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Rusting
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in Analysis of Hot Rolled Steel Transit Damage
> ASM Failure Analysis Case Histories: Improper Maintenance, Repair, and Operating Conditions
Published: 01 June 2019
Fig. 1 Red hills of hematite in Northwest Australia. Rust is iron (steel) reverting to nature. Photograph by David Dare Parker reproduced courtesy of Australian Geographic.
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in Analysis of Hot Rolled Steel Transit Damage
> ASM Failure Analysis Case Histories: Improper Maintenance, Repair, and Operating Conditions
Published: 01 June 2019
Fig. 2 (a) A magnetite coating on hot rolled sheet, with fresh rust breaking through; (b) Hot rolled surface, about 60% covered with fresh rust; (c) Hot rolled steel, with all the original magnetite lost. Rust is beginning to darken where arrowed, to form hematite.
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in Analysis of Hot Rolled Steel Transit Damage
> ASM Failure Analysis Case Histories: Improper Maintenance, Repair, and Operating Conditions
Published: 01 June 2019
Fig. 8 Fallen rust accumulates on surfaces within the stack
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Published: 15 January 2021
Fig. 13 (a) Rust on a carbon steel chain. (b) General corrosion on aluminum
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in Investigation of a Failed Stainless Steel Spindle Assembly
> ASM Failure Analysis Case Histories: Offshore, Shipbuilding, and Marine Equipment
Published: 01 June 2019
Fig. 12 Rust debris on immersion test sample. The wedge is still in place but is out of focus (×3).
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in Corroded Leaky Stainless Steel Pipes
> ASM Failure Analysis Case Histories: Buildings, Bridges, and Infrastructure
Published: 01 June 2019
Fig. 3 Rust patches on interior side of the pipes.
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in Discoloration of a Stainless Steel Kitchen Sink
> ASM Failure Analysis Case Histories: Household Products and Consumer Goods
Published: 01 June 2019
Fig. 1 Localized stain on the kitchen sink, showing the appearance of a red rust spot
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in Transgranular Stress-Corrosion Cracking Failures in AISI 304L Stainless Steel Dished Ends During Storage
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1993
Fig. 6 Rust marks at sites of carbon steel contamination on the inside surface of a dished end
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in Failure of Rockbolts in Underground Mines in Australia
> ASM Failure Analysis Case Histories: Construction, Mining, and Agricultural Equipment
Published: 01 June 2019
Fig. 2 Heavily rusted fracture surface (Bolt 36)
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in Failures of Pressure Vessels and Process Piping
> Analysis and Prevention of Component and Equipment Failures
Published: 30 August 2021
Fig. 83 Screen basket attachment weld showing irregular fillet weld. The rusted area indicates the crack location.
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in Failure Analysis of Heat Exchangers
> Analysis and Prevention of Component and Equipment Failures
Published: 30 August 2021
Fig. 18 Indications of rust behind the epoxy lining. Source: Ref 3
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Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.aero.c0048665
EISBN: 978-1-62708-217-4
.... It was concluded that stress-corrosion cracks grew out from the rust pits. The pin material was changed from 300M steel to PH 13-8 Mo stainless steel, which is highly resistant to rusting and SCC and the jacking control system was modified to prevent overdriving. Landing gear Materials substitution Pitting...
Abstract
The jackscrew drive pins on a landing-gear bogie failed when the other bogie on the same side of the airplane was kneeled for tire change. The pins, made of 300M steel, were shot peened and chromium plated on the outside surface and were cadmium plated and painted with polyurethane on the inside surface. The top of the jackscrew was 6150 steel. Both ends of the pins were revealed to be dented where the jackscrew had pressed into them and were observed to have been resulted due to overdriving the jackscrew at the end of an unkneeling cycle. These dented areas were found to be heavily corroded with chromium plating missing. A heavily corroded intergranular fracture mode was revealed by chromium-carbon replicas of the areas of fracture origin. Deep corrosion pits adjacent to the fracture origins and directly beneath cracks in the chromium plate were revealed by metallographic examination. It was concluded that stress-corrosion cracks grew out from the rust pits. The pin material was changed from 300M steel to PH 13-8 Mo stainless steel, which is highly resistant to rusting and SCC and the jacking control system was modified to prevent overdriving.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001343
EISBN: 978-1-62708-215-0
... examination of the cracked area indicated stress-corrosion cracking, which had originated at rusted areas that had formed on longitudinal scratch marks on the outer surface of the pipe. The material was free from sensitization, and there was no significant amount of cold work. It was recommended...
Abstract
A section of type 304 stainless steel pipe from a stand by system used for emergency injection of cooling water to a nuclear reactor failed during precommissioning. Leaking occurred in only one spot. Liquid penetrant testing revealed a narrow circumferential crack. Metallographic examination of the cracked area indicated stress-corrosion cracking, which had originated at rusted areas that had formed on longitudinal scratch marks on the outer surface of the pipe. The material was free from sensitization, and there was no significant amount of cold work. It was recommended that the stainless steel be kept rust free.
Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001319
EISBN: 978-1-62708-215-0
... Abstract Several type 304L stainless steel dished ends used in the fabrication of cylindrical vessels developed extensive cracking during storage. All of the dished ends had been procured from a single manufacturer and belonged to the same batch. When examined visually, several rust marks were...
Abstract
Several type 304L stainless steel dished ends used in the fabrication of cylindrical vessels developed extensive cracking during storage. All of the dished ends had been procured from a single manufacturer and belonged to the same batch. When examined visually, several rust marks were observed, indicating contamination by rusted carbon steel particles. Liquid penetrant testing was used to determine the extent of the cracks, and in situ metallographic analysis was performed over the cracked region. The morphology of the cracks was indicative of transgranular stress-corrosion cracking (TGSCC). Conditions promoting the occurrence of the TGSCC included significant tensile stresses on the inside of the dished ends, the presence of surface contamination by iron due to poor handling practice using carbon steel implements, and storage in a coastal environment with an average temperature of 25 to 32 deg C (77 to 90 deg F), an average humidity ranging from 70 to 80%, and an atmospheric NaCl content ranging from 8 to 45 mg/m2 /day. Recommendations preventing further occurrence of the situation were strict avoidance of the use of carbon steel handling implements, strict avoidance of cleaning practices that cause long-term exposure to chlorine-containing cleaning fluid, and solution annealing of the dished ends at 1050 deg C (1920 deg F) for 1 h followed by water quenching to relieve residual stresses.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.rail.c0048114
EISBN: 978-1-62708-231-0
... Abstract A locomotive suspension spring with a bar diameter of 36 mm failed. Outdoor exposure of a hot-rolled hardened-and tempered 5160 bars for suspension springs resulted in rusting in the seam and on the fracture surface. A step due to a seam was visible on the surface. The thumb nail...
Abstract
A locomotive suspension spring with a bar diameter of 36 mm failed. Outdoor exposure of a hot-rolled hardened-and tempered 5160 bars for suspension springs resulted in rusting in the seam and on the fracture surface. A step due to a seam was visible on the surface. The thumb nail looked off-center from the step, but a smaller thumb-nail shape that is concentric with the step and a second stage of growth were found to be spread principally to the right of the step. The rapid stage of failure, which began at the edge of the thumb nail, was much rougher and exhibited rays that diverge approximately radially from it. The seam wall was revealed to have two zones among which the lower zone being mottled. Dozens of spearhead shaped areas (fatigue cracks) pointing away from the seam was revealed at the base of the seam. The orientation of these origins was normal to the direction of resultant tensile stress from torsional stressing of the spring material. It was concluded that the fatigue failure in the spring was initiated at the base of a seam.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.bldgs.c9001457
EISBN: 978-1-62708-219-8
... adjacent to the shank. The fractures were of a short nature, with no evidence of progressive cracking by fatigue, nor was there any sign of stretching prior to failure. The fractured faces and the shanks of the studs were of rusted appearance. Microscopic examination of the material showed...
Abstract
The cover of a feed cock fitted to an economic boiler suddenly blew off and the plug lifted sufficiently to permit the escape of water. It was found that all four of the studs securing the cover had fractured. In each case fracture had occurred at the end of one of the screwed portions adjacent to the shank. The fractures were of a short nature, with no evidence of progressive cracking by fatigue, nor was there any sign of stretching prior to failure. The fractured faces and the shanks of the studs were of rusted appearance. Microscopic examination of the material showed it to be an austenitic nickel-chromium stainless steel, stabilized by titanium and of the free machining type. Multiple transgranular cracking characteristic of failure from stress-corrosion cracking, was present to an extensive degree. It was considered probable that there had been slight leakage of water from the valve over a period and evaporation resulted in a solution which favored failure from stress-corrosion cracking. If corrosion resistant studs were desired, those of bronze or Monel metal are to be preferred.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.bldgs.c0048039
EISBN: 978-1-62708-219-8
... of fractures: flat-type fractures were observed in 1.2 and 1 mm diam wires and cup-and-cone fractures were observed in 0.6 mm diam wires. A nick observed in the side of one of the larger wires was found to be rusted. Beach marks radiating inward, indicative of fatigue cracking, were also revealed. The smaller...
Abstract
One of six cables on a passenger elevator was found fractured during a routine inspection. The cable is made of 16-mm steel wire rope designated 8 x 19 G Preformed Extra High Strength Special Traction Elevator Cable with fiber core. Samples of wire from the cable revealed two types of fractures: flat-type fractures were observed in 1.2 and 1 mm diam wires and cup-and-cone fractures were observed in 0.6 mm diam wires. A nick observed in the side of one of the larger wires was found to be rusted. Beach marks radiating inward, indicative of fatigue cracking, were also revealed. The smaller wires were found to be slightly oxidized and behaved in a ductile manner under excessive loads before ultimate failure. Flat-type fractures were believed to have resulted from cyclic torsional stresses along with longitudinal cracking. Restriction of free movement of the socket-end in the shackle was found to have promoted fracture due to increased magnitude of stresses. Mechanical damage to surfaces of wires was concluded to be sufficient to cause fatigue cracking under the stresses encountered in service.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.bldgs.c9001168
EISBN: 978-1-62708-219-8
.... Inspection revealed a reddish-brown coating on the outside of the pipe with a few flat pitting holes and incipient cracks. Corrosion was also observed on the inner walls of the pipe, consisting of rust patches with pitting scars, branching out to predominantly transcrystalline cracks. In this case, leaking...
Abstract
Steel pipes, used for years in a food factory soft water preheater, were found to leak as a result of corrosion. The pipes, made of 18/8 steel, were immersed in steam maintained at 0.5 atm and 150 deg C. They carried desalinated process water, heating it to approximately 100 deg C. Inspection revealed a reddish-brown coating on the outside of the pipe with a few flat pitting holes and incipient cracks. Corrosion was also observed on the inner walls of the pipe, consisting of rust patches with pitting scars, branching out to predominantly transcrystalline cracks. In this case, leaking appears to be the result of a combination of pitting and stress corrosion, most likely due to chlorides. The factory was recommended to use molybdenum-alloyed steels (type 18/10 or 18/12) which are more resistant to local disruption of passivating films and pitting than molybdenum-free types such as 18/8.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.petrol.c9001166
EISBN: 978-1-62708-228-0
... product from each pipe section were analyzed for carbon, sulfur, and iron and were found to consist mainly of iron sulfide mixed with soot and rust. The damage resulted from a high content of hydrogen sulfide in the gas (6% CO2, 20% CO, 8 to 12% H2, 0.5 to 1.5% CH4, remainder N2). To process the coal...
Abstract
After four months at a temperature of 400 to 5000 C, pipes at a gas generating plant were so heavily eroded they had to be replaced. Three sections of pipe, from different locations, were analyzed to determine whether mechanical wear or corrosion caused the damage. Samples of corrosion product from each pipe section were analyzed for carbon, sulfur, and iron and were found to consist mainly of iron sulfide mixed with soot and rust. The damage resulted from a high content of hydrogen sulfide in the gas (6% CO2, 20% CO, 8 to 12% H2, 0.5 to 1.5% CH4, remainder N2). To process the coal in question, the pipes material should be a heat-resistant steel that contains more chromium and has greater resistance to hydrogen sulfide.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c0048147
EISBN: 978-1-62708-234-1
... Abstract The power-type counterbalance spring, formed from hardened-and-tempered carbon steel strip and subsequently subjected to phosphating treatment, fractured at the two locations during fatigue testing. A rust colored dark band at the inside edge of the fracture surface was disclosed...
Abstract
The power-type counterbalance spring, formed from hardened-and-tempered carbon steel strip and subsequently subjected to phosphating treatment, fractured at the two locations during fatigue testing. A rust colored dark band at the inside edge of the fracture surface was disclosed during investigation. Etch pits were revealed by the cleaned surface which were never observed on properly phosphated coating. It was interpreted that the spring had been subjected to an abnormal acid attack in pickling or phosphating which had resulted in considerable absorption of hydrogen by the metal and hence embrittlement. The part was concluded to have cracked during phosphating or excessive acid pickling before phosphating.
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