Brief overheating of the 89 mm OD 6.4 mm wall thickness titanium heater tubes (ASTM B337, grade 2) was caused by a flow stoppage in a leach heater. Blue-tinted areas and patches of flaky white, yellow, and brown oxide scale was revealed on visual examination. It was disclosed by subjecting the overheated tube to a flattening test that the tube no longer met ASTM B 337 specifications. Large grain size and numerous needlelike hydride particles were disclosed in the microstructure of the overheated tube. Heating to approximately 815 deg C was revealed by the presence of the flaky oxide and increased grain size. Hydrogen and oxygen absorption was revealed by the presence of hydrides and the shallow surface embrittlement and thus susceptibility to cracking at ambient temperatures was observed. It was concluded that the titanium tubes were embrittled due to overheating the tubes and the severe surface embrittlement resulted from oxygen absorption which made the surface layers susceptible to cracking under start up and shutdown. Replacement tubes made of a heat-resistant alloy (e.g., Hastelloy C-276) were recommended.

A hook on a two-leg chain (each 13 mm diam, included angle 60 deg) failed at the junction of the eye and shank while lifting a 4990 kg load. The diam of the hook at this junction was approximately 22 mm. Light intergranular oxidation at the surface on the side of the hook where cracking started was revealed by visual examination of the fracture region. Almost 50% of the fracture surface was found to contain beach marks (indicative of fatigue failure) while the remainder contained cleavage facets. A medium-coarse acicular as-forged structure was revealed by metallographic examination and the metal was showed by chemical analysis to be semikilled 1015 steel. The fatigue fracture was concluded to have initiated in the intergranular oxidation region and the failure of the hook was contributed by the poor fatigue and impact properties of the forged structure. As a corrective measure, the chain-sling hook was replaced with one made of normalized, fully killed, finegrain 1020 steel.