Search Results for steam pressure

Laboratory-scale tests are frequently used to generate understanding of high-temperature oxidation phenomena, to characterise and rank the performance of existing, future materials and coatings. Tests within the laboratory have the advantage of being well controlled, monitored and offer the opportunity of simplification which enables the study of individual parameters through isolating them from other factors, such as temperature transients. The influence of pressure on the oxidation of power plant materials has always been considered to be less significant than the effects of temperature and Cr content, but still remains a subject of differing opinions. Experimental efforts, reported in the literature, to measure the influence of steam pressure on the rate of oxidation have not produced very consistent or conclusive results. To examine this further a series of high pressure steam oxidation exposures have been conducted in a high pressure flowing steam loop, exposing a range of materials to flowing steam at 650 and 700 °C and pressure of 25, 50 and 60 bar. Data is presented for ferritic-martensitic alloys showing the effect of increasing pressure on the mass change and oxide thickness of these alloys in the flowing steam loop. In addition the effect observed on the diffusion of aluminium from an aluminised coating in these alloys is also presented and the differences in the extent of diffusion discussed.

Traditional laboratory steam experiments are conducted at ambient pressure with water of variable chemistry. In order to better understand the effect of steam pressure and water chemistry, a new recirculating, controlled chemistry water loop with a 650°C autoclave was constructed. The initial experiments included two different water chemistries at 550° and 650°C. Two 500-h cycles were performed using oxygenated (OT, pH ~9 and ~100 ppb O 2 ) or all-volatile treated (AVT, pH ~9 and <10 ppb O 2 ) water conditions at each temperature. Coupons exposed included Fe-(9-11)%Cr and conventional and advanced austenitic steels as well as shot peened type 304H stainless steel. Compared to ambient steam exposures, the oxides formed after 1,000 h were similar in thickness for each of the alloy classes but appeared to have a different microstructure, particularly for the outer Fe-rich layer. An initial attempt was made to quantify the scale adhesion in the two environments.

The rising global energy demand has led to a surge in the construction of high-efficiency power plants with advanced steam parameters. National and international projects indicate that fossil fuels will continue to be the primary source of power generation in the coming years, despite significant efforts and progress in utilizing alternative energy sources. Economic pressures and climate protection concerns necessitate more cost-efficient and environmentally sustainable energy production. Achieving this requires reducing specific fuel and heat consumption per kilowatt-hour, making it essential to improve the efficiency of new power plants beyond those commissioned in Germany between 1992 and 2002. While new construction and process innovations contribute to efficiency gains, the primary factors driving improvement are increased steam pressure and temperature. Current design parameters include steam temperatures of 605 °C (live steam) and 625 °C (hot reheat steam), along with pressures of 300 bar (live steam) and 80 bar (hot reheat steam), which have become critical for obtaining building and operating licenses in Germany. However, the European Creep Collaborative Committee’s (ECCC) 2005 reassessment of the creep strength of steel T/P92 (X10CrWMoVNb9-2) has placed limitations on further increasing steam temperatures beyond 625 °C.

Improving power plant efficiency through supercritical steam pressures and very high steam temperatures up to 700°C and beyond is an effective approach to reducing fuel consumption and CO2 emissions. However, these extreme steam temperatures necessitate the use of nickel-base alloys in the high-pressure/intermediate-pressure turbine sections requiring very large component sections that cannot be met by steels. Saarschmiede, involved in manufacturing large components for the power generation industry and research programs on advanced 9-12% chromium steels, has extensive experience producing nickel and cobalt-base alloy forgings for applications like aircraft engines, aerospace, land-based gas turbines, and offshore. This paper reports on the manufacturing and testing of large-section forgings made from candidate nickel-base alloys like 617 and 625 for high-pressure/intermediate-pressure turbine components in power stations operating at 700°C and higher steam temperatures.

Following the successful completion of a 15-year effort to develop and test materials that would allow advanced ultra-supercritical (A-USC) coal-fired power plants to be operated at steam temperatures up to 760°C, a United States-based consortium has been working on a project (AUSC ComTest) to help achieve technical readiness to allow the construction of a commercial scale A-USC demonstration power plant. Among the goals of the ComTest project are to validate that components made from the advanced alloys can be designed and fabricated to perform under A-USC conditions, to accelerate the development of a U.S.-based supply chain for key A-USC components, and to decrease the uncertainty for cost estimates of future commercial-scale A-USC power plants. This project is intended to bring A-USC technology to the commercial scale demonstration level of readiness by completing the manufacturing R&D of A-USC components by fabricating commercial scale nickel-based alloy components and sub-assemblies that would be needed in a coal fired power plant of approximately 800 megawatts (MWe) generation capacity operating at a steam temperature of 760°C (1400°F) and steam pressure of at least 238 bar (3500 psia).The A-USC ComTest project scope includes fabrication of full scale superheater / reheater components and subassemblies (including tubes and headers), furnace membrane walls, steam turbine forged rotor, steam turbine nozzle carrier casting, and high temperature steam transfer piping. Materials of construction include Inconel 740H and Haynes 282 alloys for the high temperature sections. The project team will also conduct testing and seek to obtain ASME Code Stamp approval for nickel-based alloy pressure relief valve designs that would be used in A-USC power plants up to approximately 800 MWe size. The U.S. consortium, principally funded by the U.S. Department of Energy and the Ohio Coal Development Office under a prime contract with the Energy Industries of Ohio, with co-funding from the power industry participants, General Electric, and the Electric Power Research Institute, has completed the detailed engineering phase of the A-USC ComTest project, and is currently engaged in the procurement and fabrication phase of the work. This paper will outline the motivation for the effort, summarize work completed to date, and detail future plans for the remainder of the A-USC ComTest project.

The acceptance of materials for long-term, safety-critical power generation applications requires multiple testing stages and data generation. Initial screening involves short-term exposures under simplified, constant atmospheres and temperatures, which can eliminate unsuitable materials but fail to distinguish between those with broadly acceptable properties. Subsequent pilot plant testing, costing over £100K for month-long exposures, is typically required. An intermediate laboratory testing step that better replicates in-service conditions would offer a cost-effective approach to material selection and lifetime prediction. For steam oxidation degradation, key experimental parameters—such as water chemistry, pressure, steam delivery, and flow rate—must be tailored to produce oxide scale morphologies similar to those observed in actual plant conditions. This study examines the effects of these parameters through steam exposure tests on ferritic (P92), austenitic (Esshete 1250), and superalloy (IN740) materials. Results indicate that oxidation rates vary with dissolved oxygen levels in feed water, increasing for austenitic materials and decreasing for ferritic materials, while also influencing spallation tendencies. Additionally, steam pressure and delivery methods impact oxidation rates and scale morphology. A comparison with service-exposed materials revealed that traditional oxide scale morphologies were not adequately replicated, whereas cyclic oxidation tests provided a closer match to service-grown scales.

The efficiency of power plants is depending on the steam temperature and/or the steam pressure. Efficiency increasing from 35% to 42-45% require increasing of the steam temperature over 600°C and the pressure over 26 MPa. According to the designer opinion it is not profitable to use classical low alloy creep resistant steels 16Mo3, 13CrMo4-5 or 10CrMo9-10 for membrane waterwall construction for these service condition. New modified low alloy creep resistance T23 and T24 (7CrMoVTiB10-10) steels were developed for membrane waterwalls. Welding of these steels with small thickness (around 6.3 mm) should be enabled without preheating and post weld heat treatment (PWHT) due to the lower carbon content below 0.1%. High creep rupture strength (CRS) values are achieved by Ti, N and B elements alloyed to T24 steel. The original expectation that the welding small thickness without preheating was early overcome and was wrong. According to the present experience the T24 steel is welded with preheating at 150-250°C depending on the wall thickness and welded joint toughness in order to achieve required hardness and impact toughness values. Opinions on the T24 welded joints post weld heat treatment (PWHT) requirements are still inconsistent. Especially the membrane waterwalls of the supercritical power plants are still produced without PWHT.

Constricted steam oxidation resistance and finite microstructural stability limits the use of 9 - 12 wt.-% chromium ferritic-martensitic steels to steam temperatures of about 620 °C. Newly developed 12 wt.-% Cr steels are prone to Z-phase precipitation, which occurs at the expense of the strengthening precipitates, and therefore suffer an accelerated decline in strength during longterm operation. While the concept of ferritic-martensitic chromium steels thus seems to hit technological limitations, further improvement in steam power plant efficiency necessitates a further increase of steam pressure and temperature. Furthermore increasing integration of intermitting renewable energy technologies in electrical power generation poses a great challenge for supply security, which has to be ensured on the basis of conventional power plant processes. Besides improved efficiency for resource preservation, load flexibility, thermal cycling capability and downtime corrosion resistance will play key roles in the design of tailored materials for future energy technology. Under these preconditions a paradigm shift in alloy development towards improvement of cyclic steam oxidation and downtime corrosion resistance in combination with adequate creep and thermomechanical fatigue strength seems to be mandatory. The steam oxidation, mechanical and thermomechanical properties of fully ferritic 18 - 24 wt.-% chromium model alloys, strengthened by the precipitation of intermetallic (Fe,Cr,Si)2(Nb,W) Laves phase particles, indicate the potential of this type of alloys as candidate materials for application in highly efficient and highly flexible future supercritical steam power plants.

The construction of highly efficient Ultra Supercritical (USC) boiler systems to operate with steam temperatures up to 760°C (1400°F) and with steam pressures up to 34.5 MPa (5000 psi) will require the use of advanced high temperature, high strength materials. As part of a 5-year project to qualify advanced boiler materials for USC power plants, a number of austenitic materials have been selected for further development and use in USC boiler systems, including alloys 230, 740, CCA 617, HR6W, and Super 304H. In one task of this project, boiler fabrication guidelines appropriate for the use of these alloys were investigated. Because it is recognized that cold formed and mechanically strained austenitic materials can degrade in material creep strength, a study to investigate the limits of strain and temperature exposure for the USC alloys was undertaken. An objective of this work was to determine for each USC alloy a relationship between the level of cold strain and the conditions of time and temperature that will cause recrystallization and significant microstructural change. The ultimate goal of this work was to determine limits of strain, due to cold forming, that can be tolerated before heat treatment is required, similar to those limits provided for the austenitic materials (e.g., 300-series stainless steels, alloy 800H) in Table PG-19 in Section I of the ASME Boiler and Pressure Vessel Code. This paper will describe the technical approach for 1) preparing specimens having discrete cold strains ranging from about 1 to 40 percent, 2) exposing these strained specimens for selected times at various elevated temperatures, 3) identifying the onset of recrystallization in the microstructures of the exposed specimens, and 4) establishing a useful engineering method to predict conditions for the onset of recrystallization in the USC alloys using the experimental results.

The construction of highly efficient, coal-burning Ultra Supercritical (USC) boiler systems to operate with steam temperatures up to 760°C (1400°F) and with steam pressures up to 35 MPa (5000 psi) will require the use of advanced high temperature, high strength materials. As part of a 5-year project to develop boiler materials for advanced USC power plants, principally funded by the Department of Energy (U.S. DOE No. DE-FG26-01NT41175) and the Ohio Coal Development Office (OCDO No. D-00-20), six alloys have been selected for development and implementation in USC boiler systems. The selected alloys are Haynes 230 (produced by Haynes International), Inconel 740 (produced by Special Metals Corp.), CCA 617 (produced by Krupp VDM GMBH), HR6W, Super 304H, and SAVE 12 (all three produced by Sumitomo Metal Industries). In this project, one of the goals has been to establish boiler fabrication guidelines for the use of these alloys. The principal objectives have been 1) to understand the behavior of these materials when subjected to conventional boiler fabrication processes, 2) to determine the thermomechanical treatments or other actions necessary to restore material properties which might degrade due to fabrication operations, and 3) to investigate prototypical manufacturing operations for producing both thick wall components (such as headers) and thin wall components (such as superheaters) from the USC alloys. This paper discusses some of the characteristics of these alloys, describes the technical approach used to assess their fabricability, and presents some of the results that have thus far been generated in this task effort.

The “Cool Earth-Innovative Energy Technology Program,” launched by the Japanese government in March 2008, aims to significantly reduce global greenhouse gas emissions. Among the 21 selected technologies is the Advanced Ultra Super Critical (A-USC) pressure power generation, which targets the commercialization of a 700°C class pulverized coal power system with a power generation efficiency of 46% by around 2015. As of 2004, Japan's pulverized coal power plant capacity reached 35 GW, with the latest plants achieving a steam temperature of 600°C and a net thermal efficiency of approximately 42% (HHV). Older plants from the 1970s and early 1980s, with steam temperatures of 538°C or 566°C, are nearing the need for refurbishment or rebuilding. A case study on retrofitting these older plants with A-USC technology, which uses a 700°C class steam temperature, demonstrated that this technology is suitable for such upgrades and can reduce CO 2 emissions by about 15%. Following this study, a large-scale development of A-USC technology began in August 2008, focusing on developing 700°C class boiler, turbine, and valve technologies, including high-temperature material technology. Candidate materials for boilers and turbine rotor and casing materials are being developed and tested. Two years into the project, useful test results regarding these candidate materials have been obtained, contributing to the advancement of A-USC technology.

The capacity of PC power plants in Japan rose to 35GW in 2004. The most current plants have a 600 deg-C class steam temperature and a net thermal efficiency of approximately 42% (HHV). Older plants, which were built in the ‘70s and early ‘80s, will reach the point where they will need to be rebuilt or refurbished in the near future. The steam temperatures of the older plants are 538 deg-C or 566 deg-C. We have done a case study on the refurbishment of one of these plants with the advanced USC technology that uses a 700 deg-C class steam temperature in order to increase the thermal efficiency and to reduce CO 2 emissions. The model plant studied for refurbishing has a 24.1MPa/538 deg-C /538 deg-C steam condition. We studied three possible systems for the refurbishing. The first was a double reheat system with 35MPa/700 deg-C /720 deg-C /720 deg-C steam conditions, the second one was a single reheat 25MPa/700 deg-C/720 deg-C system, the last one was a single reheat 24.1MPa/610 deg-C/720 deg-C system. In addition to these, the most current technology system with 600 deg-C main and reheat temperatures was studied for comparison. The study showed that the advanced USC Technology is suitable for refurbishing old plants. It is economical and environmentally-friendly because it can reuse many of the parts from the old plants and the thermal efficiency is much higher than the current 600 deg-C plants. Therefore, CO 2 reduction is achieved economically through refurbishment.

Since the 1990s, the power plant market has shifted towards more flexible and efficient Steam Power Plants (SPPs) with fewer service inspections and lifetimes of ≥200,000 hours, including combined-cycle applications. This shift has driven efforts to enhance both design and materials. One approach is the installation of super-critical SPPs with live steam temperatures of T ≥580°C and optimized steam cycles. Siemens Power Generation is leveraging its experience with Ultra Super Critical SPPs from the 1950s, which operated at up to 650°C/320bar, to develop modern turbo-set solutions using new technology from the past decade. Proven design features, such as material combinations (welded or bolted rotors and casings) and advanced cooling techniques, are being adapted for current use. Past limitations with austenitic materials have been reassessed, leading to the conclusion that improved materials are necessary for today's USC SPPs. Global material development programs, such as COST in Europe, are focusing on new 10%Cr martensitic steels, which offer cost-effectiveness and operational flexibility. Additionally, joint R&D projects are underway to evaluate the long-term creep properties and service behavior of new 10%CrMoV steels for 600/620°C applications. These projects aim to ensure the materials can withstand relevant loading conditions and multiaxial stresses.

In fossil-fired boilers, combustion-generated thermal energy transfers to the working fluid via exchanger tubes, where an internal oxide layer forms over time, reducing thermal conductivity and raising metal temperatures. This self-activating process accelerates creep damage, significantly shortening component lifespan. Boiler design codes set Maximum Allowable Stresses based on mechanical properties, primarily creep resistance, but oxidation effects are only indirectly considered through “design temperature” selection—an approach inadequate for next-generation high-performance boilers with increasingly severe steam conditions. This paper highlights the need to integrate oxidation behavior into the design of advanced heat-exchanging components by examining the impact of steam oxidation on tube lifespan, including oxide layer growth, metal loss, temperature rise, and reduced creep rupture time, with thermal flux effects illustrated through examples. It also compares the behavior of two 9-12Cr% steels: Grade 92, known for strong creep resistance, and VM12, which offers superior oxidation resistance. Additionally, it proposes a revised “design temperature” expression incorporating oxidation resistance performance indices and exchanger thermal characteristics. The study concludes by emphasizing the need for further research into oxidation kinetics, thermal properties, and oxide layer exfoliation mechanisms.

In response to the need to reduce carbon dioxide gas emissions, Japan has been actively researching 700°C-class thermal power plants with a focus on improving overall plant efficiency. This technological advancement is fundamentally grounded in advanced materials development, encompassing the creation of high-strength alloys, fireside corrosion-resistant materials, and steamside oxidation-resistant alloys. A significant challenge emerged as some of the developed materials fell outside the scope of existing domestic technical standards. Moreover, the potential failure modes for advanced ultra-supercritical (A-USC) components operating at 700°C were anticipated to differ substantially from those observed in traditional ultra-supercritical (USC) components at 600°C. Consequently, researchers systematically examined and analyzed the potential failure modes specific to 700°C A-USC components, using these insights to establish comprehensive performance requirements. The research initiative, which commenced in June 2006, was strategically planned to develop a draft technical interpretation by March 2011. This paper provides a detailed overview of the investigative process, encompassing the comprehensive analysis of failure modes, the derivation of performance requirements, and the progression toward developing a new technical interpretation framework for high-temperature power plant components.

In flexible operation with increased number of startup, shutdown, and load fluctuations, thermal fatigue damage is exacerbated along with existing creep damage in power plant pipe and pressure vessels. Recently, cracks were found in the start-up vent pipe branching from the reheat steam pipe within a heat recovery steam generator(HRSG) of J-class gas turbine, occurring in the P92 base material and repair welds. This pipe has been used at the power plant for about 10 years. Microstructural analysis of the cross-section indicated that the cracks were primarily due to thermal fatigue, growing within the grains without changing direction along the grain boundaries. To identify the damage mechanism and evaluate the remaining life, temperature and strain monitoring were taken from the damaged piping during startup and normal operation.

Preface for the 2004 Advances in Materials Technology for Fossil Power Plants conference.

Sanicro 25 material is approved for use in pressure vessels and boilers according ASME code case 2752, 2753 and VdTUV blatt 555. It shows higher creep rupture strength than any other austenitic stainless steels available today. It is a material for superheater and reheaters, enabling higher steam parameters of up to about 650 °C steam (ie about max 700 °C metal) without the need for expensive nickel based alloys. The aim of the present study is the investigation of the steam oxidation resistance of the Sanicro 25. The long term test was conducted in the temperature range 600 -750 °C up to 20 000 hours. The morphology of the oxide scale and the microstructure of the bulk material were investigated. In addition, the effect of surface finish and pressure on the steam oxidation were also studied.

One of the pathways for achieving the goal of utilizing the available large quantities of indigenous coal, at the same time reducing emissions, is by increasing the efficiency of power plants by utilizing much higher steam conditions. The US Ultra-Supercritical Steam (USC) Project funded by US Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) promises to increase the efficiency of pulverized coal-fired power plants by as much as nine percentage points, with an associated reduction of CO 2 emissions by about 22% compared to current subcritical steam power plants, by increasing the operating temperature and pressure to 760°C (1400°F) and 35 MPa (5000 psi), respectively. Preliminary analysis has shown such a plant to be economically viable. The current project primarily focuses on developing the materials technology needed to achieve these conditions in the boiler. The scope of the materials evaluation includes mechanical properties, steam-side oxidation and fireside corrosion studies, weldability and fabricability evaluations, and review of applicable design codes and standards. These evaluations are nearly completed, and have provided the confidence that currently-available materials can meet the challenge. While this paper deals with boiler materials, parallel work on turbine materials is also in progress. These results are not presented here in the interest of brevity.

The effect of taking miniature sample scoops on the creep life of ASME Grade 91 steel pipes was experimentally and analytically assessed in this work. Internal pressure tests were conducted on tubular specimens having defects on their outer surface, which simulate sampling scoops. The creep life did not decrease until the depth ratio of the defect to the wall thickness of the specimens was about 5%, and the creep life decreased with increasing defect depth when the depth ratio exceeded about 5%. When the depth ratio was about 11%, the creep life decreased to four-fifths of that of a specimen with no defects. In addition, as a result of investigating the stress concentration around a defect with a depth ratio of about 5% by the finite element method, stress concentration was clearly observed around the defect. These results suggest that taking a miniature sample up to a depth of 5% of the thickness of a Grade 91 steel pipe in service has a negligible effect on the creep life of the pipe.