High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.

Gas turbines and other types of combustion turbomachinery are susceptible to hot corrosion at elevated temperatures. Two such cases resulting in the failure of a gas turbine component were investigated to learn more about the hot corrosion process and the underlying failure mechanisms. Each component was analyzed using optical and scanning electron microscopy, energy dispersive spectroscopy, mechanical testing, and nondestructive techniques. The results of the investigation provide insights on the influence of temperature, composition, and microstructure and the contributing effects of high-temperature oxidation on the hot corrosion process. Preventative measures are also discussed.

The failure of T12 reheater tubes that had been in service for only 3000 h was investigated. The thickness of the tubes was visibly reduced by heavy oxidation corrosion on the inner and outer walls. The original pearlite substrate completely decomposed. Uniform oxide scale observed on the inner wall showed obvious vapor oxidation corrosion characteristics. Corrosion originated in the grain boundary, and selective oxidation occurred due to ion diffusion in the substrate. The layered oxide scale on the inner wall is related to the different diffusion rates for different cations. Exposure to high temperature corrosive flux accelerated the corrosion on the outer wall. Microstructure degradation and the corrosion characteristics observed indicate that the tubes failed primarily because of overheating, which is confirmed by calculations.

A sleeve-shaped fire shield that operates inside one of two burner trains in an oil and gas processing unit ruptured after 15 y of service. A detailed analysis was conducted to determine how and why the sleeve failed. The investigation included visual inspection, chemical and gas analysis, mechanical property testing, stereomicroscopy, and metallographic examination. The fire sleeves are fabricated from 3-mm thick plate made of Incoloy 800 rolled into 540-mm diam sections welded along the seam. Three such sections are joined together by circumferential welds to form a single 2.8 m sleeve. The findings from the investigation indicated that internal oxidation corrosion, driven by high temperatures, was the primary cause of failure. Prolonged exposure to temperatures up to 760 °C resulted in sensitization of the material, making it vulnerable to grain boundary attack. This led to significant deterioration of the grain boundaries, causing extensive grain loss (grain dropping) and the subsequent thinning of sleeve walls. Prior to failure, some portions of the sleeve were only 1.6 mm thick, nearly half their original thickness.

During disassembly of an engine that was to be modified, a fractured turbine blade was found. When the fracture was examined at low magnification, it was observed that a fatigue fracture had originated on the concave side of the leading edge and had progressed slightly more than halfway from the leading edge to the trailing edge on the concave surface before ultimate failure occurred in dynamic tension. Analysis (including visual inspection, SEM, and 250x/500x micrographic examination) supported the conclusions that the blades failed due to thermal fatigue. Recommendations included application of a protective coating to the blades, provided the coating was sufficiently ductile to avoid cracking during operation to prevent surface oxidation. Such a coating would also alleviate thermal differentials, provided the thermal conductivity of the coating exceeded that of the base metal. It was also determined that directionally solidified blades could minimize thermal fatigue cracking by eliminating intersection of grain boundaries with the surface. However, this improvement would be more costly than applying a protective coating.

Cartridge-pneumatic starter systems are used on military aircraft. In the cartridge mode used for alert starts, the starter turbine is driven by hot gases produced through the controlled burning of a solid propellant cartridge within a closed chamber (the breech chamber/cartridge chamber assembly). Premature failures of steel breech chambers have been prevalent enough to cause serious concern. The breech chamber is fabricated from a 4340 Ni-Cr-Mo steel forging heat treated to a hardness in the range HRC 40 to 45. The failures have taken several forms, including fracture and unzipping of the chamber dome, burn-through of the dome, and shearing of bayonet locking lugs. Factors identified as significant in the failures are the pressure developed in the chamber and internal corrosion of the chamber in an environment that can produce stress-corrosion cracking. The interior configuration of the chamber and the stress distribution also have a bearing upon the failure modes. Several failures are reviewed to illustrate the problems.

Failure occurred in two TOW flight missile cases in unrelated launchings. After an extensive investigation, it was concluded that stress corrosion was the most likely cause of failure. Subsequent to this conclusion, inner wall softening was observed in an unfired TOW flight missile case. Questions arose as to how the softening occurred and whether or not it had contributed to the failures. This report contains the results of a study which resolved that inner wall softening could not have been present in the failed missile cases.

Aluminide-coated and uncoated IN-713 turbine blades were returned for evaluation after service in a marine environment because of severe corrosion. Based on service time, failure of these blades by corrosive deterioration was considered to be premature. Analysis (visual inspection, 2.7x micrographic examination on sections etched with ferric chloride and hydrochloric acid in methanol) supported the conclusions that the blades failed by hot-corrosion attack. Variation in rate of attack on coated blades was attributed to variation in integrity of the aluminide coating, which had been applied in 1966, when these coatings were relatively new. It is evident that maintaining the integrity of a protective coating could significantly increase the life of a nickel-base alloy blade operating in a hot and corrosive environment.

The circumstances surrounding the in-service failure of a cast Ni-base superalloy (Alloy 713LC) second stage turbine blade and a cast and coated Co-base superalloy (MAR-M302) first stage air-cooled vane in two turbine engines used for marine application are described. An overview of a systematic approach, analyzing the nature of degeneration and failure of the failed components, utilizing conventional metallurgical techniques, is presented. The topographical features of the turbine blade fracture surface revealed a fatigue-induced crack growth pattern, where crack initiation had taken place in the blade trailing edge. An estimate of the crack-growth rate for the stage II fatigue fracture region coupled with the metallographic results helped to identify the final mode of the turbine blade failure. A detailed metallographic and fractographic examination of the air-cooled vane revealed that coating erosion in conjunction with severe hot-corrosion was responsible for crack initiation in the leading edge area.

Cracking was found in the heads on large Yankee dryers, large, cylindrical, rotating, pressurized, high-temperature, cast iron pressure vessels (ASME Boiler and Pressure Vessel Code Section VIII, Rules for Construction of Pressure Vessels), used to remove moisture from sheets of tissue paper during manufacturing. The typical components consist of a cast iron shell, two cast iron concave heads, and a large cast iron internal center stay attached to journals. The heads are attached to the shell and center stay with high-strength bolts. FEA and metallurgical investigation supported the conclusion that the cracking was caused by an unexpected type of load placed on the machine, namely corrosion product buildup at the head/shell interface causing the joint to displace open. It was also found that compressive bolting loads could slightly open the head/shell interface at the periphery. Recommendations included design changes in the head/shell joint, and detailed preventive maintenance inspection procedures were also suggested.

Pendant-style reheater, constructed of ASME SA-213, grade T-11, steel ruptured. A set of four tubes, specified to be 64 mm OD x 3.4 mm minimum wall thickness was examined. A small quantity of loose debris was removed from the inside of one of the tubes. The major constituent was revealed by EDS analysis of the debris to be iron with traces of phosphorus, manganese, sodium, calcium, copper, zinc, potassium, silicon, chromium, and molybdenum. Thus the debris was interpreted to be the scale from ID of the tube with boiler feedwater chemicals from the attemperation spray. The likely cause of failure was concluded to be exfoliation of the scale from the ID surface of the tube. Creep failures were interpreted to be caused by localized temperatures higher than the maximum service temperature. Replacement of the affected tubes was recommended. Inspection of the tubes by radiography to find the circuits with the greatest accumulation of debris and replacing them as necessary was recommended on an annual basis.

Severe pitting corrosion of a carbon steel tube was observed in the air preheater of a power plant, which runs on rice straw firing. Approximately 1450 tubes were removed from Stage 3 of the preheater (air inlet and flue gas outlet) due to corrosion and local bursting. Samples from Stage 2 (where corrosion was low) and Stage 3 (severe corrosion) were taken and subjected to visual inspection, SEM, x-ray diffraction, microhardness measurement, and chemical and microstructural analysis. It was determined that extended non-operation of the plant resulted in the settlement of corrosive species on the tubes in Stage 3. The complete failure of the tube occurred due to diffusion of these elements into the base metal and precipitation of potassium and chlorine compounds along the grain boundaries, with subsequent dislodging of grains. The nonmetallic inclusions acted as nucleating sites for local pitting bursting. Nonuniform heat transfer in Stage 3 operation accelerated the selective corrosion of front-end tubes. The relatively high heat transfer in this stage resulted in condensation of some corrosive gases and consequent corrosion. Continuous operation of the plant with some precautions during assembly of the tubes reduced the corrosion problem.

The top tube of a horizontal superheater bank in the reheat furnace of a steam generator ruptured after seven years in service. The rupture was found to have occurred in the ferritic steel tubing (2.25Cr-1Mo steel (ASME SA-213, grade T-22)) near the joint where it was welded to austenitic stainless steel tubing (type 321 stainless steel (ASME SA-213, grade TP321H)). The surface temperature of the tube was found to be higher than operating temperature in use earlier. The ferritic steel portion of the tube was found to be longitudinally split and heavily corroded in the region of the rupture. A red and white deposit was found on the sides and bottom of the tube in the rupture area. The deposit was produced by attack of the steel by the alkali acid sulfate and had thinned the tube wall. It was concluded that rupture of the tube had occurred due to thinning of the wall by coal-ash corrosion. The thinned tubes were reinforced by pad welding. Type 304 stainless steel shields were welded to the stainless steel portions of the top reheater tubes and were held in place about the chromium-molybdenum steel portions of the tubes by steel bands.

An aftercooler was of conventional design and fitted with brass tubes through which cooling-water circulated. Air at 100 psi pressure was passed over the outsides of the tubes, entering the vessel near to the upper tubeplate on one side and leaving it by a branch adjacent to the lower tubeplate on the opposite side. After a mishap, the paint had been burned off the upper half of the shell. Internally, most of the tubes were found to be twisted or bent. The casing of the pump used to circulate the cooling water was also found to be cracked after the mishap. All the evidence pointed to the probability that a fire had occurred within the vessel. Some months before the failure, one of the tubes situated towards the center of the nest developed a leak. Owing to the difficulty of inserting a replacement tube, the defective one was scaled by means of a length of screwed rod fitted with nuts and washers at each end. This assembly became loose, thereby allowing air under pressure to enter the waterside of the cooler and expel the water, leading to overheating and ultimately to the damage described.

A transition duct was part of a 100-MW power-generation gas turbine. The duct was fabricated from several panels of a modified nickel alloy, IN-617. After six years of operation, two such ducts failed during the next two years, causing outages. Failure was in the form of a total collapse of the duct. Carbides and carbonitrides were found in all of the transitions examined. Investigation supported the conclusion that failure was caused by oxidation, oxide penetration, and oxide spallation which caused thinning of the duct wall. It was felt that the high oxygen and nitrogen partial pressures of the gases within the duct, combined with the high temperatures, facilitated nitrogen pickup. No recommendations were made.

Turbine buckets in a 37.5-MW gas turbine made of Udimet 500 superalloy failed in service. The power plant was located 1 km (0.6 miles) from the Pacific Ocean and operated on No. 2 diesel fuel, which was supplied by tanker ship. Turbine bucket failures occurred on three units after 2500 to 6400 h of operation. Investigation (visual inspection, metallographic examination, and stress analysis) supported the conclusion that the differing microstructure of the airfoil resulted in changes in mechanical properties. Because normal operation includes cycling of loads and temperatures, the shroud tip fractured due to thermomechanical fatigue in its degraded state. Recommendations included special chromium or silicon-rich coating to minimize corrosion in gas turbines operating in a marine environment with operating temperatures in the range of type 2 corrosion (650 to 750 deg C, or 1200 to 1380 deg F). Additionally, it was suggested that fuel delivery, handling, and treatment be high quality, to maintain fuel contamination within design limits, and inlet air filtration must be designed for the coastal site. Also, changing the bucket tip by increasing its thickness and changing the casting technique would reduce the stress and make the design more tolerant of corrosion.

The phenomenon of on-load corrosion is directly associated with the production of magnetite on the water-side surface of boiler tubes. On-load corrosion may first be manifested by the sudden, violent rupture of a boiler tube, such failures being found to occur predominantly on the fire-side surface of tubes situated in zones exposed to radiant heat where high rates of heat transfer pertain. In most instances, a large number of adjacent tubes are found to have suffered, the affected zone frequently extending in a horizontal band across the boiler. In some instances, pronounced local attack has taken place at butt welds in water-wall tubes, particularly those situated in zones of high heat flux. To prevent on-load corrosion an adequate flow of water must occur within the tubes in the susceptible regions of a boiler. Corrosion products and suspended matter from the pre-boiler equipment should be prevented from entering the boiler itself. Also, it is good practice to reduce as far as possible the intrusion of weld flash and other impedances to smooth flow within the boiler tubes.

The first-stage blades in a model 501D5 gas turbine had 16 cooling holes. After 32,000 h of service, the blades exhibited cracking at the cooling holes. The blade material was wrought Udimet 520 alloy, with nominal composition of 57Ni-19Cr-12Co-6Mo-1W-2Al-3Ti-0.05C-0.005B. The cooling holes' surface was not coated. Investigation supported the conclusions that the cracking at the cooling holes was due to grain-boundary oxidation and nitridation at the cooling hole surface, embrittlement and loss of local ductility of the base alloy, temperature gradient from the airfoil surface to the cooling holes, which led to relatively high thermal stresses at the holes located at the thicker sections of the airfoil, and stress concentration of 2.5 at the cooling hole and the presence of relatively high total strain (an inelastic strain of 1.2%) at the cooling hole surface. Recommendations include applying the specially designed methods given in this case study to estimate the metal temperature and stresses in order to predict the life of turbine blades under similar operating conditions.

The intermediate pressure (IP) turbine of a thermal generating station is driven by steam from the boiler's reheater. On one particular IP turbine, a thick deposit was found on the insides of the rotor blade shrouds in two instances two years apart. The source of the deposits was not known; bulk chemical analysis had simply shown that iron was a major component. Optical microscopy and electron microprobe analysis were used to identify the deposits. In the first instance, the deposit was found to be debris that was left in the reheater tubes during boiler modification and swept to the turbine by the steam. There were still some of these debris particles present when the incident two years later was investigated but generally the second deposit was found to be of two layer oxide particles which were shown to have spalled from 2-14% chromium reheater tube surfaces.

The self-powered flux detectors used in some nuclear reactors are Pt or V-cored co-axial cables with MgO as an insulator and Inconel 600 as the outer sheath material. The detectors are designed to operate in a He atmosphere; to maximize the conduction of heat (generated from the interaction with gamma radiation) and to prevent corrosion. A number of failures have occurred over the years because of a loss of the He cover gas in the assembly. This has resulted in either acid attack on the Inconel 600 sheath in a wet environment or gaseous corrosion in a dry environment. In the latter case, nitriding and embrittlement occurred at temperatures as low as 300 to 400 deg C (determined from an examination of the oxidation of the Zircaloy-2 carrier rod on which the detectors were mounted). Recent results are described and discussed in terms of the oxidation and nitriding kinetics of Zircaloy-2 and Inconel 600, respectively.