High-level radioactive wastes generated during the processing of nuclear materials are kept in large underground storage tanks made of low-carbon steel. The wastes consist primarily of concentrated solutions of sodium nitrate and sodium hydroxide. Each of the tanks is equipped with a purge ventilation system designed to continuously remove hydrogen gas and vapors without letting radionuclides escape. Several intergranular cracks were discovered in the vent pipe of one such system. The pipe, made of galvanized steel sheet, connects to an exhaust fan downstream of high-efficiency particulate air filters. The failure analysis investigation concluded that nitrate-induced stress-corrosion cracking was the cause of the failure.

Explosive cladding is a viable method for cladding different materials together, but the complicated behavior of materials under ballistic impacts raises the probability of interfacial shear failure. To better understand the relationship between impact energy and interfacial shear, investigators conducted an extensive study on the shear strength of explosively cladded Inconel 625 and plain carbon steel samples. They found that by increasing impact energy, the adhesion strength of the resulting cladding can be improved. Beyond a certain point, however, additional impact energy reduces shear strength significantly, causing the cladding process to fail. The findings reveal the decisive role of plastic strain localization and the associated development of microcracks in cladding failures. An attempt is thus made to determine the optimum cladding parameters for the materials of interest.

This study examines the role of calcium-precipitating bacteria (CPB) in heat exchanger tube failures. Several types of bacteria, including Serratia sp. (FJ973548), Enterobacter sp. (FJ973549, FJ973550), and Enterococcus sp. (FJ973551), were found in scale collected from heat exchanger tubes taken out of service at a gas turbine power station. The corrosive effect of each type of bacteria on mild steel was investigated using electrochemical (polarization and impedance) techniques, and the biogenic calcium scale formations analyzed by XRD. It was shown that the bacteria contribute directly to the formation of calcium carbonate, a critical factor in the buildup of scale and pitting corrosion on heat exchanger tubes.

Material samples collected from failed booster pumps were analyzed to determine the cause of failure and assess the adequacy of the materials used in the design. The pumps had been in service at a power plant, transporting feedwater from a deaerator to a main turbine boiler. Samples from critical areas of the pump were examined using optical and scanning electron microscopy, electrochemical analysis, and tensile testing. Based on microstructure and morphology, estimated corrosion rates, and particle concentrations in the feedwater, it was concluded that cavitation and erosion were the dominant failure mechanisms and that the materials and processes used to make the pumps were largely unsuited for the application.

A 13/16-in. hex socket failed while in use. Analysis (hardness testing, optical and scanning electron microscopy, and EDS) revealed that the socket was made of low carbon steel formed in a powder metallurgy process. A number of flaws were found including nonuniform wall thickness, poor geometric design with sharp corners as stress raisers, and incomplete sintering evidenced by unsintered particles. These were determined to be the primary cause of failure, although inclusions on the fracture surface containing S and Al may have played a role as well.

A controllable pitch propeller (CPP) on a dynamic positioning ship failed after eight months of operation. The CPP design consists of a hollow propeller shaft and a concentrically located pipe that operates inside. The pitch of the propeller blades is controlled hydraulically through the longitudinal displacement of the inner (concentric) pipe. Fractography, microstructural, microhardness, and chemical analyses revealed that the concentric pipe failed due to fatigue. Fatigue cracks initiated along longitudinal welds where wire spacers attach to the external surface of the pipe. The effect of crack-like defects, stress concentration at the weld toe, residual tensile stress, and lack of penetration contributed to a shorter fatigue crack initiation phase and premature failure.

The governor on an aircraft engine failed and upon disassembly of the unit, it was discovered that the retainer for the flyweight pivot pins was broken. The channel-shaped retainer was made of 0.8 mm (0.030 in.) thick 1018 or 1020 steel. The part was plated with copper, which acted as a stop-off during carburizing of the offset, circular thrust-bearing surface surrounding the 16-mm (0.637-in.) diam hole. The bearing surface was case hardened to a depth of 0.05 to 0.1 mm (0.002 to 0.005 in.), then austempered to obtain a minimum hardness of 600 Knoop (1-kg, or 2.2-lb, load). Considerable vibration was created in the installation because of the design of the mechanical device used to transmit power to the governor. The pins were permitted to slide axially a small distance. Analysis (visual inspection, microscopic examination, and ductility measurements) supported the conclusion that failure of the retainer was the result of fatigue caused by vibration in the flyweight assembly. Impact of the pivot pins on the retainer also contributed to failure. Recommendations included redesign of the flyweight assembly, and replacement of the channel-shaped retainer with a spring-clip type of pin retainer.

A large pressure vessel that had been in service as a hydrogen sulfide (H2S) absorber developed cracks and began leaking at a nozzle. The vessel contained a 20% aqueous solution of potassium hydroxide (KOH), potassium carbonate (K2CO3), and arsenic. The vessel wall was manufactured of ASTM A516, grade 70, low-carbon steel plate. A steel angle had been formed into a ring was continuously welded to the inside wall of the vessel. The groove formed by the junction of the lower tray-support weld and the top part of the weld around the nozzle was found to have a crack. Pits and scale near the crack origin were revealed by microscopic examination and cracking was found to be transgranular. Periods of corrosion alternated with sudden instances of cleavage, under a tensile load, along preferred slip planes were interpreted during examination with a microscope. It was concluded that the combination of the residual plus operating stresses and the amount of KOH present would have caused stress corrosion as a result of caustic embrittlement. It was recommended that the tray support should be installed higher on the vessel wall to prevent coincidence of the lower tray-support weld with the nozzle weld.

After only a short time in service, oil-fired orchard heaters made of galvanized low-carbon steel pipe, 0.5 mm (0.020 in.) in thickness, became sensitive to impact, particularly during handling and storage. Most failures occurred in an area of the heater shell that normally reached the highest temperature in service. A 400x etched micrograph showed a brittle and somewhat porous metallic layer about 0.025 mm (0.001 in.) thick on both surfaces of the sheet. Next to this was an apparently single-phase region nearly 0.05 mm (0.002 in.) in thickness. The examination supported the conclusion that prolonged heating of the galvanized steel heater shells caused the zinc-rich surface to become alloyed with iron and reduce the number of layers. Also, heating caused zinc to diffuse along grain boundaries toward the center of the sheet. Zinc in the grain boundaries reacted with iron to form the brittle intergranular phase, resulting in failure by brittle fracture at low impact loads during handling and storage. Recommendation included manufacture of the pipe with aluminized instead of galvanized steel sheet for the combustion chamber.

Two examples concerning fabricated mild steel rotor spiders which failed due to lack of torsional rigidity, probably supplemented by the presence of high internal stress, are described. The machine concerned in the first case was a 3,000 hp three-phase slip-ring motor. In the second case the machine was a 200 kW alternator, direct-driven by a diesel engine running at 750 rpm. Both the foregoing failures reveal the same basic weakness, i.e., insufficient rigidity when subjected to variations or reversals of torque. In the first case, the bars welded to the arms were inadequately supported in a lateral direction, so that excessive stresses of a fluctuating nature were set up in the welds as a result of the frequent load changes that arose in service. This weakness was eliminated when designing the replacement spider. In the second example, failure also arose as a result of deficient torsional rigidity with the consequent development of excessive stresses in the welds at the junctions of the bars with the sleeve, the torque being of a fluctuating character due to the impulses imparted by the engine.

An LNG tanker experienced a fracture of the solid tail shaft, which is a section of the main drive shaft. The tail shaft was made of a forged low-carbon steel. In spite of two ultrasonic inspections, a large defect the size of a football in the center of the shaft was missed. During heat treating following forging, it was surmised that the defect led to the propagation of an internal brittle crack, or clink. A fatigue crack propagated from this origin to the outer surface of the shaft after about a year of service. Finally a last ligament of a few square inches held the shaft together and broke, leading to the separation of the shaft. The cause of failure was fatigue crack initiation and crack growth under reverse bending cyclic stresses. There was no indication that misalignment existed because there was no indication of fretting at the bolt holes in the flange at the end of the shaft. In the case of this shaft, a solution would have been to machine the core of the shaft to remove the brittle material or to use a tubular shaft.

A 230 mm (9 in.) thick casing, fabricated from ASTM 235-55 low-carbon steel, of a 450 Mg (500 ton) extrusion press failed after 27 years of service. Initial visual examination revealed an area that exhibited multiple origins and classic beach marks radiating out approximately 75 mm (3 in.) from the origin along the wall of a hydraulic-oil bleed hole. Investigation with a SEM showed corrosion pits along the bleed hole wall, but oxidation and corrosion prevented review of microfractographic details. Vacuum epoxy encapsulation, sectioning of the bleed hole, and metallographic examination revealed a basic microstructure of pearlite and ferrite with bands of slightly finer pearlite, with a large concentration of inclusion stringers in the area of the fracture origin. Further investigation using an energy-dispersive x-ray analyzer showed high concentrations of sulfur and manganese. Thus, the failure appeared to have resulted from corrosion-assisted fatigue, and the inclusion concentration in the fracture-initiated area indicated that the chemical-composition limits for sulfur and manganese would have greatly exceeded material specifications. A higher quality steel was recommended for the replacement unit to lessen the possibility of such gross inclusion segregation and to improve the fracture toughness of the cylinder.

The fractured end of a piston rod of a hydraulic press failed in line with the leading face of the piston retaining nut. Although the nut apparently had been seated uniformly, the face was polished, indicating that relative movement between it and the piston had taken place. Failure resulted from the culmination of two principal fatigue cracks which developed on approximately parallel planes from the roots of adjacent threads. A longitudinal section through the screw thread on the piston rod showed it had been carburized but not hardened, and that subsequent surface de-carburization to a depth of approximately 0.001 in. had occurred. It was concluded that insufficient tightening, as evidenced by the polish markings, was the main reason for failure, the portion of the rod therefore being subjected to a greater variation of cyclic stress during operation. The presence of the de-carburized layer lowered its resistance to the initiation of a fatigue crack to that of iron, considerably less than the resistance of the mild steel from which the rod was made and well below that shown by the carburized layer.

A fracture mechanics based failure analysis and life prediction of a large centrifugal fan made from low-carbon, medium-strength steel was undertaken following shortcomings in attempts to explain its fatigue life from start stop cycles alone. Measurements of the fracture toughness and flaw size at failure, coupled with quantitative SEM fractography using striation spacing methods, revealed that the cyclic stress amplitudes just prior to failure were much larger than expected, in this particular case. Subsequent improvements in fan design and fabrication have effectively alleviated the problem of slow, high cycle fatigue crack growth, at normal operating stresses in similar fans.

In a main range in a power station, steam was conveyed at a pressure of 645 psi, and a temperature of 454 deg C (850 deg F). Pipe diameter was 9 in. and the joints were of the bolted type in which a thin steel ring, serrated on both sides, was inserted between plain flanges. Thin jointing material was interposed between the serrated faces and the flanges. The first intimation of trouble was the onset of a high pitched noise audible over a radius of a quarter of a mile. The noise arose from violent lateral vibration of the serrated ring, which attained an amplitude and persisted for a sufficient number of cycles to produce an extensive system of fatigue cracks that resulted in partial disintegration of the ring. Microscopic examination of the material showed it to be a mild steel of satisfactory quality. The trouble was started by slight leakage, possibly resulting from a relaxation of the interfacial pressure on the joint faces, which eroded away the joint material locally at one face of the serrated ring. This reduced interfacial pressure at the opposite face of the ring, with resultant leakage and erosion of the joint material on this side.

A bracket which formed part of the carrier of a chain conveyor system used to transport components through a continuous oven fractured. A brittle crack originated on the inside of the right-angled bend, the surface having oxidized subsequently. The remaining portion of the fracture resulted from fatigue. Shallow oxidized regions adjacent to the inside surface of the bend indicated pre-existing cracks. A sulphur print on the edge of the bracket showed the material was rolled from a rimming steel ingot. The general appearance of the fracture, and the fact failure took place where embrittlement had developed following plastic straining and service at a temperature of 260 deg C (500 deg F) suggested that failure resulted from strain-age embrittlement.

A hot rolled, low-carbon steel pot used to melt magnesium alloys leaked, releasing about 35 kg (80 lb) of molten magnesium onto the foundry floor and causing an extensive fire. Due to the fire, the original leakage hole could not be investigated. Samples of the failed pot were polished and etched and were found to be composed of ferrite and pearlite mixtures, as would be expected. However, the sample taken from a location about 75 mm (3 in.) from the hole contained a cluster of unusually large inclusions. By removing the beryllium window from in front of the detector, EPMA spectra were obtained from the inclusions and from the steel matrix. The inclusion spectrum contained primarily iron and oxygen, whereas the matrix spectrum contained primarily iron. X-ray maps were made to show the distribution of iron and oxygen. These results indicated that the inclusions were iron oxide. A similar inclusion at the failure site in the melting pot may have reacted violently with the molten magnesium, causing the leak.

A recuperator used for preheating the combustion air for a rolling mill furnace failed after a relatively short service time because of leakage of the pipes in the colder part. The 6 % chrome steel pipes used for the warmer part connected by means of welding with austenitic electrodes to the unalloyed mild steel pipe of larger diam. Visual inspection showed corrosion and deep, trench-like erosion over the entire circumference of the seam on the side of the thicker mild steel pipe. Examination using the V2-A solution for picral etch showed the microstructure of the unalloyed pipe had become coarse-grained and acicular, and the microstructure of the welding seam had become predominantly martensitic as a result of the mixing of the weld metal with the fused pipe material. The chrome steel pipe had become partially transformed to martensite or bainite at the transition to the weld. Thus, the failure occurred due to typical contact corrosion wherein the alloyed welding seam represented the less noble electrode. The martensitic structure may have contributed to the failure as well. Due to the typical nature of the failure, no recommendations were made.

Wet natural gas was dried by being passed through a carbon steel vessel that contained a molecular-sieve drying agent. The drying agent became saturated after several hours in service and was regenerated by a gas that was heated to 290 to 345 deg C in a salt-bath heat exchanger. The tee joint in the piping between the heat exchanger and the sieve bed failed after 12 months. A hole in the tee fitting and a corrosion product on the inner surface of the pitting was revealed by visual examination. Iron sulfide was revealed by chemical analysis of the scale which indicated hydrogen sulfide attack on the carbon steel. The presence of oxygen was indicated by the carbon and sulfur found in the scale on the piping and in the sieves indicated that oxygen combined with moisture produced conditions for attack of hydrogen sulfide on carbon steel. Turbulence with some effect from the coarse grain size was interpreted to have contributed. The piping material was changed from carbon steel to AISI type 316 stainless steel as it is readily weldable and resistant to corrosion by hydrogen sulfide.

When a large LPG low-carbon steel storage tank was put into service for the first time and filled beyond the proof testing level, a brittle fracture crack initiated at a fillet weld between a stiffener ring and the wall. The crack propagated to a length of 5.5 m and arrested. Analysis showed that the plates satisfied the criteria of BS 4741. It was concluded that the cause of crack initiation was the lack of a mouse hole at the junction between the stiffening ring and the wall of the tank. The tank was repaired and put back in service. When it was filled beyond the proof test level, again a brittle crack was initiated at a horizontal weld defect and propagated vertically, destroying the tank and the liquefaction plant. The initiation site was a thumbnail elliptical crack in a horizontal weld, having a depth of 1.5 mm, and a length of 4.5 mm. This showed that as late the mid-1970s, misunderstanding of brittle fracture led to the wrong design and construction of an LPG storage tank. The best design specification is to use a correlation between LAST, the Lowest Anticipated Service Temperature, and the DBTT measured by either Charpy tests or DTT.