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Phosphate conversion coating
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Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.modes.c0048147
EISBN: 978-1-62708-234-1
Abstract
The power-type counterbalance spring, formed from hardened-and-tempered carbon steel strip and subsequently subjected to phosphating treatment, fractured at the two locations during fatigue testing. A rust colored dark band at the inside edge of the fracture surface was disclosed during investigation. Etch pits were revealed by the cleaned surface which were never observed on properly phosphated coating. It was interpreted that the spring had been subjected to an abnormal acid attack in pickling or phosphating which had resulted in considerable absorption of hydrogen by the metal and hence embrittlement. The part was concluded to have cracked during phosphating or excessive acid pickling before phosphating.
Book Chapter
Series: ASM Failure Analysis Case Histories
Publisher: ASM International
Published: 01 June 2019
DOI: 10.31399/asm.fach.mech.c0090994
EISBN: 978-1-62708-225-9
Abstract
Two large tension springs fractured during installation. The springs were manufactured from a grade 9254 chromium-silicon steel spring wire. The associated material specification allows wire in the cold-drawn or oil-tempered (quenched-and-tempered) condition. The specified wire tensile strength range was 1689 to 1793 MPa (245 to 260 ksi). The finished springs were to be shot peened for greater fatigue resistance. Investigation (visual inspection, 3x images, 2% nital etched 148x SEM images, chemical analysis, hardness testing, and EDS analysis) supported the conclusion that the springs failed during installation due to the presence of preexisting defects. Crack surfaces were found to be corroded and phosphate coated, indicating that the cracks occurred during manufacture. Installation, which presumably entailed some axial extension, resulted in ductile overload failure at the crack sites. Recommendations included evaluating the manufacturing steps to identify the process(es) wherein the cracking was likely occurring. It was further recommended that a suitable nondestructive method such as magnetic particle inspection be implemented.