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Gibbs free energy

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Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006940
EISBN: 978-1-62708-395-9
... loading limits, and loading waveform. These features appear to produce failure characteristics not otherwise encountered. Additionally, due to the viscoelastic or time-dependent nature of the polymers, significant energy dissipation occurs under pure fatigue or combined creep-fatigue loading conditions...
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006923
EISBN: 978-1-62708-395-9
... is increased. It is said that the free volume, which may be thought of as room inside the polymer, gradually increases until coordinated segmental motion of 10 to 50 mer units is possible. At this point the polymer can deform in response to an applied stress, for example, much more easily than it could...