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Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c9001455
EISBN: 978-1-62708-234-1
...-1Zn alloy, was effective in halting and preventing this form of attack. While alarming, the appearance of exfoliation corrosion provides a valuable warning to the engineer or inspector before a severe weakening of the particular sections has occurred. Aging (artificial) Bars Extrusions...
Abstract
Aluminum alloy BS.1476-HE.15 by virtue of its high strength and low density finds application in the form of bars or sections for cranes, bridges, and other such structures where a reduction in dead weight load and inertia stresses is advantageous. Bars and sections in H.15 alloy are mostly produced by extrusion. Some material processed this way has been prone to exfoliation corrosion. Extended aging for 24 h at a temperature of 185 deg C (365 deg F) virtually suppresses the tendency for exfoliation corrosion to develop. Also, the use of a sprayed coating, either of aluminum or Al-1Zn alloy, was effective in halting and preventing this form of attack. While alarming, the appearance of exfoliation corrosion provides a valuable warning to the engineer or inspector before a severe weakening of the particular sections has occurred.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.process.c0046015
EISBN: 978-1-62708-235-8
... and were within the range for 6061-T4 (acceptable hardness, 19 to 45 HRB). This indicated they had been naturally aged at room temperature after solution heat treatment instead of artificially aged as per specs. Edge cracking in two of the T-sections was the result of improper conditions during extrusion...
Abstract
A two-section extension ladder, made from 6061-T6 aluminum alloy extrusions and stampings that were riveted together at each rung location and at the ends of side rails, broke in service after having been used at the sites of several fires by the fire department of a large city. The fracture surfaces were examined visually and by optical (light) stereomicroscopy. Material testing showed a sample to be within the specified material limits for aluminum alloy 6061. Microscopic examination showed no significant differences in microstructure or grain size among the four T-sections, and thickness measurements at various locations indicated that thicknesses were well within standard industry tolerances for aluminum extrusions in this size range. However, hardness testing of the four T-sections showed that in two, hardness was considerably lower than the acceptable hardness for the T6 temper and were within the range for 6061-T4 (acceptable hardness, 19 to 45 HRB). This indicated they had been naturally aged at room temperature after solution heat treatment instead of artificially aged as per specs. Edge cracking in two of the T-sections was the result of improper conditions during extrusion of the T-sections; however, this condition was not a primary cause of failure.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006871
EISBN: 978-1-62708-395-9
... Abstract This article presents a general overview of outdoor weather aging factors, their effects on the performance of polymeric materials, and the accelerated test methods that can be used to investigate those effects. These test methods are used to characterize material performance when...
Abstract
This article presents a general overview of outdoor weather aging factors, their effects on the performance of polymeric materials, and the accelerated test methods that can be used to investigate those effects. These test methods are used to characterize material performance when subjected to specific, often controlled, and well-defined factors. The article also presents an overview of weathering instrument types that simulate outdoor stress factors.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.steel.c9001452
EISBN: 978-1-62708-232-7
... portion of a bracket, bent cold through 90° over 1 4 in. radius and artificially aged by heating at 260°C for three hours. When at attempt was made to straighten the pieces after they were cold, brittle fracture took place after an angular movement of about 5° and the fracture showed a similar...
Abstract
A bracket which formed part of the carrier of a chain conveyor system used to transport components through a continuous oven fractured. A brittle crack originated on the inside of the right-angled bend, the surface having oxidized subsequently. The remaining portion of the fracture resulted from fatigue. Shallow oxidized regions adjacent to the inside surface of the bend indicated pre-existing cracks. A sulphur print on the edge of the bracket showed the material was rolled from a rimming steel ingot. The general appearance of the fracture, and the fact failure took place where embrittlement had developed following plastic straining and service at a temperature of 260 deg C (500 deg F) suggested that failure resulted from strain-age embrittlement.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006920
EISBN: 978-1-62708-395-9
... Abstract This article describes the processes involved in photochemical aging and weathering of polymeric materials. It explains how solar radiation, especially in the UV range, combines with atmospheric oxygen, driving photooxidation and the development of unstable photoproducts that cause...
Abstract
This article describes the processes involved in photochemical aging and weathering of polymeric materials. It explains how solar radiation, especially in the UV range, combines with atmospheric oxygen, driving photooxidation and the development of unstable photoproducts that cause various types of damage when they decompose, including the scission of carbon bonds and polymer chains. The article illustrates some of the degradation reactions that occur in different polymers and presents an overview of the strategies used to prevent such reactions or otherwise mitigate their effects.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.matlhand.c9001474
EISBN: 978-1-62708-224-2
...%, at which the corresponding stress was 21.73 tons per square inch. It was then artificially aged at 250°C for a total of 24 hours, after which the tensile test was continued, the following results being obtained: If no ageing effect had taken place, then the “yield point” on re-testing would have...
Abstract
A mild steel hook that was part of the auxiliary hoist of an electric overhead crane used in a foundry was of the shank type and the rated safe working load was 15 tons. Failure took place in a wholly brittle manner, and occurred transversely through the back of the hook. From the direction in which the fracture developed, as indicated by the radial lines on its surface, it was evident that a preexisting defect served to initiate the brittle fracture. Material adjacent to the fracture was decarburized and contained numerous globules of oxide and slag. It was evident, therefore that a fissure was formed during the manufacture of the hook and had not developed in service. The failure was associated with a surface defect, and it was recommended that the other similar hooks at the establishment be crack detected and any similar discontinuities eliminated.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.design.c0091538
EISBN: 978-1-62708-233-4
... susceptible to this type of failure than retainers made from alloy C65500. The excellent formability of 37% cold-reduced alloy C64700 was a key factor in its successful use for the retainers. Cold reduction, either alone or in combination with artificial aging, has been found to minimize...
Abstract
Electrical contact-finger retainers blanked and formed from annealed copper alloy C65500 (high-silicon bronze A) failed prematurely by cracking while in service in switchgear aboard seagoing vessels. In this service they were sheltered from the weather but subject to indirect exposure to the sea air. About 50% of the contact-finger retainers failed after five to eight months of service aboard ship. Investigation (visual inspection, 250x images etched with equal parts NH4OH and H2O2, emission spectrographic analysis, and stereoscopic views) supported the conclusion that the cracking was produced by stress corrosion as the combined result of: residual forming and service stresses; the concentration of tensile stress at outer square corners of the pierced slots; and preferential corrosive attack along the grain boundaries as a result of high humidity and occasional condensation of moisture containing a fairly high concentration of chlorides (seawater typically contains about 19,000 ppm of dissolved chlorides) and traces of ammonia. Recommendations included redesign of the slots, shot-blasting the formed retainers, and changing the material to a different type of silicon bronze-copper alloy C64700.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006909
EISBN: 978-1-62708-395-9
... Abstract Accelerated life testing and aging methodologies are increasingly being used to generate engineering data for determining material property degradation and service life (or fitness for purpose) of plastic materials for hostile service conditions. This article presents an overview...
Abstract
Accelerated life testing and aging methodologies are increasingly being used to generate engineering data for determining material property degradation and service life (or fitness for purpose) of plastic materials for hostile service conditions. This article presents an overview of accelerated life testing and aging of unreinforced and fiber-reinforced plastic materials for assessing long-term material properties and life expectancy in hostile service environments. It considers various environmental factors, such as temperature, humidity, pressure, weathering, liquid chemicals (i.e., alkalis and acids), ionizing radiation, and biological degradation, along with the combined effects of mechanical stress, temperature, and moisture (including environmental stress corrosion). The article also includes information on the use of accelerated testing for predicting material property degradation and long-term performance.
Series: ASM Failure Analysis Case Histories
Volume: 1
Publisher: ASM International
Published: 01 December 1992
DOI: 10.31399/asm.fach.v01.c9001020
EISBN: 978-1-62708-214-3
... is comparable to the hardness of 7075 aluminum in the T6 (artificially aged) condition (7075 alloy composition: 5.6% Zn, 2.5% Mg, 1.6% Cu, 0.23% Cr, with the balance essentially aluminum). Discussion Results of electrical conductivity determinations showed the strut alloy to have a conductivity of 31.3...
Abstract
The right landing gear on a twin-turboprop transport aircraft collapsed during landing. Preliminary examination indicated that the failure occurred at a steel-to-aluminum (7014) pinned drag-strut connection due to fracture of the lower set of drag-strut attachment lugs at the lower end of the oleo cylinder housing. Two lug fractures that were determined to be the primary fractures were analyzed. Results of various examinations indicated that stress-corrosion cracking associated with the origins of the principal fractures in the connection was the cause of failure. It was recommended that the design be modified to avoid dissimilar metal combinations of high corrosion potential.
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.conag.c9001723
EISBN: 978-1-62708-221-1
.... This phenomenon results in embrittlement of certain susceptible steels which, after having been cold worked, are either left at room temperature for some time (naturally aged) or subjected to a slightly elevated temperature for a short time (artificially aged). Further tests were therefore carried out in order...
Abstract
A new crane failed during the overload test following erection. A test load of 5 tons at the end of the jib (rated capacity 4 tons) was in the process of being slewed at the time of this failure. Inspection revealed that the collapse had resulted from the opening out of one eye of the rimming steel tie-bar of the main jib at the lower splice. This permitted the pin to pass through and allowed the jib to fall. Examination subsequently revealed that brittle fracture of two of the corner angles of the tower head assembly had also occurred. Had the tie-bar material been of satisfactory quality and/or, if the end that failed had been flamecut instead of sheared, then the damage resulting from the excessive overload would have been limited to yielding of the material in the region of the pin-joint. Such yielding on an overload test further indicated that the scantlings of the pin-joints were inadequate. Two other crane failures showed that failure resulted from the use of rimming steel, and embrittlement of the material was evident.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006811
EISBN: 978-1-62708-329-4
..., have improved or enabled mobility for patients with debilitating injuries and age- or disease-related joint degradation. Cardiovascular devices, such as defibrillators, pacemakers, and vascular stents, have revolutionized the treatment of heart disease and defects and have enabled percutaneous...
Abstract
Bearing in mind the three-legged stool approach of device design/manufacturing, patient factors, and surgical technique, this article aims to inform the failure analyst of the metallurgical and materials engineering aspects of a medical device failure investigation. It focuses on the device "failures" that include fracture, wear, and corrosion. The article first discusses failure modes of long-term orthopedic and cardiovascular implants. The article then focuses on short-term implants, typically bone screws and plates. Lastly, failure modes of surgical tools are discussed. The conclusion of this article presents several case studies illustrating the various failure modes discussed throughout.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006778
EISBN: 978-1-62708-295-2
.... A very large-diameter worm gear that had been in service in a dam for more than 60 years exhibited cracks and was removed. It was reported that the cast bronze gear was only rarely stressed during service, associated with infrequent opening and closing of gates. Due to the age of the gear and the time...
Abstract
This article aims to identify and illustrate the types of overload failures, which are categorized as failures due to insufficient material strength and underdesign, failures due to stress concentration and material defects, and failures due to material alteration. It describes the general aspects of fracture modes and mechanisms. The article briefly reviews some mechanistic aspects of ductile and brittle crack propagation, including discussion on mixed-mode cracking. Factors associated with overload failures are discussed, and, where appropriate, preventive steps for reducing the likelihood of overload fractures are included. The article focuses primarily on the contribution of embrittlement to overload failure. The embrittling phenomena are described and differentiated by their causes, effects, and remedial methods, so that failure characteristics can be directly compared during practical failure investigation. The article describes the effects of mechanical loading on a part in service and provides information on laboratory fracture examination.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003543
EISBN: 978-1-62708-180-1
... of a Bronze Worm Gear A very large diameter worm gear that had been in service in a dam for more than 60 years exhibited cracks and was removed. It was reported that the cast bronze gear was only rarely stressed during service, associated with infrequent opening and closing of gates. Due to the age...
Abstract
Overload failures refer to the ductile or brittle fracture of a material when stresses exceed the load-bearing capacity of a material. This article reviews some mechanistic aspects of ductile and brittle crack propagation, including a discussion on mixed-mode cracking, which may also occur when an overload failure is caused by a combination of ductile and brittle cracking mechanisms. It describes the general aspects of fracture modes and mechanisms. The article discusses some of the material, mechanical, and environmental factors that may be involved in determining the root cause of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.conag.c9001471
EISBN: 978-1-62708-221-1
... test piece was cut from the wearing surface of the hook with a view to ascertaining whether any strain-age embrittlement had occurred in this region, this surface being on the tension side of the specimen when it was tested by slow bending. It bent satisfactorily to 90° without showing any indications...
Abstract
A crane hook was stamped S.W.L. 3 tons and, while its main dimensions were in approximate accordance with those specified in B.S. 482 for a hook of this capacity, its shape in some respects was not exactly in conformity with that recommended. At the time of fracture, the load being lifted was slightly under 10 cwts. Fracture occurred away from the normal wearing surface where the hook makes contact with the lifting slings. There was no evidence that fracture was preceded by any appreciable deformation locally or in the region of the failure. A sulphur print, taken on a cross section of the hook adjacent to the plane of fracture, showed the hook was made from a killed steel free from major segregation. Microscopic examination showed the material to be a mild steel in the normalized condition, the carbon content being of the order of 0.25%. Bend tests showed the material at the intrados of the hook would deform in a ductile manner both under slow and impact-loading conditions if in the form of an unnotched test piece, but if notched, it failed in a brittle manner under impact, though not under slow loading.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001819
EISBN: 978-1-62708-180-1
... ORTHOPEDIC IMPLANTS are unique in that they are exposed to the biochemical and dynamic environment of the body and their design is dictated by anatomy and restricted by physiological conditions. Orthopedic implants are artificial devices (allentheses) that are mounted to the skeletal system of the human body...
Abstract
This article commences with a description of the prosthetic devices and implants used for internal fixation. It describes the complications related to implants and provides a list of major standards for orthopedic implant materials. The article illustrates the body environment and its interactions with implants. The considerations for designing internal fixation devices are also described. The article analyzes failed internal fixation devices by explaining the failures of implants and prosthetic devices due to implant deficiencies, mechanical or biomechanical conditions, and degradation. Finally, the article discusses the fatigue properties of implant materials and the fractures of total hip joint prostheses.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006918
EISBN: 978-1-62708-395-9
Abstract
This article reviews generalized test methodologies for fatigue characterization of polymers and examines fatigue fracture mechanisms in different engineering plastics. It provides detailed micromechanistic images of crack-tip processes for a variety of semicrystalline and amorphous engineering polymers. The article describes fracture mechanics solutions and approaches to the fatigue characterization of engineering polymers when dealing with macroscale fatigue crack growth. It includes mechanistic images for high-density polyethylene, ultrahigh-molecular-weight polyethylene, nylon 6, 6, polycarbonate, and polypropylene. The article describes the micromechanisms of toughening of plastics and uses a macroscale approach of applying fracture mechanics to the fatigue life prediction of engineering polymers, building on the mechanistic concepts. It also describes the factors affecting fatigue performance of polymers.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006785
EISBN: 978-1-62708-295-2
... temper designation has been solution heat treated and artificially aged to maximum strength. For more information, refer to Properties and Selection: Nonferrous Alloys and Special-Purpose Materials , Volume 2 of the ASM Handbook , 1990. An aluminum alloy with a T7 temper designation has been solution...
Abstract
Stress-corrosion cracking (SCC) is a form of corrosion and produces wastage in that the stress-corrosion cracks penetrate the cross-sectional thickness of a component over time and deteriorate its mechanical strength. Although there are factors common among the different forms of environmentally induced cracking, this article deals only with SCC of metallic components. It begins by presenting terminology and background of SCC. Then, the general characteristics of SCC and the development of conditions for SCC as well as the stages of SCC are covered. The article provides a brief overview of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions commonly associated with the development of SCC, although not all, and numerous case studies.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003524
EISBN: 978-1-62708-180-1
Abstract
This article describes the preliminary stages and general procedures, techniques, and precautions employed in the investigation and analysis of metallurgical failures that occur in service. The most common causes of failure characteristics are described for fracture, corrosion, and wear failures. The article provides information on the synthesis and interpretation of results from the investigation. Finally, it presents key guidelines for conducting a failure analysis.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006794
EISBN: 978-1-62708-295-2
... as reference, the difference in potential between the metal and SHE is the standard electrode potential of the metal (V°). The higher the electrode potential of a metal, the lower its tendency to corrode ( Ref 25 ). For instance, Cu ( V Cu ∘ = +0.334 V) and Ag ( V Ag ∘ = +0.80 V...
Abstract
Corrosive wear is defined as surface damage caused by wear in a corrosive environment, involving combined attacks from wear and corrosion. This article begins with a discussion on several typical forms of corrosive wear encountered in industry, followed by a discussion on mechanisms for corrosive wear. Next, the article explains testing methods and characterization of corrosive wear. Various factors that influence corrosive wear are then covered. The article concludes with general guidelines for material selection against corrosive wear.
Series: ASM Failure Analysis Case Histories
Volume: 3
Publisher: ASM International
Published: 01 December 2019
DOI: 10.31399/asm.fach.v03.c9001789
EISBN: 978-1-62708-241-9
... chemistries (wt.%): measured and specified Material Al Fe Ni + Co Mn Pb Si Sn As Zn Cu + Ag ASB/HTP 6.80 <0.02 0.08 0.03 <0.01 1.70 <0.01 <0.01 0.06 bal. ASB/HTP 6.90 <0.02 0.08 <0.02 <0.01 1.60 <0.01 <0.01 0.08 bal. spec. lim. 63–1.6...
Abstract
An air system on a marine platform unexpectedly shut down due to the failure of a union nut, which led to an investigation to quantify the material limitations of bronze alloys in corrosive marine environments. The study focused on two alloys: Al-Si bronze, as used in the failed component, and Ni-Al bronze, which has a history of success in naval applications. Material samples were examined using chemical analysis, SEM imaging, and corrosion testing. Investigators also analyzed precracked tension specimens, exposing them to different conditions to quantify stress intensity thresholds for environmentally assisted cracking. Al-Si bronze was found to be susceptible to subcritical intergranular cracking in air and seawater, whereas Ni-Al bronze was unaffected. Both materials, however, are susceptible to cracking in the presence of ammonia, although the subcritical crack growth rate is two to three times higher in Ni-Al bronze. Based on the results of this work, the likelihood of subcritical cracking under various conditions can be reasonably estimated, which, in the case at hand, proved to be quite high.
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