This paper reports the results of a collaborative investigation of an ex-service grade 91 bend carried out by the UK generating companies Centrica, SSE, Engie and RWE. As part of the handover exercise for Centrica’s Langage power station in 2009 a number of routine checks were carried out on the main steam and hot reheat grade 91 steam pipework. In some cases low hardness readings were found with subsequent metallurgical replication showing the presence of an aberrant non martensitic microstructure. This led to a more extensive inspection programme on the steam lines and the discovery of other areas of suspect material. A review of the operating capability of the plant, including detailed pipework stress analysis and a pipework peaking assessment, along with the assumption that lower strength grade 91 material was present, led to the steam lines being down rated and returning to service under these revised conditions. At the first C inspection in December 2012, after the HRSG and associated pipework had operated for 18720 hours, a bend with a soft weld, along with a section of the straight pipe on either side, was removed from service. An investigation was undertaken to establish how long this component would have survived, had it been left in service, and to consider the implications for the future operation of the plant.

The application of cold weld repair techniques in the power industry has been well documented. This type of repair is only considered when a conventional repair (involving post-weld heat treatment) is impracticable or the penalties of time and cost for conventional repair are sufficiently high. A typical cold weld repair in the UK has involved low alloy ferritic steel (½Cr½Mo¼V, 2¼Cr1Mo) components welded with nickel based SMAW consumables or ferritic FCAW consumables. Modified 9Cr steel components have been used in UK power plant since the late 1980’s for a number of applications, such as superheater outlet headers, reheat drums and main steam pipework. The problems associated with this material have also been well documented, particularly premature type IV cracking of welds on creep weakened modified 9Cr steel. RWE Generation UK have developed modified 9Cr cold weld repairs on headers, pipework and tubes. These repairs have been underwritten with extensive testing. This paper will describe the work performed on developing T91 cold weld repairs and where they have been applied on power plant.

The Creep Strength Enhanced Ferritic steel grade 91 is widely used for both retrofit applications and primary construction on high temperature power plant. Although to date most structural integrity issues with this material have been associated with welds, as the operating hours of these plants accumulate, there will be a growing need for remanent creep life assessment of the base material. Arguably this is already the case for aberrant grade 91 material entering service in an incorrectly heat treated condition. In these circumstances the strength may fall below the normally accepted lower bound of the creep strength range and some indication of actual strength may be required. One strategy to address potential base material failure is to use small scale sampling of individual components, followed by small scale creep testing, to investigate the current creep strength present. The data can be compared with the equivalent data produced for well characterised material known to be at the lower bound of the creep strength range. This paper describes a methodology for using the impression creep data obtained to provide both creep strength ranking and an estimate of absolute creep strength for individual grade 91 components. This will enable appropriate judgements to be made by plant operators on repair/run decisions. For those components remaining in service, it allows for the weakest items to be given priority for early re-inspection at future outages. The ultimate goal is to identify base material creep damage development at as early a stage as possible and well in advance of failure in service.

There is a constant need for improved knowledge of the influence of non-standard processing on the expected performance of creep strength enhanced ferritic (CSEF) materials as the total installed tonnage of these materials is rapidly increasing across the power generation industry. Cr-Mo-V steel grades micro-alloyed with niobium and titanium designed for pressurized equipment operating in the supercritical steam range proved to be very sensitive to relative minor variations in the principal heat treatment parameters time and temperature, when compared to the traditional Cr-Mo-V grades. A key component for successful welds is optimised post weld heat treatment (PWHT). Under certain conditions premature failures of welds can occur when incorrect weld and heat treatment performance result in a reduction of specified mechanical properties and high temperature creep performance, it is therefore of significant importance to have a good understanding of actual material properties for effective operation and plant life studies. This study investigated the effect and impact variations of post weld heat treatment time and temperature on mechanical properties of tungsten inert gas (TIG) and manual metal arc (MMA) welds on Grade 91 pipes from a set of reference samples. This is in preparation of establishing a benchmark set of tests to determine the integrity and expected long-term performance of butt-welds from limited site sample volumes, providing a non-intrusive methodology to identify welds suspected to have received non-standard PWHT cycles on Grade 91 pipework systems.

The impression creep test method using a rectangular indenter has been well established and the applicability of the technique has been supported by the test data for a number of metallic materials at different temperatures and stresses. The technique has proved to be particularly useful in providing material data for on-site creep strength assessments of power plant components operating in the creep regime. Due to these reasons, “standard” assessment procedures using the impression testing method are needed in order for the technique to be more widely used. This paper will first address some key issues related to the use of the impression creep test method, involving the data conversion method, typical test types and validity of the test technique etc. Then some recommendations on a number of practical aspects, such as the basic requirements of test rigs, “standard” specimen geometry, indenter dimensions, sampling procedures for scoop samples, specimen preparation, temperature and loading control, and displacement measurement, are briefly addressed. Finally, applications of the test data to assist with the risk management and life assessment programme of power plant components, particularly those with service-exposed materials, using data obtained from scoop samples, are described. Proposals for future exploitation and for improvement of the technique are addressed.

Both non-destructive and traditional microsectioning techniques have been used to measure the oxide thickness of steam grown oxides between two close contacting surfaces. Different power plant materials, nickel based alloys and ferritic-martensitic steels, were exposed to steam oxidation at temperatures ranging from 650 °C up to 750 °C and periods from 500 h to 3000 h. Ultrasonic measurements of thickness, based on the speed of sound in the oxide, were performed and compared to optical thickness measurements based on conventional metallographic microsectioning with promising results. Improvements on the measurement resolution have been practically demonstrated with oxides down to 65 μm thickness being measured successfully.

In several material qualification programs tubes and thick-walled components mainly from Alloy 617 and Alloy 263 were investigated. Results as low cycle fatigue and long term creep behavior of base materials and welds are presented. Numerical models to describe the material behavior have been developed and verified by multiaxial tests. In order to ensure the feasibility of A-USC plants two test loops have been installed in GKM Mannheim – one for tube materials and a new one for thick-walled piping and components. The latter consists of a part with static loading and a part subjected to thermal cycles and is in operation since November 2012. First results of measurements and numerical calculations for a pipe bend (static loading) as well as pipes and a header (thermal cycles) are presented.

Carbon Capture and Storage (CCS) has become promising technology to reduce CO 2 emissions. However, as a consequence of CCS installation, the electrical efficiency of coal fired power plant will drop down. This phenomenon requires increase in base efficiency of contemporary power plants. Efficiency of recent generation of power plants is limited mainly by maximum live steam temperature of 620°C. This limitation is driven by maximal allowed working temperatures of modern 9–12% Cr martensitic steels. Live steam temperatures of 750°C are needed to compensate the efficiency loss caused by CCS and achieve a net efficiency of 45%. Increase in the steam temperature up to 750°C requires application of new advanced materials. Precipitation hardened nickel-based superalloys with high creep-rupture strength at elevated temperatures are promising candidates for new generation of steam turbines operating at temperatures up to 750°C. Capability to manufacture full-scale forged rotors and cast turbine casings from nickel-based alloys with sufficient creep-rupture strength at 750°C/105 hours is investigated. Welding of nickel-based alloys in homogeneous or heterogeneous combination with 10% Cr martensitic steel applicable for IP turbine rotors is shown in this paper. Structure and mechanical properties of prepared homogeneous and heterogeneous weld joints are presented.

High efficiency in power generation is not only desirable because of economical reasons but also for enhanced environmental performance meaning reduced quantity of forming ash and emissions. In modern medium to large size plants, improvements require supercritical steam values. Furthermore, in future there will be an increasing share of renewables, such as wind and solar power, which will enhance the fluctuation of supply with the consequence that other power sources will have to compensate by operating in a more demanding cyclic or ramping mode. The next generation plant will need to operate at higher temperatures and pressure cycles coupled with demanding hot corrosion and oxidation environments. Such an operation will significantly influence the performance of materials used for boilers and heat exchanger components by accelerating oxidation rates and lowering mechanical properties like creep resistance. The paper discusses the oxidation behaviour of San25, 800H and alloy 263 in supercritical water at temperatures 650 and 700 °C at 250 bar, and compares the changes of mechanical properties of materials at these temperatures.

MarBN steels, originally developed by Professor Fujio Abe at NIMS Japan, have undergone significant advancement in the UK through a series of government-funded collaborative projects (IMPACT, IMPEL, INMAP, IMPULSE, and IMPLANT). These initiatives have achieved several major milestones, including operational power plant trials, full-scale extruded pipe production, matching welding consumable development, and most notably, the creation of IBN-1—a new steel demonstrating 30-45% higher creep strength than Grade 92. However, like other creep strength-enhanced ferritic steels, IBN-1 shows reduced creep ductility under the lower stress conditions typical of operational use. Since adequate creep ductility is essential for component damage tolerance and effective in-service monitoring, this study investigates the effects of an alternative normalizing and tempering heat treatment on cast IBN-1. The research presents creep rupture test results showing improved ductility and analyzes the microstructural mechanisms responsible for this enhancement.

Extensive research and development has been undertaken in the UK on MarBN steels. These were first proposed by Professor Fujio Abe from NIMS in Japan. Within the UK, progress has been made towards commercialisation of MarBN-type steel through a series of Government funded industrial collaborative projects (IMPACT, IMPEL, INMAP and IMPULSE). As part of the IMPACT project, which was led by Uniper Technologies, boiler tubes were manufactured from the MarBN steel developed within the project, IBN1, and installed on the reheater drums of Units 2 and 3 of Ratcliffe-on-Soar Power Station. The trial tubes were constructed with small sections of Grade 91 tubing on either side of the IBN1 to allow direct comparison after the service exposure. This is the world’s first use of a MarBN steel on a full-scale operational power plant. In September 2018 the first tube was removed having accumulated 11,727 hours operation and 397 starts. This paper reports microstructural and oxidation analysis, that has been undertaken by Loughborough University as part of IMPULSE project, and outlines future work to be carried out.

Sufficient energy availability in combination with lowest environmental pollution is a basic necessity for a high living standard in each country. To guarantee power supply for future generations, improved technologies to achieve higher efficiency combined with reduced environmental impact are needed. This challenge is not only aimed to the power station manufacturers, but also to the producers of special steel forgings, who have to handle with more and more advanced materials and complex processes. Bohler Special Steel is a premium supplier of forged high quality components for the power generation industry. This paper reports about experiences in the fabrication of forged components for steam turbines for ultra-supercritical application - from basic properties up to ultrasonic detectability results. The materials used so far are the highly creep-resistant martensitic 9-10% Cr steel class for operating temperatures up to 625°C developed in the frame of the European Cost research program. Additionally our research activities on the latest generation of high temperature resistant steels for operating temperatures up to 650 degree Celsius – the boron containing 9% Cr martensitic steels (MARBN) - are discussed. In order to improve the creep behavior, MARBN steels with different heat treatments and microstructures were investigated using optical microscopy, SEM and EBSD. Furthermore, short term creep rupture tests at 650 degree Celsius were performed, followed by systematic microstructural investigations. As a result it can be concluded, that advanced microstructures can increase the time to rupture of the selected MARBN steels by more than 10 percent.

High chromium HiperFer (High performance ferritic) materials present a promising concept for the development of high temperature creep and corrosion resistant steels. The institute for Microstructure and Properties of Materials (IEK-2) at Forschungszentrum Jülich GmbH, Germany develops high strength, Laves phase forming, fully ferritic steels which feature excellent resistance to steam oxidation and better creep life than state of the art 9-12 Cr steels. Mechanical strength properties of these steels depend not only on chemical composition, but can be adapted to various applications by specialized thermo(mechanical) treatment. The paper will outline the sensitivity of tensile, creep, stress relaxation and impact properties on processing and heat treatment. Furthermore an outlook on future development potentials will be derived.

This paper reports on the latest in a series of projects aiming at the qualification of new and proven materials in components under a severe service environment. In the initial stages of the project (HWT I & HWT II), a test loop at Unit 6 of the GKM Power Plant in Mannheim was used to study the behavior of components for advanced ultra-supercritical (A-USC) plants made from nickel alloys at 725 °C under both static and fluctuating conditions. Due to recent changes in the operation modes of existing coal-fired power plants, the test loop was modified to continue operating the existing nickel components in the static section while applying thermal cycles in a different temperature range. HR6W pipes and valves were added to the bypass of the static section, and all components in the cyclic section were replaced with P92, P93, and HR6W components. The test loop achieved approximately 9000 hours of operation and around 800 cycles with holding times of 4 and 6 hours. After dismantling the loop, nondestructive and destructive examinations of selected components were conducted. The accompanying testing program includes results from thermal fatigue, fatigue, thermal shock, and long-term creep tests, focusing on the behavior of base materials and welds, particularly for HR6W, P92, P93, and other nickel-based alloys. Additionally, test results on dissimilar welds between martensitic steel P92 and nickel alloys A617 and HR6W are presented. Numerical assessments using standardized and numerical lifetime estimation methods complement the investigations. This paper provides insights into the test loop design and operational challenges, material behavior, and lifetime, including advanced numerical simulations and operational experiences with valves, armatures, piping, and welds.

Driven by the need to reduce CO 2 emissions through increased steam temperature and pressure in new power plants, research in Europe led to the development of enhanced high-chromium steels with improved creep resistance and service temperature stability. After years of development, Rotor E, a steel composition created during the COST programs (501, 522, and 536), has become a commercially available product. While traditionally forged and remelted using electroslag remelting (ESR), this paper demonstrates the successful production of large rotor components using a conventional process without ESR, achieved through tailored process control. This paper details Società delle Fucine's (SdF) current production of Rotor E using a conventional route based on ladle furnace and vacuum degassing, as well as the mechanical and creep behaviors of the resulting forged products. Additionally, SdF produced a prototype FB2 rotor using a conventional process. FB2, a 10% Cr steel containing cobalt and boron but lacking tungsten, emerged from the COST 522 program as the best candidate for scaling up from a laboratory experiment to a full-sized industrial component. Notably, the addition of boron effectively improved the microstructure's stability and consequently enhanced the creep resistance of these new, advanced martensitic steels. Finally, the paper will present updates on the long-term characterization program for the FB2 steel trial rotor.

In order to enable safe long-term operation, metallic pipes operated in the creep range at high temperatures require considerable wall thicknesses at significant operating pressures, such as those required in thermal power plants of all kinds or in the chemical industry. This paper presents a concept that makes it possible to design such pipes with thinner wall thicknesses. This is achieved by adding a jacket made of a ceramic matrix composite material to the pipe. The high creep resistance of the jacket makes it possible to considerably extend the service life of thin- walled pipes in the creep range. This is demonstrated in the present paper using hollow cylinder specimens. These specimens are not only investigated experimentally but also numerically and are further analyzed after failure. The investigations of the specimen show that the modeling approaches taken are feasible to describe the long-term behavior of the specimen sufficiently. Furthermore, the paper also demonstrates the possibility of applying the concept to pipeline components of real size in a power plant and shows that the used modeling approaches are also feasible to describe their long-term behavior.

The present study presents a detailed investigation on the evolution of the microstructure during welding on virgin and long-term service exposed (creep aged 1 = 535°C; 16.1 MPa; 156 kh and creep aged 2 = 555°C; 17.0 MPa; 130 kh) 12% Cr (X20CrMoV11-1) martensitic steel. This study was carried out in order to understand the impact of welding on prior creep exposed Tempered martensite ferritic (TMF) steel and to explain the preferential failure of weldments in the fine grained heat affected zone (FGHAZ) of the creep aged material side instead of the new material side. Gleeble simulation (Tp = 980°C; heating rate = 200 °C/s; holding time = 4 seconds) of the FGHAZ was performed on the materials to create homogeneous microstructures for the investigation. Quantitative microstructural investigations were conducted on the parent plate and simulated FGHAZ materials using advanced electron microscopy to quantify: a) voids, b) dislocation density, c) sub-grains, and d) precipitates (M 23 C 6 , MX, Laves, Z-phase) in the materials. Semi-automated image analysis was performed using the image analysis software MIPARTM. The pre-existing creep voids in the creep aged parent material and the large M 23 C 6 carbides (Ø > 300 nm) in the FGHAZ after welding are proposed as the main microstructural contributions that could accelerate Type IV failure on the creep aged side of TMF steel weldments.

This paper reports the results of a collaborative small scale creep testing exercise carried out by the UK generating companies Centrica, SSE, Engie and RWE as part of an investigation of an ex-service grade 91 bend.

Components such as tubes, pipes and headers used in power generation plants are operated in a creep regime and have a finite life. During partial replacement, creep exhausted materials are often welded to virgin materials with superior properties. The aim of this study was to identify a suitable weld filler material to join creep aged X20CrMoV12-1 to a virgin P91 (X10CrMoVNbV9-1) steel. Two dissimilar joints were welded using the gas tungsten arc welding (GTAW) process for the root passes, and manual metal arc (MMA) welding for filling and capping. The X20 and the P91 fillers were selected for joining the pipes. The samples were further heat treated at 755°C to stress relief the samples. Microstructural evolution and mechanical properties of the weld metals were evaluated. The average hardness of X20 weld metal (264 HV10) was higher than the hardness measurement of P91 weld metal (206 HV10). The difference in hardness was attributed to the high carbon content in X20 material. The characterisation results revealed that the use of either X20 or P91 weld filler for a butt weld of creep aged X20 and virgin P91 pipes material does not have a distinct effect on the creep life and creep crack propagation mechanism. Both weld fillers (X20 and P91) are deemed to be suitable because limited interdiffusion (<10 μm) of chromium and carbon at the dissimilar weld interface was observed across the fusion line. The presence of a carbon ‘denuded’ zone was limited to <10 μm in width, based on the results from local measurements of the precipitate phase fractions using image analysis and from elemental analysis using EDS. However the nanoindentation hardness measurements across the fusion line could not detect any ‘soft’ zone at the dissimilar weld interface. The effect of the minute denuded zone was also not evident when the samples were subjected to nanoindentation hardness testing, tensile mechanical testing, Small Punch Creep Test (SPCT) and cross weld uniaxial creep testing.