A support arm on a front-end loader failed in a brittle manner while lifting a load. The arm had a cross section of 50 x 200 mm (2 x 8 in.). Material used for the arm was hot-rolled ASTM A572, grade 42 (type 1), steel, which exhibited poor impact properties in the as-rolled condition and had a ductile-to-brittle transition temperature exceeding 93 deg C (200 deg F). This transition temperature was much too high for the application. It was recommended that a modified ASTM A572, grade 42 (0.15% C max), type 1 or 2, steel be used (type 1, which contains niobium, may be needed to meet strength requirements). The steel should be specified to be killed, fine-grained, and normalized, with Charpy V-notch impact-energy values of 20 J (15 ft·lbf) at -46 deg C (-50 deg F) in the longitudinal direction and 20 J (15 ft·lbf) at -29 deg C (-20 deg F) in the transverse direction.

A riveted 0.25% carbon steel oil-storage tank in Oklahoma was dismantled and reassembled in Minnesota by welding to form a storage tank for soybean oil. An opening was cut in the side of the tank to admit a front-end loader. A frame of heavy angle iron was welded to the tank and drilled for bolting on a heavy steel plate. The tank was filled to a record height. In mid-Jan the temperature dropped to -31 deg C (-23 deg F), with high winds. The tank split open and collapsed. The welding used the shielded metal arc process with E6010 electrodes, which could lead to weld porosity, hydrogen embrittlement, or both. At subzero temperatures, the steel was below its ductile-to-brittle transition temperature. These circumstances suggest a brittle condition. Steps to avoid this type of failure: For cold conditions, the steel plate should have a low carbon content and a high manganese-to-sulfur ratio and be in a normalized condition, low-hydrogen electrodes and welding practices should be used, all corners should be generously radiused, the welds should be inspected and ground or dressed to minimize stress concentrations, postweld heating is advisable, and radiographic and penetrant inspection tests should be performed.

The splined shaft (1040 steel, heat treated to a hardness of 44 to 46 HRC and a tensile strength of approximately 1448 MPa, or 210 ksi) from a front-end loader used in a salt-handling area broke after being in service approximately two weeks while operating at temperatures near -18 deg C (0 deg F). During the summer, similar shafts had a service life of 5 to eight months. Examination of the fracture surface showed brittle fatigue cracks, and visual examination of the splines disclosed heavy chatter marks at the root of the spline, with burrs and tears at the fillet area. Evidence found supports the conclusion that the shaft failed as the result of stress in the sharp fillets and rough surfaces at the root of the splines. Cold weather failure occurred sooner than in hot weather because ductile-to-brittle transition temperature of the 1040 steel shaft was too high. Recommendations include redesign of the fillet radius to a minimum of 1.6 mm (0.06 in.) and a maximum surface finish in the spline area of 0.8 microns. Material for the shafts should be modified to a nickel alloy steel, heat treated to a hardness of 28 to 32 HRC before machining.

In TAKR 300 (Bob Hope) Class transport ships, the builder observed cracking of steel cloverleaf vehicle tie-down deck sockets following installation. Sockets were made from AH36 steel plate by flame cutting and cold coining, then submerged-arc welded to the shop deck. Cracks initiated from the tip of the cloverleaf pattern in >300 cases aboard several cargo vessels in various stages of construction. Consultants who analyzed the situation concluded that the problem may have been corrosion and hydrogen embrittlement. Three possible mechanisms of failure were considered: overload failure; fatigue fracture; and, environmentally-assisted cracking. Testing indicated overload failure was the cause. Remedial actions were taken to improve the fracture properties of the deck socket. A modified manufacturing process was developed involving milling and cutting instead of coining to round the comers of the flame-cut cloverleaf lobe. This new manufacturing process solved the problem.

A metallurgical failure analysis was performed on pieces of the cracked vent header pipe from the Edwin I. Hatch Unit 2 Nuclear power plant. The analysis consisted of optical microscopy, chemical analysis, mechanical Charpy impact testing, and fractography. It was found that the material of the vent header met the mechanical and chemical properties of ASTM A516 Grade 70 carbon-manganese steel material and microstructures were consistent with this material. Fracture faces of the cracked pipe were predominantly brittle in appearance with no evidence of fatigue contribution. The NDTT (Nil ductility Transition Temperature) for this material was approximately -51 deg C (-60 deg F). The fact that the material's NDTT was significantly out of the normal operating range of the pipe suggested an impingement of low temperature nitrogen (caused by a faulty torus inerting system) induced a thermal shock in the pipe which, when cooled below its NDTT, cracked in a brittle manner.

During construction of a revolving sky-tower observatory, a 2.4 m (8 ft) diam cylindrical column developed serious circumferential cracks overnight at the 14 m (46 ft) level where two 12 m (40 ft) sections were joined by a girth weld. The temperatures ranged from 12 deg C (53 deg F) to 7 deg C (45 deg F) that night. The column was shop fabricated in 12 m (40 ft) long sections of 19 mm (3/4 in.) thick steel plate of ASTM A36 steel. Crack initiation was caused by high residual stress during girth welding, and the presence of notches formed by the termination of the incomplete welds. Continuation of the cracks was attributed to the brittle condition of the steel when cooled by the night air. A steel with a much lower ductile-to-brittle transition temperature is essential for this type of structure. Other necessary steps include better control of the girth-welding, choice of a more favorable electrode to avoid porosity, careful termination of all welds to avoid formation of notches, and completion of all welds before other sections of the column are erected.

A 208 cm (82 in.) ID steel aqueduct (ASTM A572, grade 42, type 2 steel) fractured circumferentially at two points 152 m (500 ft) apart in a section above ground. A year later, another fracture occurred in a buried section 6.4 km (4 mi) away. Both pipes fractured during Jan at similar temperatures and pressures. The pipe had a 24 mm wall thickness, and the hydrostatic head was 331 m (1085 ft). The air temperature was approximately -13 deg C (9 deg F), the water temperature approximately 0.6 deg C (33 deg F), and the steel temperature approximately -4 deg C (25 deg F). The pipe had been shop-fabricated in 12 m (40 ft) lengths, then shop welded into 24 m (80 ft) lengths. Field assembly was with bell-and-spigot joints. Investigation (visual inspection and Charpy V-notch testing) supported the conclusion that brittle fracture of the aqueduct pipe was attributed to a combination of stress concentrations at the toes of the fillet welds due to poor welding technique, including shop welds made without preheat, and a brittle condition of the steel at winter temperatures. Recommendations included revised welding techniques, installation of expansion joints, and the use of steel plate rolled from fully killed ingots.

The article commences with an overview of short-term and long-term mechanical properties of polymeric materials. It discusses plasticization, solvation, and swelling in rubber products. The article further describes environmental stress cracking and degradation of polymers. It illustrates how surface degradation of a plain strain tension specimen alters the ductile brittle transition in polyethylene creep rupture. The article concludes with information on the effects of temperature on polymer performance.