This article reviews various rapid prototyping (RP) processes such as stereolithography, powder sintering, hot melt extrusion, sheet lamination, solid ground curing, and three-dimensional printing. It discusses the various material prototypes produced by RP technology. The list of materials includes particulate and fiber-reinforced polymers, ceramic-matrix composites, and metal-matrix composites. The article also provides information on freeform-fabrication techniques for composite part lay-up.