On 13 Dec 1994, two massive detonations leveled portions of an ammonium nitrate plant near Sioux City, IA. The primary explosion allegedly occurred in defectively-designed titanium sparger piping inside the neutralizer vessel. Investigation however, revealed the explosion occurred because of unsafe plant operations and poor maintenance procedures. Specifically, the ammonium nitrate within the 18,000 gal capacity neutralizer vessel had become contaminated and made highly acidic. The operators then injected superheated steam directly into the ammonium nitrate in the neutralizer vessel.

Corrosion failure occurred in a titanium clad tubesheet because of a corrosive tube-side gas-liquid mixture leaking through fatigue cracks in the seal welds at tube-to-tubesheet joints. The tubesheet was a carbon steel plate clad with titanium on the tube side face. The seal weld cracks were initiated by cyclic stress imposed by exchanger tubes. The gas-liquid mixture passed through cracks under tube-side pressure, resulting in severe corrosion of the steel backing plate. The failure started with the loosening of the expanded tube-to-tubesheet joints. Loose joints allowed the exchanger tubes to impose load on seal welds and the shell side cooling water entered the crevice between the tubesheet and the tubes. The cooling water in the crevice caused galvanic reaction and embrittlement of seal welds. Brittle crack opening and crack propagation in seal welds occurred due to the cyclic stress imposed by the tubes. The cyclic stress arised from the thermal cycling of the heat exchanger. The possible effects of material properties on the failure of the tubesheet are discussed.

A DC-10 in transit from Denver to Chicago experienced failure of the center engine. The titanium compressor disk burst and severed the hydraulics of the plane. Investigation supports the conclusion that the cause of the disk rupture was the presence of a large fatigue crack near the bore emanating from a hard alpha (HA) defect. Such defects can result from occasional upsets during the vacuum melting of titanium. These nitrogen-rich alpha titanium anomalies are brittle and often have associated microcracks and microvoids. A probabilistic damage tolerance approach was recommended to address the anomalies, with the objective of enhancing rotor life management practices. The ongoing work involves the use of fracture mechanics and software (called DARWIN.) optimized for damage tolerant design and analysis of metallic structural components.

This article provides an overview of the classification of hydrogen damage. Some specific types of the damage are hydrogen embrittlement, hydrogen-induced blistering, cracking from precipitation of internal hydrogen, hydrogen attack, and cracking from hydride formation. The article focuses on the types of hydrogen embrittlement that occur in all the major commercial metal and alloy systems, including stainless steels, nickel-base alloys, aluminum and aluminum alloys, titanium and titanium alloys, copper and copper alloys, and transition and refractory metals. The specific types of hydrogen embrittlement discussed include internal reversible hydrogen embrittlement, hydrogen environment embrittlement, and hydrogen reaction embrittlement. The article describes preservice and early-service fractures of commodity-grade steel components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also reviewed.

This article discusses the fundamental variables involved in fatigue-life assessment, which describe the effects and interaction of material behavior, geometry, and stress history on the life of a component. It compares the safe-life approach with the damage-tolerance approach, which employs the stress-life method of fatigue life assessment. The article examines the behavior of three different metallic materials used in the design and manufacture of structural components: steel, aluminum, and titanium. It also reviews the effects of retardation and spectrum load on component life. The article concludes with case studies of fatigue life assessment from the aerospace industry.