Work rolls made of indefinite chill double-poured (ICDP) iron are commonly used in the finishing trains of hot-strip mills (HSMs). In actual service, spalling, apart from other surface degeneration modes, constitutes a major mechanism of premature roll failures. Although spalling can be a culmination of roll material quality and/or mill abuse, the microstructure of a broken roll can often unveil intrinsic inadequacies in roll material quality that possibly accentuate failure. This is particularly relevant in circumstances when rolls, despite operation under similar mill environment, exhibit variations in roll life. The paper provides an insight into the microstructural characteristics of spalled ICED HSM work rolls, which underwent failure under similar mill operating environment in an integrated steel plant under the Steel Authority of India Limited. Microstructural features influencing ICDP roll quality, viz. characteristics of graphite, carbides, martensite, etc., have been extensively studied through optical microscopy, quantitative image analysis (QIA), and electron-probe microanalysis (EPMA). These are discussed in the context of spalling propensity and roll life.

Although a precise understanding of roll failure genesis is complex, the microstructure of a broken roll can often unravel intrinsic deficiencies in material quality responsible for its failure. This is especially relevant in circumstances when, even under a similar mill-operating environment, the failure involves a particular roll or a specific batch of rolls. This paper provides a microstructural insight into the cause of premature breakage of a second-intermediate Sendzimir mill drive roll used at a stainless steel sheet rolling plant under the Steel Authority of India Limited. Microstructural issues influencing roll quality, such as characteristics of carbides, tempered martensite, retained austenite, etc., have been extensively studied through optical and scanning electron microscopy, electron-probe microanalysis, image analysis, and x-ray diffractometry. These are discussed to elucidate specific microstructural inadequacies that accentuated the failure. The study reveals that even through retained austenite content is low (6.29 vol%) and martensite is non-acicular, the roll breakage is a consequence of intergranular cracking caused by improper carbide morphology and distribution.

An extensive metallurgical investigation was carried out on samples of a failed roller bearing from the support and tilting system of a basic oxygen furnace converter used in the steel melting shop of an integrated steel plant. The converter bearing was fabricated from low-carbon, carburizing grade steel and had failed in service within a year of fitting to a repaired shaft. Microscopic observations of both the broken roller and inner-race samples revealed subsurface cracking and preponderance of brittle oxide and other macroinclusions. Electron probe microanalysis studies confirmed that the brittle oxides that formed stringers were alumina, and the other macroinclusions were complex silicates. Both the alumina and silicate inclusions were deleterious to contact-fatigue properties. Microstructurally, the carburized regions of the broken roller and of inner-race samples contained high-carbon tempered martensite. Microhardness measurements revealed that. Although the core hardness of the roller and the inner-race samples were similar, the surface hardness of the roller was approximately 8.5 HRC units harder than that of the inner-race. SEM observations of the roller fracture surface revealed striations indicative of fatigue, and EDS analyses corroborated a high incidence of silicate inclusions at crack sites. The study suggests that the failure of the bearing occurred because the hardness difference between the roller bearing and the inner-race surfaces resulted in wear of the inner-race. The wear led to shaft misalignment and play during service. The misalignment, coupled with the presence of inclusions, caused fatigue failure of the roller bearing.

Locked coil wire ropes, by virtue of their unique design and construction, have specialized applications in aerial ropeways, mine hoist installations, suspension bridge cables, and so forth. In such specialty ropes, the outer layer is constructed of Z-profile wires that provide not only effective interlocking but also a continuous working surface for withstanding in-service wear. The compact construction and fill-factor of locked coil wire ropes make them relatively impervious to the ingress of moisture and render them less vulnerable to corrosion. However, such ropes are comparatively more rigid than conventional wire ropes with fiber cores and therefore are more susceptible to the adverse effects of bending stresses. The reasons for premature in-service wire rope failures are rather complex but frequently may be attributed to inappropriate wire quality and/or abusive operating environment. In either case, a systematic investigation to diagnose precisely the genesis of failure is desirable. This article provides a microstructural insight into the causes of wire breakages on the outer layer of a 40 mm diam locked coil wire rope during service. The study reveals that the breakages of Z-profile wires on the outer rope layer were abrasion induced and accentuated by arrays of fine transverse cracks that developed on a surface martensite layer.

The genesis of failure of 6.1 mm thick electric resistance welded API 5L X-46 pipes during pretesting at a pressure equivalent to 90% of specified minimum yield strength was investigated. Cracks were found to initiate on the outer surface of the pipes in the fusion zone and propagate along the through-thickness direction. The presence of extensive decarburization and formation of a soft ferrite band within the fusion zone may have contributed to the nucleation of the cracks. Crack propagation was aided by the presence of exogenous inclusions entrapped within the fusion zone. Analysis of these inclusions confirmed the presence of Fe, Si, Ca, and O, indicating slag entrapment to be the most probable culprit.

A failure analysis was conducted in late 1996 on two rolls that had been used in the production of iron and steel powder. The rolls had elongated over their length such that the roll trunnions had impacted with the furnace wall refractory. The result was distortion and bowing of the roll bodies which necessitated their removal from service. The initial analysis found large quantities of nitrogen had been absorbed by the roll shell. Further research indicated nitrogen pickup accounted for 3% volumetric growth for every 1% by weight nitrogen absorption. This expansion was sufficient to account for the dimensional change observed in the failed rolls. This paper details the failure analysis and resulting research it inspired. It also provides recommendations for cast material choice in highly nitriding atmospheres.

An automatic press for making burlap bags had been used for several years. The press failed after being shipped by truck for a distance of about 400 mi. The objective was to determine whether failure occurred during or before shipment. The large piece which broke off the press included a section of the ways and a heavy adjustable mechanism which normally rides on these ways. The weight of the broken section was estimated at several hundred pounds. There was no support for the broken piece beyond the point of breakage. The material was a commercial cast iron, and the largest proportion of the fracture area was fresh and bright. It was concluded that this was a fresh fracture which occurred during shipment, and the crack itself was not present prior to shipment. The fact that a material defect of some sort was present and probably determined the location of the crack was apparently not significant as far as its usage was concerned. The failure could have been avoided by providing support underneath the overhanging member.

On 14 April 1912, at 11:40 p.m., Greenland Time, the Royal Mail Ship Titanic on its maiden voyage was proceeding westward at 21.5 knots (40 km/h) when the lookouts on the foremast sighted a massive iceberg estimated to have weighed between 150,000 to 300,000 tons at a distance of 500 m ahead. Immediately, the ship’s engines were reversed and the ship was turned to port (left) in an attempt to avoid the iceberg. In about 40 sec, the ship struck the iceberg below the waterline on its starboard (right) side near the bow. The iceberg raked the hull of the ship for 100 m, destroying the integrity of the six forward watertight compartments. Within 2 h 40 min the RMS Titanic sank. Metallurgical examination and chemical analysis of the steel taken from the Titanic revealed important clues that allow an understanding of the severity of the damage inflicted on the hull. Although the steel was probably as good as was available at the time the ship was constructed, it was very inferior when compared with modern steel. The notch toughness showed a very low value (4 J) for the steel at the water temperature (-2 deg C) in the North Atlantic at the time of the accident.

The Pandia digester is a long cylindrical vessel which uses alkaline sulfite liquor to cook sawdust for pulping. The inlet cone was fabricated from AISI 304L stainless steel with E308 welds. Typical liquor concentration was approximately 80% NaOH, 20% Na2SO3 with chloride concentrations at 2 grams per liter. The operating pressures in the inlet cone were up to 1.2 MN/sq m (170 psig). The inlet cone had developed leaks within a year of service. Liquid penetrant inspection showed significant through-wall cracking near the fillet welds joining the bottom flange and side wall and the butt welds. Metallographic specimens were prepared from the welds to examine the microstructure and nature of the cracks. The cooking liquor at the inlet cone contained over ppm chlorides and was aggressive to 304 stainless steel. The cracking was identified as chloride-induced SCC. The inlet cone was replaced with an Inconel clad carbon steel inlet cone to combat the SCC.

A welded elbow assembly (AISI type 321 stainless steel, with components joined with ER347 stainless steel filler metal by gas tungsten arc welding) was part of a hydraulic-pump pressure line for a jet aircraft. The other end of the tube was attached to a flexible metal hose, which provided no support and offered no resistance to vibration. The line was leaking hydraulic fluid at the nut end of the elbow. Investigation supported the conclusion that failure was by fatigue cracking initiated from a notch at the root of the weld and was propagated by cyclic loading of the tubing as the result of vibration and inadequate support of the hose assembly. Recommendations included changing the joint design from a cylindrical lap joint to a square-groove butt joint. Also, an additional support was recommended for the hose assembly to minimize vibration at the elbow.

An LNG tanker experienced a fracture of the solid tail shaft, which is a section of the main drive shaft. The tail shaft was made of a forged low-carbon steel. In spite of two ultrasonic inspections, a large defect the size of a football in the center of the shaft was missed. During heat treating following forging, it was surmised that the defect led to the propagation of an internal brittle crack, or clink. A fatigue crack propagated from this origin to the outer surface of the shaft after about a year of service. Finally a last ligament of a few square inches held the shaft together and broke, leading to the separation of the shaft. The cause of failure was fatigue crack initiation and crack growth under reverse bending cyclic stresses. There was no indication that misalignment existed because there was no indication of fretting at the bolt holes in the flange at the end of the shaft. In the case of this shaft, a solution would have been to machine the core of the shaft to remove the brittle material or to use a tubular shaft.

This article focuses on the general root causes of failure attributed to the casting process, casting material, and design with examples. The casting processes discussed include gravity die casting, pressure die casting, semisolid casting, squeeze casting, and centrifugal casting. Cast iron, gray cast iron, malleable irons, ductile iron, low-alloy steel castings, austenitic steels, corrosion-resistant castings, and cast aluminum alloys are the materials discussed. The article describes the general types of discontinuities or imperfections for traditional casting with sand molds. It presents the international classification of common casting defects in a tabular form.

This article addresses the forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. It describes the mechanisms of corrosive attack for specific forms of corrosion such as galvanic corrosion, uniform corrosion, pitting and crevice corrosion, intergranular corrosion, and velocity-affected corrosion. The article contains a table that lists combinations of alloys and environments subjected to selective leaching and the elements removed by leaching.

A hot rolled, low-carbon steel pot used to melt magnesium alloys leaked, releasing about 35 kg (80 lb) of molten magnesium onto the foundry floor and causing an extensive fire. Due to the fire, the original leakage hole could not be investigated. Samples of the failed pot were polished and etched and were found to be composed of ferrite and pearlite mixtures, as would be expected. However, the sample taken from a location about 75 mm (3 in.) from the hole contained a cluster of unusually large inclusions. By removing the beryllium window from in front of the detector, EPMA spectra were obtained from the inclusions and from the steel matrix. The inclusion spectrum contained primarily iron and oxygen, whereas the matrix spectrum contained primarily iron. X-ray maps were made to show the distribution of iron and oxygen. These results indicated that the inclusions were iron oxide. A similar inclusion at the failure site in the melting pot may have reacted violently with the molten magnesium, causing the leak.

Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.

Nickel anodes failed in several electrolysis cells in a heavy-water upgrading plant. Dismantling of a cell revealed gouging and the presence of loosely attached black porous masses on the anode. The carbon steel top, plate was severely corroded. An appreciable quantity of black powder was also present on the bottom or the cell. SEM/EDX studies of the outer and inner surfaces of the gouged anode showed the presence of iron globules at the interface between the gouged and the unattacked anode. The chemical composition of the black powder was determined to be primarily iron. Cell malfunction was attributed to the accelerated dissolution of the carbon steel anode top, dislodgment of grains from the material, and subsequent closing of the small annular space between the anode and the cathode by debris from the anode top. Cladding of the carbon steel top with a corrosion-resistant material, such as nickel, nickel-base alloy, or stainless steel, was recommended.

Carbon steel tubes from a boiler feedwater heater feeding a deaerator were treated to control scale formation, but the treatment instead produced more iron oxide. The additional iron oxide reduced the tubing to a totally corroded condition. Investigation showed that the chelate injected to control the scaling was added ahead of the preheater, where the boiler water still contained oxygen. As the chelate removed iron oxide, the O2 in the water continued to form more. Recommendations included moving the chelate addition to a point after the deaerator to stop the corrosion.

The drive shaft on a centrifugal pump fractured after five months of operation. The fracture occurred at a packing gland inside a sleeve against which the packing material sealed. The shaft and sleeve were of duplex stainless steel. In contrast to a previous conclusion that heating had caused property deterioration resulting in embrittlement and fracture, it was concluded that the shaft must have fractured (most probably by fatigue cracking originating at the change of section) and that heating had then taken place from friction between the rotating input shaft and the remaining part attached to the pump. High temperature was thus a result, not the cause, of the failure.

The surface of a hook did not possess the smooth and shiny zinc bloom surface normally observed on hot galvanized steel parts but was matte and rough. Large cracks were observed in the zinc layer. The hook was made of silicon-killed alloy steel 41Cr4. A silicon content of 0.27% was established analytically. Silicon accelerates the reaction between iron and zinc, which should have been taken into account in the present case by reducing the dip time or a small addition of aluminum (0.1 to 0.2%) to the galvanizing bath to retard the extremely rapid growth of the zinc layer and the strong alloy formation. Even in the case of steel parts with lower silicon contents the reaction between iron and zinc can continue until the pure zinc layer has been consumed entirely if the work piece is not cooled sufficiently after withdrawal.