This study examines the role of calcium-precipitating bacteria (CPB) in heat exchanger tube failures. Several types of bacteria, including Serratia sp. (FJ973548), Enterobacter sp. (FJ973549, FJ973550), and Enterococcus sp. (FJ973551), were found in scale collected from heat exchanger tubes taken out of service at a gas turbine power station. The corrosive effect of each type of bacteria on mild steel was investigated using electrochemical (polarization and impedance) techniques, and the biogenic calcium scale formations analyzed by XRD. It was shown that the bacteria contribute directly to the formation of calcium carbonate, a critical factor in the buildup of scale and pitting corrosion on heat exchanger tubes.

Material samples collected from failed booster pumps were analyzed to determine the cause of failure and assess the adequacy of the materials used in the design. The pumps had been in service at a power plant, transporting feedwater from a deaerator to a main turbine boiler. Samples from critical areas of the pump were examined using optical and scanning electron microscopy, electrochemical analysis, and tensile testing. Based on microstructure and morphology, estimated corrosion rates, and particle concentrations in the feedwater, it was concluded that cavitation and erosion were the dominant failure mechanisms and that the materials and processes used to make the pumps were largely unsuited for the application.

Explosive cladding is a viable method for cladding different materials together, but the complicated behavior of materials under ballistic impacts raises the probability of interfacial shear failure. To better understand the relationship between impact energy and interfacial shear, investigators conducted an extensive study on the shear strength of explosively cladded Inconel 625 and plain carbon steel samples. They found that by increasing impact energy, the adhesion strength of the resulting cladding can be improved. Beyond a certain point, however, additional impact energy reduces shear strength significantly, causing the cladding process to fail. The findings reveal the decisive role of plastic strain localization and the associated development of microcracks in cladding failures. An attempt is thus made to determine the optimum cladding parameters for the materials of interest.

High-level radioactive wastes generated during the processing of nuclear materials are kept in large underground storage tanks made of low-carbon steel. The wastes consist primarily of concentrated solutions of sodium nitrate and sodium hydroxide. Each of the tanks is equipped with a purge ventilation system designed to continuously remove hydrogen gas and vapors without letting radionuclides escape. Several intergranular cracks were discovered in the vent pipe of one such system. The pipe, made of galvanized steel sheet, connects to an exhaust fan downstream of high-efficiency particulate air filters. The failure analysis investigation concluded that nitrate-induced stress-corrosion cracking was the cause of the failure.

A 13/16-in. hex socket failed while in use. Analysis (hardness testing, optical and scanning electron microscopy, and EDS) revealed that the socket was made of low carbon steel formed in a powder metallurgy process. A number of flaws were found including nonuniform wall thickness, poor geometric design with sharp corners as stress raisers, and incomplete sintering evidenced by unsintered particles. These were determined to be the primary cause of failure, although inclusions on the fracture surface containing S and Al may have played a role as well.

A controllable pitch propeller (CPP) on a dynamic positioning ship failed after eight months of operation. The CPP design consists of a hollow propeller shaft and a concentrically located pipe that operates inside. The pitch of the propeller blades is controlled hydraulically through the longitudinal displacement of the inner (concentric) pipe. Fractography, microstructural, microhardness, and chemical analyses revealed that the concentric pipe failed due to fatigue. Fatigue cracks initiated along longitudinal welds where wire spacers attach to the external surface of the pipe. The effect of crack-like defects, stress concentration at the weld toe, residual tensile stress, and lack of penetration contributed to a shorter fatigue crack initiation phase and premature failure.

A shaft which carried the diverter sheave wheel of an electric goods lift failed, resulting in the cage failing to the bottom of the well. Failure had taken place at a reduction in diam at which no filet radius existed. Metallurgical examination did not disclose any abnormal features. The material was a mild steel in the normalized condition. The appearance of the fracture indicated failure was due to bending stresses. The absence of any fillet radius at the reduction in diam provided a region of stress concentration from which fatigue cracks developed.

Following three similar failures of load chains on manually operated geared pulley-blocks of 1-ton capacity, a portion of one of the chains was obtained for examination. The chain was made of mild steel and the links had been electrically butt-welded at one side. In the case of the sample obtained, the failure in service had resulted from fracture of one of the links in the plane of the weld. Six of the other links in the vicinity showed cracks in the welds in various stages of development. Microscope examination showed a crack in an early stage of development and also from an apparently sound link, the prepared surfaces lying in the planes of the links. This examination revealed that the welds were initially defective. Discontinuities were present in both cases adjacent to the insides of the links, of a type indicative of either inadequate fusion or incomplete expulsion of oxide, etc., at the time of the upset, i.e. the pressing together of the ends of the links to complete the welding. It was evident from the examination that the service failures were due to the use of chain that was initially defective.

The cross bars of conveyor belt links that served to transport glass containers through a stress relief furnace fractured in many cases. They consisted of wires of 5 mm diam made of low-carbon Siemens-Martin steel, while the interwoven longitudinal bars were made of strip steel of 4 x 2 sq mm. The furnace temperature was said to be 500 deg C. In addition to the fractures they also showed many more or less advanced cracks. These occurred in the circumferential grooves that recurred at regular intervals. The fractures were abraded and oxidized. They could have been fatigue fractures. The fracture probably was induced by the pressing-in or abrading of the sharp steel band edges into the surface of the cross bars. Torsion fatigue fractures may have started from these notches. Relaxation then contributed positively through recovery and recrystallization. Such damage occurs less frequently in round wire conveyor belt links because the round wire neither impresses so sharply nor abrades against the cross bars, and it also exerts less torsion than the flat wire.

A hook, which was marked for a safe working load of 2 tons, failed while lifting a load of approximately 35 cwts. Fracture took place at the junction of the shank with the hook portion, at which no fillet radius existed. Except for an annular region round the periphery, which was of a smooth texture, the fracture was brightly crystalline indicative of a brittle failure. Microscopic examination showed the material was a low-carbon steel in the normalized condition; no abnormal features were observed. The basic cause of failure was the presence of a fatigue crack at the change of section where the shank joined the hook portion. To minimize the possibility of fatigue cracking, it was recommended that a generous radius be provided at the change of section.

A mild steel hook that was part of the auxiliary hoist of an electric overhead crane used in a foundry was of the shank type and the rated safe working load was 15 tons. Failure took place in a wholly brittle manner, and occurred transversely through the back of the hook. From the direction in which the fracture developed, as indicated by the radial lines on its surface, it was evident that a preexisting defect served to initiate the brittle fracture. Material adjacent to the fracture was decarburized and contained numerous globules of oxide and slag. It was evident, therefore that a fissure was formed during the manufacture of the hook and had not developed in service. The failure was associated with a surface defect, and it was recommended that the other similar hooks at the establishment be crack detected and any similar discontinuities eliminated.

The interior of a cylindrical tank used for the road transport of concentrated sulfuric acid revealed severe blistering of the plates, mainly over the crown and more particularly on the first ring. The tank, made in 1958, was of welded construction, the material being mild steel plate. Some of the blisters were pierced by drilling a hole in the center and at the same time applying a small flame. In several cases combustion of the escaping gas caused minor explosions, a result characteristic of hydrogen. Etching showed the material to be a low-carbon steel in the partly spheroidized condition. There was no evidence of cracking of the material in the region of the blisters and bend tests demonstrated it possessed satisfactory ductility. The primary cause of the blistering was ascribed to the presence of discontinuities within the plate. This provided cavities in which the hydrogen was able to accumulate and build up pressure. Had the material been free from discontinuities of appreciable size, the blistering would not have occurred.

A steam jacketed autoclave of orthodox design was fabricated from mild steel for a working pressure of 320 psi. The only unusual feature in its construction was a protective layer of weld metal, which was deposited on the internal surface of the upper half of the 1 in. thick shell. The first indication of latent trouble was provided by the bolts which attached the stirring paddles to the shaft and the stationary scraper blades to the shell, either failing in service or breaking off when an attempt was made to remove them. It was the practice to renew them all annually. Microscopic examination of a failed bolt showed the path of the fracture and the secondary cracking associated with it were intergranular, suggesting that failure resulted from stress corrosion. A steel of the rimming type had been used to make the bar from which the bolt was forged. Cracks which originate at the root of threads generally result from fatigue but, in this instance, their intergranular mode of progression indicated that they were due to stress-corrosion. Examination of shell material showed that the cracks in the vessel were wholly intergranular. It was apparent from this evidence that this cracking was also due to stress-corrosion.

Welded steel storage vessels used to hold mildly alkaline solution were produced in exactly the same manner from deep-drawn aluminum-killed SAE 1006 low-carbon steel sheet. After the cylindrical shell was drawn, a top low-carbon steel closure was welded to the inside diameter. The containers were then filled with the slightly alkaline solution, pressurized, and allowed to stand under ambient conditions. A small number, less than 1%, were returned because they began to leak in service. Inspection revealed general corrosion and pitting on the inner surfaces. However, other tanks that experienced the same service conditions developed no corrosion. Corrosion was linked to forming defects that provided sites for localized corrosion, and to lack of steam drying after cleaning, which increased susceptibility to general corrosion.

A fracture mechanics based failure analysis and life prediction of a large centrifugal fan made from low-carbon, medium-strength steel was undertaken following shortcomings in attempts to explain its fatigue life from start stop cycles alone. Measurements of the fracture toughness and flaw size at failure, coupled with quantitative SEM fractography using striation spacing methods, revealed that the cyclic stress amplitudes just prior to failure were much larger than expected, in this particular case. Subsequent improvements in fan design and fabrication have effectively alleviated the problem of slow, high cycle fatigue crack growth, at normal operating stresses in similar fans.

In a main range in a power station, steam was conveyed at a pressure of 645 psi, and a temperature of 454 deg C (850 deg F). Pipe diameter was 9 in. and the joints were of the bolted type in which a thin steel ring, serrated on both sides, was inserted between plain flanges. Thin jointing material was interposed between the serrated faces and the flanges. The first intimation of trouble was the onset of a high pitched noise audible over a radius of a quarter of a mile. The noise arose from violent lateral vibration of the serrated ring, which attained an amplitude and persisted for a sufficient number of cycles to produce an extensive system of fatigue cracks that resulted in partial disintegration of the ring. Microscopic examination of the material showed it to be a mild steel of satisfactory quality. The trouble was started by slight leakage, possibly resulting from a relaxation of the interfacial pressure on the joint faces, which eroded away the joint material locally at one face of the serrated ring. This reduced interfacial pressure at the opposite face of the ring, with resultant leakage and erosion of the joint material on this side.

Welded low-carbon steel bomb fins were rejected because of poor weld practice. Visual and metallographic examination revealed that the resistance plug welds that attach the outer skin to the inner spar displayed inadequate weld penetration. Recommended changes to the resistance welding parameters resulted in acceptable welds.

Pipes made of low-carbon Thomas steel had been welded longitudinally employing the carbon-arc process with bare electrode wire made for argon-shielded arc welding. Difficulties were encountered during the cutting of threads because of the presence of hard spots. Microstructural examination showed welding conditions were such that a carburizing atmosphere developed, which led to an increase in carbon content and hardening at certain locations such as terminal bells and lap joints. This explained the processing difficulties during the threading operation.

Handles welded to the top cover plate of a chemical-plant downcomer broke at the welds when the handles were used to lift the cover. The handles were fabricated of low-carbon steel rod; the cover was of type 502 stainless steel plate. The attachment welds were made with type 347 stainless steel filler metal to form a fillet between the handle and the cover. The structure was found to contain a zone of brittle martensite in the portion of the weld adjacent to the low-carbon steel handle; fracture had occurred in this zone. The brittle martensite layer in the weld was the result of using too large a welding rod and too much heat input, melting of the low-carbon steel handle, which diluted the austenitic stainless steel filler metal and formed martensitic steel in the weld zone. Because it was impractical to preheat and postheat the type 502 stainless steel cover plate, the low-carbon steel handle was welded to low-carbon steel plate, using low-carbon steel electrodes. This plate was then welded to the type 502 stainless steel plate with type 310 stainless steel electrodes. This design produced a large weld section over which the load was distributed.

A case-hardened sleeve made of C 15 (Material No. 1.0401) was flattened at two opposing sides and had cracked open at these places, the crack initiating at a face plane. The wall of the sleeve was 9 mm thick, but the flat ends were machined down to 5.5 mm from the outside. The customer had specified a 2 mm case depth and a hardness of at least HRC 55 at a depth of 1.5 mm. An etched cross section of the cracked end showed that the case layer had a depth of 2.3 mm, so that the sleeve was almost through-hardened at the flat ends. While the core material with the full wall thickness had the quench structure of low-carbon steel, the structure of the flattened area consisted of coarse acicular martensite with a small amount of pearlite (quench troostite) and ferrite. Therefore the sleeve was overheated and probably quenched directly from case. To prevent damage, it would have been necessary to have a lower case depth, carburize less deeply, and prevent overheating that causes brittleness and leads also to increased case depth, or else use a fine-grained steel of lower hardenability.