Coiled tubing used in drilling operations failed at the halfway point of its estimated fatigue life. The failure was found to be transverse to the tubing axis. Visual examination revealed a flat fracture surface extending 13 mm with the rest of the fracture showing shear lips indicative of tensile overload. The flat portion of the fracture surface was typical of fatigue cracking. Fatigue striations were revealed by SEM. Corrosion pitting on the tubing ID from which the fatigue crack had propagated were observed on closer examination. The corrosion pitting was speculated to have occurred when the tubing was idle and fluids accumulated at the bottom of the tubing wraps. The coiled tubing was concluded to have failed prematurely due to low-cycle fatigue initiated at corrosion pitting sites. Corrosive attack on the coiled tubing was recommended to be reduced by completely removing fluids or modifying the fluids in the tubing or purging by flowing dry nitrogen to dry it out.

Coiled tubing with 80 ksi yield strength manufactured to a maximum hardness of 22 HRC to meet NACE Standard MR0175 requirement for sour gas service failed after being on 38 jobs (70% of its estimated fatigue life). A transverse crack where a leak occurred was identified as the primary failure point. Numerous OD surface fissures were revealed by a low-power microscope. A brittle zone near the OD, identified as a sulfide stress crack with additional fatigue cracking was revealed by SEM. Sulfide stress cracking defined as brittle failure by cracking under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide was concluded to have initiated the failure which was propagated by fatigue. It was recommended that in the presence of known corrosive environments the tubing should not be used above 50% of its theoretical fatigue life.

An interstage radiator gas coil began leaking after only 45 days of service. The original brass coil with several aluminum fins was replaced three times but each replacement lasted less than a day. After removing the fins, leaks were found at circumferential cracks. A section of a tube was removed and split, revealing a series of cracks, evenly spaced. Crack spacing coincided with fin spacing, indicating that stresses incurred during installation of the fins promoted failure. Metallographic examination showed intergranular, branched cracking, characteristic of stress corrosion failures, with the cracks starting on the inside surfaces of the tubes. There was no known corrosive agent in the system, and no other corrosion damage could be found. Qualitative tests and spectrographic analysis gave a positive indication for mercury. The spacing of the cracks, the branched intergranular cracking, the rapid failure, and presence of mercury led to the conclusion of stress-corrosion cracking. It was impossible to remove mercury from the system so carbon steel coils were substituted for the brass ones. The carbon steel coils gave failure-free service for over nine years.

After some 87,000 h of operation, failure took place in the bend of a steam pipe connecting a coil of the third superheater of a steam generator to the outlet steam collector. The unit operated at 538 deg C and 135 kPa, producing 400 t/h of steam. The 2.25Cr-1Mo steel pipe in which failure took place was 50.8 mm in diam with a nominal wall thickness of 8 mm. It connected to the AISI 321 superheater tube by means of a butt weld and was one of 46 such parallel connecting tubes. The Cr-Mo tubing was situated outside the heat transfer zone of the superheater. The overall sequence of failure involved overheating of the Cr-Mo outlet tubes, heavy oxidation, oxide cracking on thermal cycling, thermal fatigue cracking plus oxidation, creep-controlled crack growth, and rapid plastic deformation and rupture. This failure was indicative of excess temperature of the steam coming from the heat transfer zone of the coil. It showed that many damage mechanisms may combine in the transition from fracture initiation to final failure. The presence of grain boundary sliding as an indication of creep damage was useful in the characterization of the stress level as high and showed that the process of creep was not operative throughout the life of the equipment.

A root cause failure analysis was performed on a vaporizer coil removed from a horizontal forced circulation vaporizer. The carbon steel coil was wound in a right-hand helix with a coil centerline diameter of about 2 m. The vaporizer was gas fired and used Dowtherm A as the heat transfer fluid. Design conditions are based on annular fluid flow to cool the coil wall. NDE, metallographic and fractographic examinations were performed. Numerous, circumferentially oriented, OD initiating cracks were found near the crown for two coils near the non-fired end of the vaporizer. The cracking was confined to the inner diameter of the vaporizer coil at positions from 4:00 to 7:00. The cracking was characterized as transgranular and the fracture surface had beach marks. The failure mechanism was thermal fatigue. The heat transfer calculation predicted that dryout of the coil would occur for coils at the non-fired end of the vaporizer during low flow transients. Dryout results in rapid increase in the tube wall temperature. Thermal cycling of the coil is completed by liquid quenching resulting from resumption of normal flow rates and the return to annular flow. The probable root cause of failure was low flow transient operation.

A solution containing 50 to 70% calcium chloride (pH 7.5 to 8.5) was concentrated by evaporation in a brick-lined vessel by passing steam at a pressure of 15 atmospheres through a system of heating coils made of austenitic stainless steel X 10 Cr-Ni-Mo-Ti 18 12 (Material No. 1.4573). After five months one of the coils, which consisted of tubes having a wall thickness of 3.4 mm, developed a leak. Tightly closed cracks were seen on the outer surface of the tube. Further tests with color penetration process revealed multiple branched cracks. Longitudinal section showed that the cracks had started from the outside surface of the tube. Electrolytic etching further showed that they had propagated mainly across the grains. It was concluded that this was a typical case of transcrystalline stress corrosion.

A gas-fired, ASTM A-106 Grade B carbon steel vaporizer failed on three different occasions during attempts to bring the vaporizer on line. Dye penetrant examination indicated the presence of multiple packets of ductile cracks on the inside of the coil radius at the bottom of the horizontal axis coils. Visual examination of the inside of the tubing indicated the presence of a carbonaceous deposit resulting from decomposition of the heat-exchanging fluid. Subsequent metallographic examination and microhardness testing indicated that the steel was heated to a temperature above the allowable operating temperature for the fluid. The probable cause for failure is thermal fatigue due to the localized overheating. Flow conditions inside the tubing should be reexamined to ensure suitable conditions for annular fluid flow.

The working fluid of a hypersonic wind tunnel is freon 14 heated in molten-metal-bath heat exchangers. The coils of the heaters have failed several times from various causes. They have been replaced each time with a stainless steel deemed more appropriate, but they continue to fail. In this case study, the history of failures is traced, the causes are analyzed, and recommendations are made for future design and maintenance. Coils fabricated from AISI 316 should provide satisfactory service life if reasonable precautionary measures are observed during maintenance and testing.

A process vessel heating coil, consisting of several 3 ft diam turns, was supplied with steam at 400 psi and a temperature of 343 deg C (650 deg F). At bi-weekly intervals well water was introduced to effect rapid cooling of the contents. After about eight months, leakage developed from a circumferential crack on the underside of the uppermost turn. Shorter cracks were found at a similar location on the bottom turn, and further leakage occurred at pinhole perforations adjacent to the crack in the top turn and near to a butt-weld in the coil. Microscopic examination revealed that the cracks were predominantly of the intergranular variety. In addition, transgranular cracks were present. Material was an austenitic stainless steel of the type specified but the absence of columbium and titanium in significant amounts showed that it was not stabilized against intergranular carbide precipitation. The transgranular cracks indicated that failure was due partly to stress-corrosion. It was concluded that the chlorides provided the main corrodent for both the stress and intercrystalline-corrosion cracking.

The metallurgical condition of a cylindrical induction melter (CIM) vessel was evaluated after approximately 375 h of operation over a two-year span at temperatures between 1400 to 1500 deg C. Wall thinning and significant grain growth was observed in the lower portion of the conical section and the drain tube. No through-wall penetrations were found in the cylindrical and conical sections of the CIM vessel and only one leak site was identified in the drain tube. Failure of the drain tube was associated with localized overheating and creep. The observed degradation resulted from cumulative service at elevated temperature. A recommendation was made to implement a support for the conical section of the CIM and to increase the wall thickness of the drain tube. Thus, the possibility of drain tube misalignment in the induction coils and localized over heating will be minimized. In addition, the use of grain stabilized Pt/Rh alloy should be evaluated as a method to prevent grain growth.

Alloy UNS N08800 (Alloy 800) tubes of the steam superheating coils of two hydrocracker charge heaters in a refinery failed prematurely in service. Failure analysis of the tubes indicated that the failures could be attributed to thermal fatigue as a result of temperature fluctuations as well as restriction to movement. Fatigue cracks initiated intergranularly from both the flue gas and steam sides. Enhanced general and grain boundary oxidation coupled with age hardening of the alloy led to the formation of incipient intergranular cracks that acted as sites for the initiation of the fatigue cracks.

The self-powered flux detectors used in some nuclear reactors are Pt or V-cored co-axial cables with MgO as an insulator and Inconel 600 as the outer sheath material. The detectors are designed to operate in a He atmosphere; to maximize the conduction of heat (generated from the interaction with gamma radiation) and to prevent corrosion. A number of failures have occurred over the years because of a loss of the He cover gas in the assembly. This has resulted in either acid attack on the Inconel 600 sheath in a wet environment or gaseous corrosion in a dry environment. In the latter case, nitriding and embrittlement occurred at temperatures as low as 300 to 400 deg C (determined from an examination of the oxidation of the Zircaloy-2 carrier rod on which the detectors were mounted). Recent results are described and discussed in terms of the oxidation and nitriding kinetics of Zircaloy-2 and Inconel 600, respectively.

To samples of helical compression springs were returned to the manufacturer after failing in service well short of the component design life. Spring design specifications required conformance to SAE J157, “Oil Tempered Chromium Silicon Alloy Steel Wire and Springs.” Each spring was installed in a separate heavy truck engine in an application in which spring failure can cause total engine destruction. The springs were composed of chromium-silicon steel, with a hardness ranging from 50 to 54 HRC. Chemical composition and hardness were substantially within specification. Failure initiated from the spring inside coil surface. Examination of the fracture surface using scanning electron microscopy showed no evidence of fatigue. Final fracture occurred in torsion. X-ray diffraction analysis revealed high inner-diameter residual stresses, indicating inadequate stress relief from spring winding. It was concluded that failure initiation was caused by residual stress-driven stress-corrosion cracking, and it was recommended that the vendor provide more effective stress relief.

An SB407 alloy 800H tube failed at a 100 deg bend shortly after startup of a new steam superheater. Three bends failed and one bend remote from the failure area was examined. Visual examination showed that the fracture started on the outside surface along the inside radius of the bend and propagated in a brittle, intergranular fashion. Chemical analysis revealed that lead contamination was a significant factor in the failure and phosphorus may have contributed. The localized nature of the cracks and minimum secondary cracking suggested a distinct, synergistic effect of applied tensile stress with the contamination. Stress analysis found that stress alone was not enough to cause failure; however the operating stresses in the 100 deg bends were higher than at most other locations in the superheater Reduced creep ductility may be another possible cause of failure. Remedial actions included reducing the tube temperature, replacing the Schedule 40 100 deg bends with Schedule 80 pipe, and solution annealing the pipe after bending.

A shopping mall in South Carolina was originally constructed in 1988 and a second phase completed in 1989. The HVAC system inside the mall included an open, recirculating condenser water loop that served various fan coil units located within tenant spaces. The system had a recirculating capacity of about 44,000 gal (166,000 L) of water. It consisted primarily of steel pipes fitted with threaded connectors on the 2 in. (46 cm) pipes and bolted flanged couplings on the larger pipes. Seven years following the completion of the mall, corrosion problems were noted at the outer and inner surfaces of the pipe. Visual observations on the inner diametral surfaces revealed that the pipes were, in almost all cases, filled with corrosion products. A significant amount of base metal loss was documented in all of the samples. The cause of the observed corrosion was determined to be a lack of corrosion monitoring and poor water quality. Pipe replacement and a regular water testing program were recommended.

Radiant tubes that failed prematurely in an ethylene cracking furnace were analyzed to determine the cause of their early demise. The tubes were made from austenitic heat-resistant steel and cracked along their longitudinal axis. New and used tubes were compared using scanning electron microscopy, energy dispersive x-ray spectrometry, and mechanical property testing. This provided critical information and revealed that improper coking and decoking had removed the protective oxide layer (Cr 2 O 3 ) that normally prevents coke deposits from forming on exposed surfaces. Without this layer, coke readily accumulates on the surface of the tubes, fueling carbon diffusion into the metal and a corresponding degradation in microstructure and loss of ductility at high temperatures.

An investigation was conducted to determine why 16 out of 139 pipe bends cracked during hot induction bending. The pipe conformed to API 5L X65 PSL2 line pipe standards and measured 1016 mm (40 in.) in diam with a wall thickness of 18.5 mm. A metallurgical cross section was removed along a crack on the extrados to document the crack morphology using optical microscopy. In addition to cracking, golden-yellow streaks were visible at the extrados, and the composition was examined using scanning electron microscopy with energy dispersive spectroscopy. Based on the results, investigators concluded the pipe was contaminated with copper at the mill were it was produced.

Nondestructive testing (NDT), also known as nondestructive evaluation (NDE), includes various techniques to characterize materials without damage. This article focuses on the typical NDE techniques that may be considered when conducting a failure investigation. The article begins with discussion about the concept of the probability of detection (POD), on which the statistical reliability of crack detection is based. The coverage includes the various methods of surface inspection, including visual-examination tools, scanning technology in dimensional metrology, and the common methods of detecting surface discontinuities by magnetic-particle inspection, liquid penetrant inspection, and eddy-current testing. The major NDE methods for internal (volumetric) inspection in failure analysis also are described.

An investigation of a Stirling engine after an aborted test run revealed that the regenerator screens had suffered substantial damage. During the run, the individual screens oscillated as the helium working fluid was shuttled through the regenerator. In localized areas, the 41 mu m (1600 mu in.) diam type 304 stainless steel wire screening had been torn and pieces were missing. Scanning electron microscope revealed that the fracture had occurred at wire crossover locations by a fatigue mechanism. The problem was solved by sintering the individual screens into a single unit.