Search Results for Carbon

A carbon steel (ASTM A515 grade 70) pressure vessel failed by brittle fracture while being hydro tested in the fabricating shop. The fracture origin was a small crack at a welding arc strike associated with the toe of a nozzle weld. A fracture mechanics calculation indicated that this imperfection, although small, initiated fracture because of the local geometry and stress conditions and the low toughness of the steel. It was recommended that (1) the probability of flaws be reduced by welding over or grinding out arc strikes, (2) the local stresses be lowered by post weld stress relief and improved weld toe geometry, and (3) toughness be improved by specifying fine-grain steel and/ or by normalizing.

Schedule 80 low-carbon steel pipes used to transfer kraft liquor in a Kamyr continuous pulp digester failed within 18 months after installation. Visual and metallographic examinations established that the cracking initiated on the internal surfaces of the equalizer pipes in the welds and heat-affected zones (HAZs). Fracture/crack morphology was brittle and primarily intergranular and deposits at crack tips were primarily iron oxides with significant amounts of sodium compounds. On these bases, the cracking was characterized as intergranular stress-corrosion cracking (IGSCC). Corrosion-related deterioration was not found, indicating that the material was generally suitable for the intended service. High residual tensile stresses in the welds and HAZS, resulting from field welding under highly constrained conditions using inadequate weld procedures, were the most probable cause of the failures. Minimizing residual stresses through use of welding procedures that include appropriate preweld and interpass temperatures and postweld stress relief heat treatment at 650 deg C (1200 deg F) was recommended to prevent further failures.

Replacement sprockets installed on chain drive shafts for winding fibers exhibited excessive wear. Metallographic and chemical analyses conducted on the original and replacement sprockets showed that the material of the replacement sprocket was 1020 low-carbon steel, whereas the original (and specified) material was medium-carbon 1045 steel. The low-carbon steel also had lower hardness because of a lower pearlite fraction in the microstructure. It was recommended that replacement sprockets be made of normalized 1045 steel. It was further suggested that wear resistance could be improved by through hardening or induction surface hardening of the teeth.

A roadarm for a tracked vehicle failed during preproduction vehicle testing. The arm was a weldment of two cored low-alloy steel sand castings specified to ASTM A 148, grade 120–95. A maximum carbon content of 0.32% was specified. The welding procedure called for degreasing and gas metal arc welding; neither preheating nor postheating was specified. The filler metal was E70S-6 continuous consumable wire with a copper coating to protect it from atmospheric oxidation while on the reel. Analysis of the two castings revealed that the carbon content was higher than specified, ranging from 0.40 to 0.44%. The fracture occurred in the HAZ , where quenching by the surrounding metal had produced a hardness of 55 HRC. Some roadarms of similar carbon content and welded by the same procedure had not failed because they had been tempered during a hot-straightening operation. Brittle fracture of the roadarm was caused by a combination of too high a carbon equivalent in the castings and the lack of preheating and postheating during the welding procedure. A pre-heat and tempering after welding were added to the welding procedure.

Two superheater tubes from a 6.2 MPa (900 psig) boiler failed in service because of creep rupture. One tube was carbon steel and the other was carbon steel welded to ASTM A213 Grade T22 (2.25Cr-1.0Mo) tubing. The failure in the welded tube occurred in the carbon steel section. Portions of the superheater were retubed five years previously with Grade 722 material. The failures indicated that tubes were exposed to long-term overheating conditions. While the carbon steel tube did not experience temperatures above the lower transformation temperature 727 deg C (1340 deg F), the welded tube did experience a temperature peak in excess of 727 deg C (1340 deg F). The long-term overheating conditions could have been the result of excessive heat flux and /or inadequate steam flow. In addition, the entire superheater bank should have been upgraded to Grade 722 material at the time of retubing.

Two identical “D” tube package boilers, installed at separate plants, experienced a number of tube ruptures after relatively short operating times. The tubes, which are joined by membranes, experienced localized bulging and circumferential cracking along the fireside crown as a result of overheating and thermal fatigue. It was recommended that recent alterations to the steam-drum baffling be remodified to improve circulation in the boiler and prevent further overheating. Several thermocouples were attached to tubes in problem areas of the boiler to monitor the effects of the steam-drum modifications on tube wall temperatures.

A recurring piston shaft failure problem on the billet-loading tray of an extrusion press was investigated. Two shafts fractured within a period of 10 days. The shaft was machined from normalized EN3 (AISI C1022) steel stock without further treatment. Visual, microstructural, chemical, and mechanical (hardness and tensile properties) analyses of failed shaft specimens were conducted. The examinations showed that the shafts had failed by fatigue. It was recommended that a low-alloy steel (e.g., 3% Ni-Cr) in the hardened and tempered condition and subjected to shot-peening surface-hardening treatment be used. The provision of a stop to reduce bending stresses was also recommended.

Two leaks were discovered at a sulfur recovery unit in a refinery. The leaks were at pipe-to-elbow welds in a 152 mm (6 in.) (NPS 6) diam line, operating in lean amine service at 50 deg C (120 deg F) and 2.9 MPa (425 psig). Thickness measurements indicated negligible loss of metal, and the leaks were clamped. A year later, 15 additional leaks were discovered, again at pipe-to-elbow welds in lean amine lines. Further nondestructive testing located other cracks, giving a total of 35. These lines had been in service for approximately eight years. Investigation (visual inspection, hardness testing, and micrographic cross-sections) supported the conclusion that the failure was caused by lean amine SCC. It was considered unlikely that these pipe welds had received such a postweld heat treatment, although it is industry practice to postweld stress relieve piping and pressure vessels in lean amine service if the temperature is expected to be above 95 deg C (200 deg F). Recommendations included inspecting all welds using shear wave ultrasonic testing and postweld heat treating all welds in lean amine service.

The welds joining the liner and shell of a fluid catalytic cracking unit failed. The shell was made of ASTM A515 carbon steel welded with E7018 filler metal. The liner was made of type 405 stainless steel and was plug welded to the shell using ER309 and ER310 stainless steel filler metal. Fine cracks starting inside the weld zone and spreading outward through the weld and toward the surface were observed during examination. Decarburization and graphitization of the carbon steel at the interface was noted. The high carbon level was found to allow martensite to form eventually. The structure was found to be austenitic in the area where the grain-boundary precipitates appeared heaviest. The composition of the precipitates was analyzed using an electron microprobe to reveal presence of sulfur. Microstructural changes in the weld alloy at the interface were interpreted to be caused by dilution of the alloy and the presence of sulfur caused hot shortness. The necessary internal stress to produce extensive cracking was produced by the differential thermal expansion of the carbon and stainless steels. Periodic careful gouging of the affected areas followed by repair welding was recommended.

A large pressure vessel that had been in service as a hydrogen sulfide (H2S) absorber developed cracks and began leaking at a nozzle. The vessel contained a 20% aqueous solution of potassium hydroxide (KOH), potassium carbonate (K2CO3), and arsenic. The vessel wall was manufactured of ASTM A516, grade 70, low-carbon steel plate. A steel angle had been formed into a ring was continuously welded to the inside wall of the vessel. The groove formed by the junction of the lower tray-support weld and the top part of the weld around the nozzle was found to have a crack. Pits and scale near the crack origin were revealed by microscopic examination and cracking was found to be transgranular. Periods of corrosion alternated with sudden instances of cleavage, under a tensile load, along preferred slip planes were interpreted during examination with a microscope. It was concluded that the combination of the residual plus operating stresses and the amount of KOH present would have caused stress corrosion as a result of caustic embrittlement. It was recommended that the tray support should be installed higher on the vessel wall to prevent coincidence of the lower tray-support weld with the nozzle weld.

Tubes in a marine boiler on a new ship failed after brief service lives. Circumferential brittle cracking was found to occur in the carbon-molybdenum steel tubes near the points where the tubes were attached to the steam drum. Fatigue striations were revealed by examination of fracture surfaces by electron microscopy at high magnification. Fatigue failures were concluded to be caused by vibrations resulting from normal steam flow at high steam demand. Too rigid support near the steam drum resulted in concentration of vibratory strain in the regions of failure. The method of supporting the tubes was changed to reduce the amount of restraint and the strain concentration.

A steel galvanizing vat measuring 3 x 1.2 x 1.2 m (10 x 4 x 4 ft) and made of 19 mm thick carbon steel plate (ASTM A285, grade B)) at a shipbuilding and ship-repair facility failed after only three months of service. To verify suspected failure cause, two T joints were made in 12.5 mm thick ASTM A285, grade B, steel plate. One joint was welded using the semiautomatic submerged arc process with one pass on each side. A second joint was welded manually by the shielded metal arc process using E6010 welding rod and four passes on each side. The silicon content of the shielded metal arc weld was 0.54%, whereas that of the submerged arc weld was 0.86%. After being weighed, the specimens were submerged in molten zinc for 850 h. Analysis (visual inspection, chemical analysis, 100x 2% nital-etched micrographs) supported the conclusions that the vat failed due to molten-zinc corrosion along elongated ferrite bands, possibly because silicon was dissolved in the ferrite and thus made it more susceptible to attack by the molten zinc. Recommendations included rewelding the vat using the manual shielded metal arc process with at least four passes on each side.

An LNG tanker experienced a fracture of the solid tail shaft, which is a section of the main drive shaft. The tail shaft was made of a forged low-carbon steel. In spite of two ultrasonic inspections, a large defect the size of a football in the center of the shaft was missed. During heat treating following forging, it was surmised that the defect led to the propagation of an internal brittle crack, or clink. A fatigue crack propagated from this origin to the outer surface of the shaft after about a year of service. Finally a last ligament of a few square inches held the shaft together and broke, leading to the separation of the shaft. The cause of failure was fatigue crack initiation and crack growth under reverse bending cyclic stresses. There was no indication that misalignment existed because there was no indication of fretting at the bolt holes in the flange at the end of the shaft. In the case of this shaft, a solution would have been to machine the core of the shaft to remove the brittle material or to use a tubular shaft.

Welded low-carbon steel bomb fins were rejected because of poor weld practice. Visual and metallographic examination revealed that the resistance plug welds that attach the outer skin to the inner spar displayed inadequate weld penetration. Recommended changes to the resistance welding parameters resulted in acceptable welds.

After 10 to 20 months of service, the carbon steel hoppers on three trucks used to transport bulk ammonium nitrate prills developed extensive cracking in the upper walls. The prills were discharged from the steel hoppers using air superchargers that generated an unloading pressure of approximately 11 kPa (7 psi). Each hopper truck held from 9,100 to 11,800 kg (10 to 13 tons) of prills when fully loaded and handled approximately 90,700 kg (100 tons) per month. The walls of the hoppers were made of 2.7 mm (0.105 in.) thick flat-rolled carbon steel sheet of structural quality, conforming to ASTM A 245 (obsolete specification replaced by A 570 and A 611). Investigation (visual inspection and 100x micrographs polished and etched with nital) supported the conclusion that failure of the hoppers was the result of intergranular SCC of the sheet-steel walls because of contact with a highly concentrated ammonium nitrate solution. Recommendations included the cost-effective solution of applying a three-coat epoxy-type coating with a total dry thickness of 0.3 mm (0.013 in.) to the interior surfaces of the hoppers.

A 75 mm OD x 7.4 mm wall thickness carbon steel boiler tube ruptured. A substantial degree of corrosion on the water-side surface leaving a rough area in the immediate vicinity of the rupture was revealed by visual examination. Decarburization and extensive discontinuous intergranular cracking was revealed by microscopic examination of a cross section through the tube wall at the fracture. It was concluded that the rupture occurred because of hydrogen damage involving the formation of methane by the reaction of dissolved hydrogen with carbon in the steel. Hydrogen was produced by the chemical reaction that corroded the internal tube surface. Steel embrittled by hydrogen can be restored only if grain boundary cracking or decarburization had not occurred but since the material embrittled in this manner, its replacement was recommended.

Welded to the top of a dust bin for rigid support, a furnace water-wall tube in a new stationary boiler broke at the welded joint shortly after start-up. The tubes measured 64 mm (2.5 in.) OD by 3.2 mm (0.125 in.) wall thickness and were made of carbon steel to ASME SA-226 specifications. Investigation supported the conclusion that a crevice-like undercut was likely the primary cause of the fracture and that the source of the necessary fluctuating stress was tube vibration inherent in boiler operation. Recommendations included magnetic-particle inspection of the remaining water-wall tubes in the row, replacing the broken tube, and repairing cracks in other tubes by welding.

A 455 mm diam x 8 mm thick wall carbon steel (ASTM A 53) discharge line for a circulating-water system at a cooling tower fractured in service; a manifold section cracked where a Y-shaped connection had been welded. Investigation (visual inspection and photographs) supported the conclusion that the pipe failed by fatigue. Cracks originated at crevices and pits in the weld area that acted as stress raisers, producing high localized stresses because of the sharp-radius corner design. Abnormally high structural stresses and alternating stresses resulting from the pump vibrations contributed to the failure. Recommendations included changing the joint design to incorporate a large-radius corner and improving fitting of the components to permit full weld penetration. Backing strips were suggested to increase weld quality, and the pipe wall thickness was increased from 8 to 9.5 mm.

Grease-wiper springs for cams formed from stampings of 0.25-mm thick carbon spring steel (0.65 to 0.80% C) fractured at the 0.025 mm radius on the stamped 135 deg corner at a 90 deg bend after 5,000,000 cycles. Tool marks 2 to 2.3 mm from the center of the stamped bend were disclosed by visual examination. Fatigue striations originating from cracks at the 0.025 mm radius inside corner at the bend were revealed by SEM of the fractured surface. The maximum stress at the bend, in stock of maximum thickness and as a function of the radius of the 135 deg corner, was indicated by stress calculations to be very close to the maximum allowable fluctuating stress for the material. The wiper springs were concluded to be fractured in fatigue and the cyclic loading resulted from cam rotation. The maximum applied stress approached the allowable limit due to high stress-concentration factor in the spring (caused by the very small inside radius). The corner radius was increased to 0.76 mm and the tools were re-polished to avoid tool marks.

The connecting end of two forged medium-carbon steel rods used in an application in which they were subjected to severe low-frequency loading failed in service. The fractures extended completely through the connecting end. The surface hardness of the rods was found to be lower than specifications. The fractures were revealed to be in areas of the transition regions that had been rough ground to remove flash along the parting line. The presence of beach marks, indicating fatigue failure, was revealed by examination. The fracture origin was confirmed by the location and curvature of beach marks to be the rough ground surface. An incipient crack 9.5 mm along with several other cracks on one of the fractured rods was revealed by liquid penetration examination. Metallographic examination of the fractured rods indicated a banded structure consisting of zones of ferrite and pearlite. It was established that the incipient cracks found in liquid-penetrant inspection had originated at the surface in the banded region, in areas of ferrite where this constituent had been visibly deformed by grinding. Closer control on the microstructure, hardness of the forgings and smooth finish in critical area was recommended.