse pearlite structure beneath the martensitic zone. The fatigue fracture was concluded to have initiated in the brittle martensitic surface while failure was contributed by the 25% overload. As a corrective measure, the coil hooks were flame cut from ASTM A242 fine-grain steel plate, ground to remove the material damaged by flame cutting and stress relieved at 620 deg C.

A few Cr-Mo steel piston rods from different production batches were found identically cracked in the eye end near the radius after chrome plating and baking treatment. Two of them cracked in the plating stage itself instantly broke on slight tapping. Cracking initiated from the outer base surface of the forked eye end. The 40 mm diam forged piston rods were subjected to plating after heavy machining on the part without any stress-relieving treatment. Also, time lapses between plating and baking were varied from 3 to 11 h. The brittle cracking along forked eye-end radius portion was attributed to hydrogen embrittlement that occurred during chrome plating.

A substantial number of copper alloy C27000 (yellow brass, 65Cu-35Zn) ferrules for electrical fuses cracked while in storage and while in service in paper mills and other chemical processing plants. The ferrules, made by three different manufacturers, were of several sizes. One commonly used ferrule was 3.5 cm long by 7.5 cm in diam and was drawn from 0.5 mm (0.020 in.) thick strip. Investigation (visual inspection, metallographic examination, and a mercurous nitrate test, which is an accelerated test used to detect residual stress in copper and copper alloys) of both ferrules from fuses in service and storage in different types of plants, and ferrules from newly manufactured fuses, supported the conclusion that the ferrules failed by SCC resulting from residual stresses induced during forming and the ambient atmospheres in the chemical plants. The atmosphere in the paper mills was the most detrimental, and the higher incidence of cracking of ferrules there was apparently related to a higher concentration of ammonia in conjunction with high humidity. Recommendations included specifying that the fuses meet the requirements of ASTM B 154.

Several type 304L stainless steel dished ends used in the fabrication of cylindrical vessels developed extensive cracking during storage. All of the dished ends had been procured from a single manufacturer and belonged to the same batch. When examined visually, several rust marks were observed, indicating contamination by rusted carbon steel particles. Liquid penetrant testing was used to determine the extent of the cracks, and in situ metallographic analysis was performed over the cracked region. The morphology of the cracks was indicative of transgranular stress-corrosion cracking (TGSCC). Conditions promoting the occurrence of the TGSCC included significant tensile stresses on the inside of the dished ends, the presence of surface contamination by iron due to poor handling practice using carbon steel implements, and storage in a coastal environment with an average temperature of 25 to 32 deg C (77 to 90 deg F), an average humidity ranging from 70 to 80%, and an atmospheric NaCl content ranging from 8 to 45 mg/m2 /day. Recommendations preventing further occurrence of the situation were strict avoidance of the use of carbon steel handling implements, strict avoidance of cleaning practices that cause long-term exposure to chlorine-containing cleaning fluid, and solution annealing of the dished ends at 1050 deg C (1920 deg F) for 1 h followed by water quenching to relieve residual stresses.