The surface of a hook did not possess the smooth and shiny zinc bloom surface normally observed on hot galvanized steel parts but was matte and rough. Large cracks were observed in the zinc layer. The hook was made of silicon-killed alloy steel 41Cr4. A silicon content of 0.27% was established analytically. Silicon accelerates the reaction between iron and zinc, which should have been taken into account in the present case by reducing the dip time or a small addition of aluminum (0.1 to 0.2%) to the galvanizing bath to retard the extremely rapid growth of the zinc layer and the strong alloy formation. Even in the case of steel parts with lower silicon contents the reaction between iron and zinc can continue until the pure zinc layer has been consumed entirely if the work piece is not cooled sufficiently after withdrawal.

A steel galvanizing vat measuring 3 x 1.2 x 1.2 m (10 x 4 x 4 ft) and made of 19 mm thick carbon steel plate (ASTM A285, grade B)) at a shipbuilding and ship-repair facility failed after only three months of service. To verify suspected failure cause, two T joints were made in 12.5 mm thick ASTM A285, grade B, steel plate. One joint was welded using the semiautomatic submerged arc process with one pass on each side. A second joint was welded manually by the shielded metal arc process using E6010 welding rod and four passes on each side. The silicon content of the shielded metal arc weld was 0.54%, whereas that of the submerged arc weld was 0.86%. After being weighed, the specimens were submerged in molten zinc for 850 h. Analysis (visual inspection, chemical analysis, 100x 2% nital-etched micrographs) supported the conclusions that the vat failed due to molten-zinc corrosion along elongated ferrite bands, possibly because silicon was dissolved in the ferrite and thus made it more susceptible to attack by the molten zinc. Recommendations included rewelding the vat using the manual shielded metal arc process with at least four passes on each side.

Galvanized A36 steel unsleeved shear-type anchor bolts failed during installation. The galvanized steel bolts were approximately 18 mm (0.7 in.) in diameter with a 90 deg bend between the long and short legs. As-fractured, sawcut, and unfractured specimens were examined. Failure analysis revealed dark thumbnail regions at the fracture origins and a very narrow and uniform shear lip. The thumbnail region exhibited zinc deposits with no apparent fracture detail, indicating preexisting cracks that had occurred before galvanizing. The balance of the fracture exhibited a transgranular mode with cleavage and ductile, dimpled shear. Hardness values as high as 35 HRC were measured in the bend area. The as-galvanized bolts fractured in a brittle manner. Failure was attributed to improper bending of the bolts, which provided a severely cold-worked bend area susceptible to strain-age embrittlement.