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in Formation of Refractory Films on Metal Contacts in an Electrical Switchgear
> Handbook of Case Histories in Failure Analysis
Published: 01 December 1993
Fig. 2 Typical microstructure of a 27Ag–73W contact. The light areas are silver, the dark areas tungsten. 380×
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Series: ASM Failure Analysis Case Histories
Volume: 2
Publisher: ASM International
Published: 01 December 1993
DOI: 10.31399/asm.fach.v02.c9001389
EISBN: 978-1-62708-215-0
..., and calibration areas be isolated from molding areas. Ammonia, environment Atmospheric corrosion Circuit breakers Electric contacts, corrosion Electrical resistance 50Ag-50Mo 73W-27Ag Uniform corrosion Background During routine quality control testing, electrical switchgear devices exhibited...
Abstract
During routine quality control testing, small circuit breakers exhibited high contact resistance and, in some cases, insulation of the contacts by a surface film. The contacts were made of silver-refractory (tungsten or molybdenum) alloys. Infrared analysis revealed the film to be a corrosion layer that resulted from exposure to ammonia in a humid atmosphere. Simulation tests confirmed that ammonia was the corrodent. The ammonia originated from the phenolic molding area of the plant. It was recommended that fumes from molding areas be vented outside the plant and that assembly, storage, and calibration areas be isolated from molding areas.