A thick-walled tube that was weld fabricated for use as a pressure vessel exhibited cracks. Similar cracking was apparent at the weld toes after postweld stress relief or quench-and-temper heat treatment. The cracks were not detectable by nondestructive examination after welding, immediately prior to heat treatment. Multiple-pass arc welds secured the carbon-steel flanges to the Ni-Cr-Mo-V alloy steel tubes. Investigation (visual inspection, metallographic analysis, and evaluation of the fabrication history and the analysis data) supported the conclusion that the tube failed as a result of stress-relief cracking. Very high residual stresses often result from welding thick sections of hardenable steels, even when preheating is employed. Quenched-and-tempered steels containing vanadium, as well as HSLA steels with a vanadium addition, have been shown to be susceptible to this embrittlement. Manufacturers of susceptible steels recommend use of these materials in the as-welded condition.

Beveled weld-joint V-sections were fabricated to connect inlet and outlet sections of tubes in a type 347 stainless steel heat exchanger for a nitric acid concentrator. Each V-section was permanently marked with the tube numbers by a small electric-arc pencil. After one to two years of service, multiple leaks were observed in the heat-exchanger tubes. Investigation supported the conclusion that the corrosion occurred at two general locations: the stop point of the welds used to connect the inlet and outlet legs of the heat exchanger, and the stop points on the identifying numerals. Recommendations included replaced the material with type 304L stainless steel.

Welded to the top of a dust bin for rigid support, a furnace water-wall tube in a new stationary boiler broke at the welded joint shortly after start-up. The tubes measured 64 mm (2.5 in.) OD by 3.2 mm (0.125 in.) wall thickness and were made of carbon steel to ASME SA-226 specifications. Investigation supported the conclusion that a crevice-like undercut was likely the primary cause of the fracture and that the source of the necessary fluctuating stress was tube vibration inherent in boiler operation. Recommendations included magnetic-particle inspection of the remaining water-wall tubes in the row, replacing the broken tube, and repairing cracks in other tubes by welding.

A backwell tube situated in the combustion chamber of a 100 atm boiler, which had been in service for many years, failed. The temperature of the saturated steam was about 300 deg C. Two pipe sections with attacked areas in the circumferential welding joint were examined for cause of failure. First section showed strong pit or trench-like attack in the welding seam on the inner surface. A bluish-black corrosion product adhered to the pits. The second section showed small blisters at the welding seam. The metallographic examination of the first section showed welding seam was strongly reduced in bulk from the inside and covered with a thick crumbling layer of magnetic iron oxide (Fe3-O4). This was a corrosion product resulting from the operation of the boiler. In addition, it was decarburized from the inside, and interspersed with grain boundary cracks. This form of attack is typical for the decarburization of steel by high-pressure hydrogen. Hence, the defects in the pipe sections were the result of scaling during the operation of the steam boiler. It was recommended to avoid unnecessary overheating during the welding of materials for high-pressure steam boiler operations.